Mechanisms of granular activated carbon anaerobic fluidized-bed process for treating phenols wastewater

ＩｎｔｒｏｄｕｃｔｉｏｎＢｅｆｏｒｅｔｈｅ 1 980ｓｃｏｎｖｅｎｔｉｏｎａｌｔｒｅａｔｍｅｎｔｐｒｏｃｅｓｓｅｓｏｆｐｈｅｎｏｌｓｗａｓｔｅｗａｔｅｒａｒｅｓｏｌｖｅｎｔｅｘｔｒａｃｔｉｏｎ ,ｐｈｙｓｉｃａｌａｄｓｏｒｐｔｉｏｎ ,ｃｈｅｍｉｃａｌｏｘｉｄａｔｉｏｎａｎｄａｅｒｏｂｉｃｂｉｏｌｏｇｉｃａｌｐｒｏｃｅｓｓ.Ａｍｏｎｇｔｈｅｂｉｏｌｏｇｉｃａｌｕｎｉｔｐｒｏｃｅｓｓｅｓａｃｔｉｖａｔｅｄｓｌｕｄｇｅｐｒｏｃｅｓｓｉｓｍａｉｎｏｎｅ.Ａｆｔｅｒｔｈｅ 1 980ｓａｎａｅｒｏｂｉｃｂｉｏｌｏｇｉｃ…     

三唑磷农药废水厌氧处理可行性研究

采用厌氧流化率工艺处理在唑磷农药废水，必须降低原水中ＮＨ３－Ｎ含量，调整营养比例，当ＣＯＤ：Ｎ：Ｐ＝（１８０～２００）：５：１时，在中温厌氧消化条件下，ＣＯＤ含量可从４１７０ｍｇ／ｌ，去除率约５０％，沼气产率达到０．２５６ｍ＾３／ｍ＾３．ｄ。因此，把厌氧处理作为好氧处理的预处理单元，能确保整个处理系统出水达标。     

生物陶粒流化床-污泥滤层脱氮工艺的试验研究

采用生物陶粒流化床-污泥滤层工艺对含氮有机废水处理进行试验研究,研究结果表明:系统内可固着生长不受抑制的硝化菌种群,氨氮去除率可以达到93%￣95%;三相分离区形成稳定的污泥滤层,可使总氮去除率得以显著提高;当HRT为1.5h,曝气量为0.25m3/h,BOD容积负荷为9.2～10.4BOD5/m3.d,总氮容积负荷0.65kgTN/m3.d条件下,可得到BOD5的去除率85%,总氮去除率74%的处理效果。     

一种新型复合式生物流化反应器混合特性的研究

对新型蜂窝状断面复合生物流化反应器进行了液体循环速率和水力停留时间分布曲线的测定，实验表明新型反应器具有抗冲击负荷强，接近CSTR反应器的特点，反应器随气量增大、载体投加量减少和进水量减少而更近似于CSTR反应器，通过理论分析，证明了影响液体循环速率的参数主要有气体流量(气含率)、反应器沿程和局部阻力系数以及Ad/Ar，并且得出液体循环速率与反应器高度的0．5次方成正比。     

循环流化床锅炉床温控制方法

就目前电厂循环流化床锅炉运行中存在的床温波动问题，讨论了导致床温波动的因素，并针对性地提出了控制床温的一些措施。     

流化催化裂化烟气脱硫助剂的制备及其脱硫活性

采用溶胶-凝胶法制备锌铝助剂，该助剂于700℃焙烧后与流化催化裂化（FCC）催化剂进行机械混合，制得混合催化剂；在FCC烟气工业模拟装置上考察混合催化剂的脱硫活性，用混合催化剂的脱硫活性来反映锌铝助剂的脱硫性能。实验结果表明，氧化锌质量分数为10％的锌铝助剂的脱硫活性最佳，脱硫率达62．5％。采用红外光谱和X射线衍射（XRD）对锌铝助剂的脱硫机理进行了研究，红外分析结果表明，弱的L酸中心有利于锌铝助剂脱硫，XRD分析结果表明，锌铝助剂在锌铝尖晶石结构尚未完全形成时，存在较多的晶格缺陷，能够有效地吸附烟气中的SOx，将其转化为H2S。     

云天化3#循环流化床锅炉项目技术经济分析

云天化股份公司在2004年建造了3#循环流化床锅炉，以煤代气。它可以缓解公司原料天然气的紧张状况，并能带来很大的经济效益。从技术经济的角度对该项目的技术先进性、可靠性及内部收益率、投资回收期、净现值等技术指标进行了分析。     

厌氧-好氧一体化反应器处理高浓度有机废水的运行特性研究

本实验采用新型厌氧—好氧一体化反应器处理高浓度有机废水,主要研究了系统的启动与运行性能,并对系统的NH3 N去除效果作了初步考察。实验结果表明:在16℃～24℃的自然温度下,采用递增负荷、厌氧和好氧分期启动的方式,系统可在38天内达到较好的启动效果;在系统负荷运行期内,当系统总进水COD浓度平均值为3601 8mg/L,总出水COD浓度平均值为384 0mg/L,系统容积负荷平均值为2 54kgCOD/(m3·d),系统总HRT平均值为35 1h时,系统总COD去除率平均值达90 6%。实验还发现:当进水NH3 N浓度为280 3～350 7mg/L,整个系统的NH3 N去除率在68 5%～91 7%,平均为81 0%。由此说明,本反应器具有很好的COD去除性能和NH3 N去除效果,适合于处理COD浓度高且含有中等NH3 N浓度的有机废水。     

Application of 1D and 2D MFR reactor technology for the isolation of insecticidal and anti-microbial properties from pyrolysis bio-oils

Valuable chemicals can be separated from agricultural residues by chemical or thermochemical processes. The application of pyrolysis has already been demonstrated as an efficient means to produce a liquid with a high concentration of desired product. The objective of this study was to apply an insect and microorganism bioassay-guided approach to separate and isolate pesticidal compounds from bio-oil produced through biomass pyrolysis. Tobacco leaf (Nicotianata bacum), tomato plant (Solanum lycopersicum), and spent coffee (Coffea arabica) grounds were pyrolyzed at 10°C/min from ambient to 565°C using the mechanically fluidized reactor (MFR). With one-dimensional (1D) MFR pyrolysis, the composition of the product vapors varied as the reactor temperature was raised allowing for the selection of the temperature range that corresponds to vapors with a high concentration of pesticidal properties. Further product separation was performed in a fractional condensation train, or 2D MFR pyrolysis, thus allowing for the separation of vapor components according to their condensation temperature. The 300–400°C tobacco and tomato bio-oil cuts from the 1D MFR showed the highest insecticidal and anti-microbial activity compared to the other bio-oil cuts. The 300–350 and 350–400°C bio-oil cuts produced by 2D MFR had the highest insecticidal activity when the bio-oil was collected from the 210°C condenser. The tobacco and tomato bio-oil had similar insecticidal activity (LC₅₀ of 2.1 and 2.2 mg/mL) when the bio-oil was collected in the 210°C condenser from the 300–350°C reactor temperature gases. The 2D MFR does concentrate the pesticidal products compared to the 1D MFR and thus can reduce the need for further separation steps such as solvent extraction.     

Nitrogen evolution during the co-combustion of hydrothermally treated municipal solid waste and coal in a bubbling fluidized bed

Nitrogen evolution was studied during the co-combustion of hydrothermally treated municipal solid wastes (HT MSW) and coal in a bubbling fluidized bed (BFB). HT MSW blending ratios as 10%, 20% and 30% (wt.%) were selected and tested at 700, 800, 900 °C. Emissions of NO and N₂O from blends were measured and compared with the results of mono-combustion trials. Moreover, concentrations of precursors like NH₃ and HCN were also quantified. The results are summarized as follows: NO emissions were predominant in all the cases, which rose with increasing temperature. The blending of HT MSW contributed to the NO reduction. N₂O emissions decreased with temperature rising and the blending of HT MSW also presented positive effects. At 30% HT MSW addition, both NO and N₂O emissions showed the lowest values (391.85 ppm and 55.33 ppm, respectively at 900 °C). For the precursors, more HCN was detected than NH₃ and both played important roles on the gas side nitrogen evolution.