硬脆性无机材料激光成形加工研究与应用现状

硬脆性无机材料激光成形加工是激光加工技术最有前途的领域之一。本文综述了国内外在硬脆性无机材料的激光成形加工方面的研究成果和应用状况，并展望了无机材料激光成形加工的研究与应用前景。     

熔融-固相缩聚法中固相聚合对聚乳酸合成的影响

以L 乳酸单体为原料 ,熔融 -固相缩聚法合成了聚乳酸 ,重点研究了固相聚合的工艺条件。结果表明 ,绝对压力 60Pa ,氯化亚锡为催化剂 ,分段控温 ,可使聚乳酸的粘均分子量提高到固相聚合反应前的 5 3倍。通过对固相聚合产物的结晶度和熔点的分析 ,探讨了固相聚合的机理。     

Preparation and Application of Active Composite Antibacterial Material Containing Ag~ and Zn~(2 )

1Introduction Harmfulbacteriaexistanywhereintheworldsuchas soil,air,water,surfacesofobjectsandourskins,etc.Thenumberofbacteriumisenormous,withmanydiffer entspecies.Theyhavethreatenedthehealthofhuman beingsseriously.Withthedevelopmentofeconomyand environme…     

Specification methods for material-handling control algorithms in flexible manufacturing systems

Good methods are needed to specify, test, and debug material-handling control logic. This article surveys a number of representative methods for defining and describing control algorithms for programmable material-handling equipment used in flexible manufacturing systems. The methods are evaluated with regard to their suitability for communication between people and as bases for interfaces to automatic program generators. It is concluded that no single method is entirely satisfactory. Three methods (position diagrams, function block diagrams, and operation networks) have potential to be combined into an effective hybrid approach that minimizes the need for the user to switch between various conceptual models.     

Electrocatalysis of chlorine evolution on different materials and its influence on the performance of an electrochemical reactor for indirect oxidation of pollutants

Two different Ti/Pt–Ir materials (commercial and home made) and Ti/PdO + Co₃O₄ were investigated for their electrocatalytic properties versus Cl₂ evolution reaction. The materials were used in a batch electrochemical reactor to treat biologically recalcitrant di-azo compound. An electrochemically driven oxidation, mediated by a Cl₂/Cl⁻ couple, proved efficient for destruction of this complex organic molecule, causing cleavage of the conjugated double bonds and destruction of unsatured bonds. Both Ti/Pt–Ir materials performed well; lower kinetics obtained with the Ti/PdO + Co₃O₄ anode was caused by adsorption of the model compound, evidenced in preliminary voltammetric measurements. The dye oxidation reaction followed the second order kinetics with partial orders in the model compound and (time varying) chlorine concentrations equal to one. Specific energy consumption of 3.12 kWh m⁻³ proved the process more economic than the homogeneous phase oxidation.     

Al/Fe2O3反应合成材料热力学

运用CALPHAD技术，基于多组元多相复杂平衡体系的吉布斯自由能最小化原理，用大型集成数据库F^*A^*C^*T系统，考察了铝和氧化铁经典反应体系的热力学规律。针对材料的反应合成技术，计算了化学计量铝和氧化铁体系以及各种产物中物种的相变情况；分析了原料初始温度、配料比和SiO2含量对绝热温度和平衡组成的影响。     

关于混凝土四面体截流材料的探讨

通过对比混凝土四面体与特大块石这两种截流材料的抗冲稳定性和施工的方便性,分析了混凝土四面体截流材料在工程应用中存在的问题。指出:①混凝土四面体密度、综合稳定系数、化引球形粒径都偏小,在龙口的抗冲稳定性不如特大块石;②混凝土四面体制作麻烦,成本高,占地面积大,装运困难,抛投强度低,施工不如特大块石方便;③在截流施工中宜优先使用特大块石,慎用混凝土四面体。     

未增塑聚氯乙烯(PVC-U)异型材配方基础

PVC-U异型材配方十分复杂,常用原料通常在10种以上。根据大连实德集团实际生产情况,这10多种原料通常以7大组分的方式进行配料和生产。文中就该配方中7大组分的分类、特点及应用情况分别进行了详细介绍。     

土工合成材料在辽宁省水利工程中应用效益分析

截止2003年辽宁省水利工程中应用土工合成材料已达1450万多m^2，尤其在河道护岸、堤(坝)护坡、防渗工程上这种新型工程材料得到了广泛应用。结合辽宁省水利工程上应用的实际，对其效益进行了分析，分析结果表明：采用土工织物软体排护岸比传统柴排护岸节省投资35％～80％；堤坝护坡采用土工织物滤层比传统砂砾料滤层节省投资30％以上；土工膜防渗可比粘土防渗节省投资30％～50％。同时还取得了保护生态平衡、节省能源、促进化纤工业发展等十分显的社会效益。     

Preparation and Properties of Rare Earth Modified Carbon Black/Natural Rubber Composites

The oxides Eu, Ho, Er and Dy were used to prepare the hydroxides of rare earth modified carbon black. Then natural rubber latex （NRL） was added into the reactor. The system reacted at 85 ℃ with stirring for 1 h to prepare powdered HAF-Ln（OH）3/NR composites. The effects of the kind and content of Ln on the particle size distribution of P [ NR/HAF-Ln （OH）3 ] and mechanical properties of its vulcanizate were studied respectively. It is found that rare earth can help to get the powder of the composite, the product particle with a diameter less than 0.9mm will be get when the composites containing the compound of Ho, Er and Dy with dosage of 1.0, 1.0, O. 5 percent, respectively. The adding of Ln can improve the tensile strength and tear strength of the vulcanizate effectively, what＇s more, Er and Dy can decrease the permanent set of vulcanizate significantly. The SEM studies shows that P[ NR/HAF-Dy （OH）3 ] vulcanizate shows superior mechanical properties that depend primarily on the absence of free carbon black, the fine dispersion of carbon black in the rubber matrix and better polymer-filler interaction.