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91.
1 INTRODUCTIONIn recent years, the application of the roomtemperature type ( < 100 ℃) polymer electrolytemembrane fuel cells(PEMFCs) as a primary powersource in electric vehicles and portable equipmentsetc has received increasing attention[1 4]. Usuallyin a PEMFC system, platinum is chosen as the e lectrode electrocatalyst, however, it results in ahigh cost PEMFC system for commercialization be cause Pt is a high cost, source limit metal. So,looking fo… 相似文献
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1 INTRODUCTION in 1 5 0℃ .Maas[1 0 ] alsomanufacturedtheH2 O2 fuelcellstackswiththeoutputpowerupto 1kW ,andthepropertiesoftheas preparedfuel 相似文献
95.
碳钢在流动3%氯化钠溶液中的腐蚀机理的探讨 总被引:4,自引:1,他引:4
本文利用自行设计的模拟流动状态的装置,研究了碳钢在流动3%NaCl溶液中的腐蚀规律及施加阴极电流后对腐蚀的影响。结果表明:随着相对流速的增大,碳钢的腐蚀随之加剧,并发现存在一个临界相对流速值。当相对流速小于此值时,腐蚀主要受电化学因素影响。而相对流速大于此值时,流体力学因素开始明显起主导作用,并与电化学因素间的协同效应增强,导致腐蚀速度急剧上升。施加阴极电流后,不仅抑制了电化学因素引起的腐蚀,而且大幅度地削弱了电化学因素与流体力学因素间的协同效应,从而使腐蚀速度大大降低。 相似文献
96.
热处理对La0.7Mg0.3Ni2.8Co0.5贮氢合金电化学性能的影响 总被引:6,自引:0,他引:6
La0.7Mg0.3Ni2.8Co0.5贮氢电极合金经过适当热处理后(1123K),最大放电容量、循环稳定性、高倍率放电性能(HRD)、交换电流密度(I0)以及极限电流密度(IL)都有明显改善,铸态合金电极的最大放电容量为392mAh/g,放电电流密度,Id=2000mA/g时,HRD2000=74.0%,I0=266.7mA/g,IL=3425.5mA/g;经1123K保温8h退火的合金电极的最大放电容量提高到414mAh/g,HRD2000=76.2%,I0=407.9mA/g,IL=3753.6mA/g。X射线衍射(XRD)分析表明,衍射峰宽度随着退火温度的升高而变窄,其原因是合金经退火处理相结构的变化和成分的均匀化。 相似文献
97.
Hot-corrosion attack on gas-turbine components has been a problem of practical importance for over two decades. The nature and the extent of corrosion are influenced by the type of contaminants, the alloy constituents, and temperature. The hot-corrosion process is quite complex. There is controversy regarding the role of alloying elements, and whether the process is chemical or electrochemical in nature. In this investigation, an attempt has been made to investigate the role of Al and Ti in influencing the hot-corrosion attack of Ni-20 wt. % Cr alloys in molten Na2SO4-NaCl mixtures. It was found that Ni-Cr-Al alloys undergo a localized, heavy-blister attack under certain experimental conditions which is electrochemical in nature. An electrochemical model has been proposed which can satisfatorily explain the nature and kinetics of the localized blister corrosion. 相似文献
98.
The calcium-containing active material of secondary alkaline zinc electrodes was prepared by a chemical coprecipitation method and characterized by scanning electron microscopy(SEM) and X-ray diffractometry(XRD).Their electrochemical performance was tested by the Galvanstatic charge-discharge method. The experimental results show that the sample synthesized at pH: 11. 15 has a typical calcium zincate crystal. The zinc electrode using this sample as active material shows higher discharge capacity, more negative discharge plateau potential and longer cycle lifetime. 相似文献
99.
讨论了壁厚(1~10mm)对无钕低铈低钴LPC(NiCoMnAlCuFeSi)5和商用成分Mm(NiCoMnAl)5铸态贮氢合金电化学性能的影响。研究发现:10mm厚的两种合金活化性能均优于1~6mm厚度合金;在0.2C充放电制度下,两种合金的放电容量对铸锭厚度均不敏感,LPC(NiCoMnAlCuFeSi)。合金的最大容量约为285mAh/g,Mm(NiCoMnAl)5合金的放电容量约为300mAh/g;在1C充放电制度下,LPC(NiCoMnAlCuFeSi)5合金的最大容量约为250mAh/g,对壁厚不敏感,Mm(NiCoMnAl)5合金的放电容量为250~280mAh/g,对壁厚敏感,并且前者显示出更好的循环稳定性。造成LPC(NiCoMnAlCuFeSi)。合金电化学性能对冷却速度不敏感的主要原因是元素Cu、Fe和Si的作用;晶胞参数和内应力等因素的交互作用也对该合金的性能有一定的影响。 相似文献
100.
Surface finishing is one of the most important processes in mould and die making. This process is necessary not only for smoothing the surface of die or mould, but also for removing the surface layer, which has been damaged by the preceding machining process and finally improve the performances and lifetime of moulds to a large extent. It has been reported that between 30% and 40% of the total time required to manufacture a die or mold is spent on finishing operations, most of which are performed by skilled workers employing traditional techniques. At present, key problems in mould and die finishing technology can improve the finishing efficiency, consistency and quality at reduced costs. A new and high efficiency unconventional finishing technology, pulse electrochemical finishing was introduced. Experiments were done in neutral nitrate electrolytes. The influence of electrolyte composition, intereletrode gap, finishing time, flow quality, current density, compositions of steel materials and pulse parameters on the resulting surface finishing was investigated. Results indicate that pulse parameters have important influence on operations finishing and the proper selection of pulse parameters can lead to both good smoothing efficiency and surface quality at low costs. 相似文献