冀北赤城红旗营子群黑云斜长片麻岩的岩石学、地球化学及原岩特征

冀北赤城红旗营子群黑云斜长片麻岩具斑状变晶结构,变基质为中、细粒鳞片粒状变晶结构,片麻状构造,局部保留有变余砂状结构。岩石主要由斜长石(28%~32%)、石英(35%~40%)、黑云母(18%~25%)及少量石榴石(2%~8%)和石墨(1%~4%)等组成,其变质演化可能是一个降温、降压的过程。黑云斜长片麻岩样品具有较宽的常量元素变化范围,稀土元素含量不是很高且变化较大,ΣREE介于49.45×10-6~140.10×10-6之间,具有轻稀土富集、重稀土平坦的球粒陨石标准化稀土配分模式,轻、重稀土元素比值为5.23~9.16,(La/Yb)CN值为5.07~8.70。大多数样品具中等程度的负Eu异常和不太明显的负Ce异常,(Eu/Eu*)CN和(Ce/Ce*)CN值分别为0.63~0.81和0.82~1.01。岩石中Rb、Sr、Cs、Ba、Zr、Hf、Nb、Ta、Th和U等微量元素含量均低于上地壳的平均含量,但Sr/Ba和Th/U值高于上地壳的平均值。红旗营子群黑云斜长片麻岩的地球化学特征表明其原岩应为泥质(或含泥质)砂岩,可能形成于大陆岛弧环境。     

Early Miocene post-collisional magmatism in NW Turkey: geochemical and geochronological constraints

The Alaçam region of NW Turkey lies within the Alpine collision zone between the Sakarya continent and the Menderes platform. Four different tectonic zones of these two continents form imbricated nappe packages (including the Afyon zone), intruded by the Alaçam granite. Newly determined U-Pb zircon ages of this granite are 20.0 ± 1.4 and 20.3 ± 3.3 Ma, indicating early Miocene emplacement. Rb-Sr biotite ages of the granite are 20.01 ± 0.20 and 20.17 ± 0.20 Ma, suggesting fast cooling at a shallow crustal level. Geochemical characteristics show that the Alaçam granite is similar to numerous EW-trending plutons in NW Anatolia.

Gneissic granites of the Afyon tectonic zone were intruded by the Miocene Alaçam granite and have been interpreted in earlier studies as sheared parts of the Alaçam granite, which formed along a crustal-scale detachment zone under an extensional regime. We determined a U-Pb zircon age of 314.9 ± 2.7 Ma for a gneissic granite sample of the Afyon zone, demonstrating that these rocks are unrelated to the Miocene Alaçam granite. The early Miocene granitic plutons bear post-collisional geochemical features and are interpreted as products of Alpine-type magmatism along the Izmir–Ankara suture zone in NW Turkey, and seem to have no genetic relation to the detachment zone.     

Mineral chemistry of Plio-Quaternary subvolcanic rocks,southwest Yazd Province,Iran

The NW–SE-trendingLate Cretaceous–Cenozoic Urumieh-Dokhtar Magmatic Arc (UDMA) in southwest Iran hosts numerous Plio-Quaternary subvolcanic porphyritic andesitic to rhyodacitic domes intruded into a variety of rock sequences. Bulk-rock geochemical data show that the calc-alkaline dacitic to rhyodacitic subvolcanic rocks share compositional affinities with high-silica adakites, including high ratios of Na₂O/K₂O >1, Sr/Y (most >70), and La/Yb (>35), high Al₂O₃ (>15 wt.%), low Yb (<1.8 ppm) and Y (<18 ppm) contents, no significant Eu anomalies, and flat to gently upward-sloping chondrite-normalized heavy rare-earth element (HREE) patterns. All analysed rocks are characterized by enrichment in large-ion lithophile elements (LILEs) and depletion in high field strength elements (HFSEs). They also display typical features of subduction-related calc-alkaline magmas. In chondrite-normalized rare-earth element patterns, the light rare-earth elements (LREEs) are enriched ((La/Sm) _N = 3.49–7.89) in comparison to those of the HREE ((Gd/Yb) _N = 1.52–2.38). Except for the G-Aliabad Dome, plagioclase crystals in the Shamsabad, Ostaj, Abdollah, and Bouragh Domes are mostly oligoclase to andesine (An_19–49). Amphibole and biotite are abundant ferromagnesian minerals in the subvolcanic rocks. Calcic amphiboles are dominantly magnesiohornblende, magnesiohastingsite, and tschermakite with Mg/(Mg + Fe_tot) ratios ranging from 0.58 to 0.78. In all the studied domes, amphiboles are typically ferric iron-rich, but that those the Shamsabad Dome have the highest Fe³⁺/(Fe³⁺ + Fe²⁺) ratios, between 0.69 and 0.98. Amphiboles from the Ostaj and Shamsabad Domes are relatively rich in F (0.39–1.01 wt.%) in comparison to the other studied domes. This phase commonly shows pargasitic and hastingsitic substitutions with a combination of tschermakitic and edenitic types.

Temperature-corrected Al-in-hornblende data show that amphibole phenocrysts from the Ostaj, Abdollah, and G-Aliabad Domes crystallized at pressures ranging from 2.14 to 3.42 kbar, 3.49 to 3.96 kbar, and 2.02 to 3.47 kbar, respectively. Temperatures of crystallization calculated with the amphibole–plagioclase thermometer for the Ostaj, Abdollah, and G-Aliabad subvolcanic domes range from 735°C to 826°C (mean = 786 ± 29), 778°C to 808°C (mean = 791 ± 13), and 866°C to 908°C (mean = 885 ± 12), respectively. In the annite–siderophyllite–phlogopite–eastonite quadrilateral, biotite from the G-Aliabad, Bouragh, and Ostaj Domes are characterized by relatively low total Al contents with variable Fe_tot/(Fe_tot + Mg) values from 0.26 to 0.43. All biotite analyses define a nearly straight line in the X _Mg versus Fe_tot plot, with r = –0.96 correlation coefficient. In comparison to other domes, the F content of biotite from the G-Aliabad Dome shows high concentrations in the range of 1.80–2.57 wt.% (mean = 2.20). Inferred pre-eruptive conditions based on the calcic amphibole thermobarometric calculations for the Shamsabad, Abdollah, and Ostaj Domes show that the calc-alkaline subvolcanic magma chamber, on average, was characterized by a water content of 6.10 wt.%, a relatively high oxygen fugacity of 10^–10.66 (ΔNNO + 1.28), a temperature of 896°C, and a pressure of 2.75 kbar.     

Petrology and geochemistry of calc-alkaline volcanic and subvolcanic rocks,Dalli porphyry copper–gold deposit,Markazi Province,Iran

Early Miocene igneous rocks associated with the Dalli porphyry ore body are exposed within the Urumieh-Dokhtar Magmatic Arc (UDMA). The Dalli porphyry Cu–Au deposit is hosted by subduction-related subvolcanic plutons with chemical composition from diorite to granodiorite, which intruded andesitic and dacitic volcanic rocks and a variety of sedimentary sequences. ⁴⁰Ar/³⁹Ar age data indicate a minimum emplacement age of ～21 million years for a potasically altered porphyritic diorite that hosts the porphyry system. The deposit has a proven reserve of 8 million tonnes of rock containing 0.75 g/t Au and 0.5% Cu. Chondrite-normalized rare earth element (REE) patterns for the subvolcanic rocks are characterized by light REE enrichments [(La/Sm) _n ?=?2.57–6.40] and flat to gently upward-sloping profiles from middle to heavy REEs [(Dy/Yb) _n ?=?0.99–2.78; (Gd/Yb) _n ?=?1.37–3.54], with no significant Eu anomalies. These characteristics are generated by the fractionation of amphibole and the suppression of plagioclase crystallization from hydrous calc-alkaline magmas. In normalized multi-element diagrams, all analysed rocks are characterized by enrichments in large ion lithophile elements and depletions in high field strength elements, and display typical features of subduction-related calc-alkaline magmas. We used igneous mineral compositions to constrain the conditions of crystallization and emplacement. Biotite compositions plot above the nickel–nickel oxide (NNO) buffer and close to oxygen fugacity values defined by the hematite–magnetite (HM) buffer, indicating oxidizing conditions during crystallization. Assuming a minimum crystallization temperature of 775°C, the oxygen (fO₂) and water (fH₂O) fugacities are estimated to be 10^?10.3 bars (～ΔNNO+4) and ≤748 bars, respectively, during the crystallization of biotite phenocrysts. The temperature and pressure conditions, estimated from temperature–corrected Al-in-hornblende barometry and amphibole-plagioclase thermometry, suggest that the hornblende phenocrysts in Dalli rocks crystallized at around 780 ± 20°C and 3.8 ± 0.4 kbar. An alternative method using the calcic amphibole thermobarometer indicates that the Dalli magmas were, on average, characterized by an H₂O content of 4.3 wt.%, a relatively high oxygen fugacity of 10^?11.0 bars (ΔNNO+1.3), and a hornblende phenocryst crystallization temperature of 880 ± 68°C and pressure of 2.6 ± 1.7 kbar.     

赣北石门寺矿区钨多金属矿床成矿地质条件

赣北石门寺矿区位于下扬子成矿省江南地块中生代铜钼金银铅锌成矿带中.根据区域地质背景和矿床地质特征,详细分析了矿区围岩、母岩和控矿断裂等成矿地质条件.矿区钨多金属矿床的围岩为晋宁晚期黑云母花岗闪长岩,判断为新元古代在不成熟陆壳基础上发育而成的火山弧同碰撞过程中形成的S型花岗岩;燕山中期似斑状黑云母花岗岩、细粒黑云母花岗岩、花岗斑岩为成矿母岩,属硅、铝过饱和钙碱性岩石,为九岭岩基在陆内碰撞挤压环境下熔融、同源演化而成的S型花岗岩;石门寺断裂与仙果山—大湖塘－狮尾洞基底断裂的交叉部位控制着矿区燕山中期含矿花岗岩的侵位和钨多金属矿床的分布,为矿区的控矿断裂.     

江西武山花岗闪长斑岩中黑云母成分特征及其成岩成矿意义

江西武山花岗闪长斑岩与矽卡岩铜矿在成因上密切相关,通过对其中的黑云母进行的岩相学观察和详细的矿物化学分析来探讨黑云母的形成条件及其成岩成矿意义。电子探针分析结果表明,武山花岗闪长斑岩中的黑云母富镁贫铁低铝高钛,属镁质黑云母。其AlⅥ为0.03~0.19,w(ΣFeO)/w(ΣFeO+MgO)为0.531~0.567,w(MgO)为12.80%~14.06%,指示武山花岗闪长斑岩属壳幔混源的I型花岗岩。黑云母结晶的温度为720℃~750℃,logfO2为-11.6~-12.5,压力为86 MPa~103 MPa,对应的侵位深度为2.84 km~3.39 km,表明该岩体形成于相对高温较浅环境,具有较大成矿潜力,有利于武山铜矿的形成。     

西准噶尔包古图富镁闪长质岩墙的时代、地球化学特征以及铜金成矿意义

西准噶尔包古图地区广泛发育富镁闪长质岩墙.对这些岩墙进行角闪石Ar-Ar和锆石U-Pb定年分别获得(313.1±3.5)Ma和(316.3±3.8) Ma的年龄,显示其主要形成于晚石炭世.闪长质岩墙以富Si(SiO2=56.8 ％～62.9％)、Mg(MgO=2.39％～4.04％、Mg#=54-62)、Cr(Cr=30×10-6～80×10-6)、Ni(Ni=20×10-6～62×10-6)为特征,具有弱的Eu负异常和高Sr/Y比值(36～44),强烈亏损HREE (Yb=1.32×10-6～1.54×10-6、Y=13.1×10-6～15.5×10-6),富集LILE (K、Sr、Ba),亏损HFSE(Nb、Ta、Ti).这些特点显示,这些闪长质岩墙可能是由俯冲的板片熔体与地幔橄榄岩反应而成,与洋脊俯冲有关.而闪长质岩墙的形成过程也有利于铜金矿床的形成,显示该区有良好的成矿远景.     

U-Pb Zircon Dating of the Yeniutan Granitic Intrusion in the Western Sector of the North Qilian Mountains

Zircons from granodiorite and biotite granite in the Yeniutan granitic intrusion in the western North Qilian Mountains yielded a weighted mean 206Pb/238U apparent age of 460±3 Ma, suggesting that the intrusion originated during the late stage of plate subduction. Its related Ta'ergou and Xiaoliugou deposits are two of the few large tungsten deposits formed in the plate subduction environment in the world. The U-Pb dating of the zircons from the biotite granite gave a discordant lower intercept age of 183±4 Ma, which implies that the Yanshanian event was probably superimposed on the North Qilian region.     

Microstructure and compositional changes across biotite‐rich reaction selvedges around mafic schollen in a semipelitic diatexite migmatite

Biotite‐rich selvedges developed between mafic schollen and semipelitic diatexite in migmatites at Lac Kénogami in the Grenville Province of Quebec. Mineral equilibria modelling indicates that partial melting occurred in the mid‐crust (4.8–5.8 kbar) in the range 820–850°C. The field relations, petrography, mineral chemistry and whole‐rock composition of selvedges along with their adjacent mafic schollen and host migmatites are documented for the first time. The selvedges measured in the field are relatively uniform in width (~1 cm wide) irrespective of the shape or size of their mafic scholle. In thin section, the petrographic boundary between mafic scholle and selvedge is defined by the appearance of biotite and the boundary between selvedge and diatexite by the change in microstructure for biotite, garnet, plagioclase and quartz. Three subtypes of selvedges are identified according to mineral assemblage and microstructure. Subtype I have orthopyroxene but of different microstructure and Mg# to orthopyroxene in the mafic scholle; subtype II contain garnet with many mineral inclusions, especially of ilmenite, in contrast to garnet in the diatexite host which has few inclusions; subtype III lack orthopyroxene or garnet, but has abundant apatite. Profiles showing the change in plagioclase composition from the mafic schollen across the selvedge and into the diatexite show that each subtype of selvedge has a characteristic pattern. Four types of biotite are identified in the selvedges and host diatexite based on their microstructural characteristics. (a) Residual biotite forms small rounded red‐brown grains, mostly as inclusions in peritectic cordierite and garnet in diatexite; (b) selvedge biotite forms tabular subhedral grains with high respect ratio; (c) diatexite biotite forms tabular subhedral grains common in the matrix of the diatexite; and (d) retrograde biotite that partially replaces peritectic cordierite and garnet in the diatexite. The four groups of biotite are also discriminated by their major element (EMPA) and trace elements (LA‐Q‐ICP‐MS) compositions. Residual biotite is high in TiO₂ and low in Sc and S, whereas retrograde biotite has high Al₂O₃, but low Sc and Cr. Selvedge and diatexite biotite are generally very similar, but selvedge biotite has higher Sc and S contents. Whole‐rock compositional profiles across the selvedges constructed from micro‐XRF and LA‐Q‐ICP‐MS analyses show: (a) Al₂O₃, FeO, MgO and CaO all decrease from mafic scholle across the selvedge and into the diatexite; (b) Na₂O is lowest in the mafic scholle, rises through the selvedge and reaches its maximum about 20–30 mm into the diatexite host; (c) K₂O is lowest in the mafic scholle and reaches its highest value in the first half of the selvedge, then declines before reaching a higher, but intermediate value, about 20 mm into the diatexite. Of the trace elements, Cs and Rb show distributions very similar to K₂O.