广东茂名高岭土煅烧实验研究

对茂名高岭土进行煅烧，结合X-射线衍射、扫描电子显微镜分析，得到了茂名高岭土在不同温度点煅烧的性能参数，并确定出其非晶化转变的温度是550℃。同时对煅烧过程中的煅烧温度、恒温时间等影响因素进行探讨，结果表明，在茂名高岭土的煅烧过程中，适当延长恒温时间可降低非晶化转变的温度，缩短恒温时间，则非晶化转变温度升高。     

四川新康风化淋滤型海泡石的热相变研究

以四川新康风化淋滤型海泡石为研究对象，利用X射线衍射分析和红外光谱分析技术，对海泡石的热相变过程及特征进行了研究。结果发现，四川新康风化淋滤型海泡石的相变过程与沉积型、热液型海泡石相变过程明显不同，其相变过程可以划分为两个阶段：800℃以下保持海泡石相；800℃以上海泡石相转化为斜顽辉石相。     

糜棱岩化过程中绿泥石多型与结晶度的演变--以郯庐断裂带南段为例

摘要：根据郯庐断裂带南段韧性剪切带糜棱岩中同构造矿物组合、黑云母的存在以及长石的变形行为，推测其变形．变质温度为400一450oC。bo值分析表明．这些糜棱岩是在低压环境下形成的。在流体作用下。糜棱岩中的绿泥石既可以交代其它矿物而形成，也可以直接从流体中结晶形成。交代其它矿物所形成的绿泥石为Ⅱ型绿泥石，其结晶度值介于0．21^。一0．23^。20．与温度具有较好的对应关系。直接从流体中结晶而产生的绿泥石初始时刻为工型．其结晶度值介于0．236^。-0．341^。20之间，多屑于近变带范畴。其指示温度要低于实际所经历的环境温度。由于糜棱岩化过程中工型绿泥石的不断产生以及工型绿泥石向Ⅱ型绿泥石转化的不充分。导致了在400以上仍然出现工型绿泥石与Ⅱ型绿泥石混合的现象．并且实测的结晶度是不同时刻形成的、具不同结晶度的绿泥石的混合结晶度。     

Subsurface Occurrence of Natural Gas Hydrate in the Nankai Trough Area: Implication for Gas Hydrate Concentration

Abstract. The Nankai Trough runs along the Japanese Islands, where extensive BSRs have been recognized in its forearc basins. High resolution seismic surveys and site-survey wells undertaken by the MITI have revealed the gas hydrate distribution at a depth of about 290 mbsf. The MITI Nankai Trough wells were drilled in late 1999 and early 2000. The highlights were successful retrievals of abundant gas hydrate-bearing cores in a variety of sediments from the main hole and the post survey well-2, keeping the cored gas hydrate stable, and the obtaining of continuous well log data in the gas hydrate-dominant intervals from the main hole, the post survey well-1 and the post survey well-3. Gas-hydrate dominant layers were identified at the depth interval from 205 to 268 mbsf. Pore-space hydrate, very small in size, was recognized mostly filling intergranular pores of sandy sediments. Anomalous chloride contents in extracted pore water, core temperature depression, core observations as well as visible gas hydrates confirmed the presence of pore-space hydrates within moderate to thick sand layers. Gas hydrate-bearing sandy strata typically were 10 cm to a meter thick with porosities of about 40 %. Gas hydrate saturations in most hydrate-dominant layers were quite high, up to 90 % pore saturation.
All the gas hydrate-bearing cores were subjected to X-ray CT imagery measurements for observation of undisturbed sedimentary textures and gas-hydrate occurrences before being subjected to other analyses, such as (1) petrophysical properties, (2) biostratigraphy, (3) geochemistry, (4) microbiology and (5) gas hydrate characteristics.     

广东省东部地区的S波速度结构

利用广东省数字遥测台网记录到的2000年11月16日发生在所罗门群岛的两次Ms7．7和Ms7．8地震及2000年11月18日新爱尔兰地区的Ms7．3地震面波波形数据，测定了在广东地区汕头和韶关之间路径上的相速度频散曲线并反演得到了对应的地壳横波速度结构。结果表明该地区的地壳厚度为30km，上地壳横波速度变化较大，中下地壳相对均匀，没有发现地壳内部的低速层。     

Frequency dependence of elastic wave speeds at high temperature: a direct experimental demonstration

At sufficiently high temperatures and/or long periods, the elastic behaviour of crystalline material gives way progressively to viscoelastic behaviour associated with the stress-induced migration of crystal defects. This transition is marked by the onset of appreciable strain energy dissipation accompanied by frequency dependence (dispersion) of the shear modulus and elastic wave speeds. Ultrasonic interferometry and torsional forced-oscillation techniques can be used to probe the low-amplitude stress-strain behaviour of fine-grained polycrystalline material in two very different frequency ranges, respectively 10-100 MHz and 1 mHz-1 Hz. Here we demonstrate and apply these two complementary methods in a study of the high-temperature mechanical behaviour of a fine-grained synthetic olivine polycrystal. At the high frequencies of ultrasonic interferometry, the shear wave speed varies linearly with temperature between room temperature and the highest experimentally accessible temperature (1300 °C) in close accord with expectations based on similarly high-frequency studies of the elastic behaviour of single-crystal olivine. However, at teleseismic frequencies (<1 Hz) and temperatures >900 °C, the shear wave speed becomes much more strongly temperature-sensitive reflecting markedly viscoelastic behaviour. Newly emerging laboratory-derived constraints on this viscoelastic enhancement of the temperature sensitivity of seismic wave speeds and its grain-size dependence will provide a more robust interpretation of seismological models for the variation of wave speeds and attenuation within the Earth's interior.     

Continuous Multi‐probe Measurements in Fastflowing Waters Using a Hydrographic Slot

Taking continuous spatiotemporal in situ measurements with multi‐probes in fast‐flowing waters/rivers can be problematic because the sensors may be damaged by high shear forces and flotsam. To protect the multi‐probe and to enable easy access for the maintenance and calibration of the sensors, a special multi‐probe holder fixed in a hydrographic slot was developed. The validation of the probe system revealed a “memory effect” at short time scales (< 10 s) within sharp gradients caused by the overflow container of the multi‐probe rack keeping the sensors submerged in the sample water. Continuously recorded data (conductivity, temperature, pH, oxygen concentration and saturation, as well as in vivo fluorescence of chlorophyll‐a) from a research cruise on board the RV ALBIS along the river Elbe (river km 309) and entering the river Saale are presented. This river stretch upstream of the city of Magdeburg to the mouth of the Saale tributary was found to have a complex physicochemical character, which is attributable to the long mixing process of water from the river Saale and the river Elbe.     

Structural properties of (Mn1-x Fe x )Nb2O6 columbites from X-ray diffraction and IR spectroscopy

A suite of (Mn_1-x Fe _x )Nb₂O₆ (x=0, 0.05, 0.25, 0.50, 0.75, 1) columbite samples has been prepared by solid-state reaction from oxides. X-ray diffraction and spectroscopic investigations have been carried out in order to gain different perspectives on how the solid solution adapts at different length scales to cation mixing. X-ray powder diffraction and powder absorption IR spectroscopy data are presented. The powder diffraction data show that there is no significant excess volume of mixing on the Fe–Mn columbite join. All the unit-cell parameters decrease linearly as a function of increasing Fe content. Substitution of Fe²⁺ for the larger Mn²⁺ cation causes a decrease in the volume of the A polyhedron, which also becomes more regular with respect to both bond-length and edge-length distortion parameters. No significant variation of the B site has been observed. Wavenumber shifts of the IR peaks nearly all vary linearly with composition, consistent with linear variations of the lattice parameters. Line broadening has been quantified by autocorrelation analysis of the IR spectra. This is interpreted as suggesting that there is some element of local strain or positional disorder at the length scale of second or third nearest neighbours around sites occupied by Fe.     

Estimation of Seasonal Sun-Induced Fluorescence Dynamics of Indian Tropical Deciduous Forests using SCOPE and Sentinel-2 MSI

This paper presents a new approach to estimate spatial Sun-Induced Fluorescence (SIF) using the empirical relationship between simulated Canopy Chlorophyll Concentration (CCC) and simulated SIF. PROSAIL model [PROpriétésSPECTrales (PROSPECT) and Scattering by Arbitrarily Inclined Leaves (SAIL) models] was used to simulate CCC. CCC maps were generated through an Automated Radiative Transfer Model Operator (ARTMO) using the PROSAIL model and Sentinel-2 Multi-Spectral Imager (MSI) imagery. The Soil Canopy Observation, Photochemistry, and Energy fluxes (SCOPE) model was used to simulate SIF emitted at 740 nm (SIF₇₄₀), at 760 nm (SIF₇₆₀), and top of canopy (SIF_TOC) (640-850 nm). The SCOPE model, configured with the specification of the Sentinel-2 sensor, simulates SIF within the spectrum range of 640-850 nm. A non-linear logarithmic relationship (R²>0.9, p < 0.05) was observed between simulated SIF and simulated CCC. Simulated CCC was linearly related to observed CCC with R² 0.88, 0.92 and 0.89 and RMSE = 0.04, 0.17 and 0.09 gm/m² at p < 0.05 for summer, post-monsoon and early winter respectively. Whereas, the simulated CCC did not capture the full range of CCC variability for the post-monsoon season. Simulated SIF (SIF₇₆₀) was well correlated with SIF from Orbiting Carbon Observatory-2 (OCO-2) satellite with R² 0.68, 0.73 and 0.73 (RMSE = <1 W/m²/sr/μm, p < 0.05) for the month of summer (April), pre-monsoon (May) and early winter season (November) respectively. Temporal SIF_TOC effectively captured the seasonal variability associated with the phenology of deciduous tree species. Among various Sentinel-2 MSI derived VIs, Red Edge NDVI (RENDVI) exhibited maximum sensitivity with SIF (highest monthly average R²> 0.6, p < 0.05). The spatial SIF would serve as an useful link between airborne /satellite derived SIF and in-situ fluorescence measurements to understand multiscale SIF variability of terrestrial vegetation.     

泡沫塑料吸附分离富集-电感耦合等离子体质谱法测定稀土矿石中的镓

采用电感耦合等离子体质谱法(ICP-MS)测定稀土矿石中的镓,高含量的稀土元素会造成严重的质谱干扰。本文采用聚氨酯泡沫塑料在6 mol/L盐酸介质中吸附样品溶液中的镓后,以0.5 mol/L氯化铵水浴加热解脱30 min,镓的吸附-解脱效率超过99%,稀土元素等干扰物质基本不进入解脱液中,即在富集镓的同时实现了镓与基体元素的高效分离,降低了质谱干扰。本方法检出限低(0.022μg/g),经土壤及水系沉积物标准物质验证,镓的测定值与标准值吻合(绝对偏差为0.38%~4.70%),实际稀土矿石样品的加标回收率为94.1%~100.6%,精密度(RSD)低于4%(n=12),可应用于分析一般地质样品以及稀土矿石中的镓。