云南茶树林铅锌矿电磁波找矿效果

茶树林铅锌矿，过去认为震旦系赋矿，钻探验证未见矿。本次利用物探方法实施深部探矿。依据物探异常，结合地质规律综合分析，认为是构造控矿。布置验证坑道，沿断裂破碎带发现新的厚大、品位高铅锌矿体，收到良好的找矿效果。     

滇南新元古代的岩浆作用：来自瑶山群深变质岩SHRIMP锆石 U-Pb年代学证据

滇南瑶山—哀牢山地区出露一套呈NW—SE向狭长条带状展布的深变质岩系——下元古界瑶山群和哀牢山群,并认为存在前寒武纪的结晶基底。本文选取瑶山群眼球状花岗质糜棱岩和金平阿得博的片麻状花岗岩作为研究对象,进行SHRIMP锆石U-Pb定年。结合阴极发光图像,获得岩浆锆石的结晶年龄为828±6.2Ma(N=11,MSWD=1.8)和748～801Ma。同时,作者在墨江-元江剖面的哀牢山群黑云母花岗闪长质片麻岩中获得SHRIMP锆石核部U-Pb年龄为769～893Ma。研究揭示滇南的瑶山和哀牢山地区存在新元古代岩浆作用。瑶山群中古老残余锆石核部的984Ma年龄和哀牢山群中古老残余锆石核部年龄1104～1353Ma及2655Ma,表明该区存在中元古代或太古代的结晶基底,研究区很可能位于南华裂谷与康滇裂谷的交汇部位,新元古代的岩浆活动可能与Rodinia超大陆聚合——裂解过程有关。这为构筑Rodinia超大陆聚散过程和揭示华南大地构造演化史提供年代学方面证据。     

Dissolved inorganic carbon evolution in neutral discharge from mine tailings piles

We measured the concentrations of dissolved inorganic carbon (DIC) and major ions and the stable carbon isotope ratios of DIC (δ¹³C_DIC) in two creeks discharging from carbonate‐rich sulphide‐containing mine tailings piles. Our aim was to assess downstream carbon evolution of the tailings discharge as it interacted with the atmosphere. The discharge had pH of 6.5–8.1 and was saturated with respect to carbonates. Over the reach of one creek, the DIC concentrations decreased by 1.1 mmol C/l and δ¹³C_DIC increased by ~4.0‰ 200 m from the seep source. The decrease in the DIC concentrations was concomitant with decreases in the partial pressure of CO_2(aq) because of the loss of excess CO_2(aq) from the discharge. The corresponding enrichment in the δ¹³C_DIC is because of kinetic isotope fractionation accompanying the loss of CO_2(g). Over the reach of the other creek, there was no significant decrease in the DIC concentrations or notable changes in the δ¹³C_DIC. The insignificant change in the DIC concentrations and the δ¹³C_DIC is because the first water sample was collected 160 m away from the discharge seep, not accessible during this research. In this case, most of the excess CO_2(aq) was lost before our first sampling station. Our results indicate that neutral discharges from tailings piles quickly lose excess CO_2(aq) to the atmosphere and the DIC becomes enrich in ¹³C. We suggest that a significant amount of carbon cycling in neutral discharges from tailings piles occur close to the locations where the discharge seeps to the surface. Copyright © 2015 John Wiley & Sons, Ltd.     

大别造山带白垩纪花岗岩对太古宙基底的再造:来自U-Pb年代学、Sr-Nd-Hf同位素的证据

本文对大别造山带大崎山花岗岩进行了系统的野外调查、岩石学、地球化学、锆石U- Pb- Hf和Sr- Nd同位素研究。锆石U- Pb定年结果显示大崎山花岗岩形成于早白垩世,年龄为124~120 Ma。样品具有较高的SiO2(69. 3%~75. 2%)、Al2O3(13. 4%~15. 3%)和全碱(7. 94%~8. 71%)含量,较低的MgO(0. 23%~0. 84%)、TiO2(0. 16%~0. 49%)与TFeO(1. 05%~2. 66%)含量,A/CNK=1. 01~1. 03,显示弱过铝质特征。岩石富集大离子亲石元素(如Rb、K、Pb)、轻稀土元素以及Th、U等,亏损高场强元素(如Nb、Ta、Ti)、重稀土元素以及Sr和Ba,具有明显Eu负异常(δEu=0. 34~0. 52),属于高钾钙碱性的I型花岗岩,这些地球化学特征表明大崎山花岗岩经历了以斜长石、钾长石和磷灰石为主的分离结晶作用。白垩纪锆石εHf(t)值为〖CD*2/3〗32. 9~〖CD*2/3〗15. 2,对应tDM2为3258~2140 Ma,全岩εNd(t)为〖CD*2/3〗22. 5~〖CD*2/3〗15. 8,对应tDM2=2754~2209 Ma,指示岩浆源区主要为古老地壳物质。样品中含有大量的~2. 65 Ga继承锆石,锆石εHf(t)为〖CD*2/3〗7. 3~3. 6,显示与贾庙地区2. 65~2. 63 Ga片麻状花岗岩有良好的亲缘性。大崎山花岗岩可能源自北大别变质带太古宙基底的再造,其源区还存在年轻地壳物质的参与,可能形成于古太平洋板块的俯冲板片在130 Ma后快速后撤的伸展背景。     

蚌埠隆起区古元古代钾长花岗岩的成因:岩石地球化学、锆石U-Pb年代学与Hf同位素的制约

对蚌埠隆起区庄子里和磨盘山钾长花岗岩进行了系统的年代学和地球化学以及锆石Hf同位素的研究, 以便对其岩石成因进行约束.研究结果表明, 庄子里和磨盘山钾长花岗岩中锆石发育震荡生长环带, 且具有较高的Th/U比值(0.13~1.47), 反映了岩浆成因特征.对庄子里和磨盘山钾长花岗岩中岩浆锆石进行的LA-ICP-MSU-Pb定年结果(上交点年龄) 分别为2104±20Ma和2196±190Ma, 这表明蚌埠隆起区钾长花岗岩的形成时代为古元古代.钾长花岗岩的SiO₂和K₂O含量分别介于69.65%~77.95%和4.98%~5.17%之间; 该类岩石富集轻稀土元素和Zr、Hf、Rb、Th、U等元素, 明显亏损Ba、Sr、Eu、P和Ti等元素; 它们的ε_Nd(t) 值变化于-3.4~+3.2之间, Nd的模式年龄变化于2.31~2.79Ga之间; 钾长花岗岩中锆石的ε_Hf(t) 值和Hf同位素两阶段模式年龄分别介于-5.1~+7.8和2.26~2.83Ga之间.上述特征表明, 蚌埠隆起区钾长花岗岩的原始岩浆起源于有少量古老地壳物质涉入的新生下地壳的部分熔融.庄子里和磨盘山钾长花岗岩为A型花岗岩, 形成于伸展的构造背景.      

Composition and origin of the volatile components released from the Pesyanoe aubrite by stepwise crushing and heating

Aubrites are achondritic meteorites (enstatite pyroxenites) that were formed in highly reduced magmatic environments on a differentiated parent body sharing a common oxygen isotope reservoir with enstatite chondrites (EC), Earth and Moon, and could be considered as a geochemical model of the early proto-Earth. Some pyroxenes of the Pesyanoe aubrite have high abundance of gaseous inclusions, captured during the crystallization of the rocks. Investigation of the inclusions by IR spectroscopy reveals presence of OH⁻ groups and C–H bonds. The former are assigned to protonated point defects in enstatite lattice and the latter to compounds occupying void walls. Molecular water and CO₂ were not observed. Volatile components released from the samples of the Pesyanoe enstatite by stepwise crushing and heating are composed of CO₂, H₂O and a non-condensable phase. Hydrogen isotopic composition of volatiles extracted in form of molecular water in Px-separates varies in the range δD = −61 – −84‰ with mean value of δD = −73 ± 16‰ VSMOW and is within the ranges of ECs and Earth’s mantle. The total abundance of H₂ in the pyroxene of Pesyanoe were estimated as at least 0.047 ppm that is too low in comparison with that of enstatite chondrites (≥30 ppm H₂) and could indicate nearly complete degassing of the Pesyanoe primitive precursor material during the Pesyanoe parent body accretion or a mantle degassing in igneous differentiation process. In a last case a primitive precursor could have D/H ratio different from that of enstatite chondrites.     

东昆仑东段三叠纪岩浆岩Nd–Hf同位素组分特征、物源演变规律及其构造背景

作为中央造山系西段的重要组成部分,东昆仑造山带以大面积区域性展布的三叠纪岩浆岩为鲜明特色。依据收集的东昆仑东段三叠纪岩浆岩96件锆石U–Pb年代学数据,限定三叠纪岩浆作用时间为252～212 Ma。结合岩石组合,将其进一步划分为早（252～238 Ma）、中（238～226 Ma）、晚（226～212 Ma）3期,其中岩浆活动峰值为早期（252～238 Ma）。Nd同位素数据（106件）统计结果表明：东昆仑东段三叠纪岩浆岩εNd(t)值为–9.4～–1.7,大多为–6.5～–3.0;Nd模式年龄TDM(Nd)为0.72～1.88 Ga,大多为1.00～1.80 Ga。Hf同位素数据（全岩、锆石;41件）统计结果表明：东昆仑东段三叠纪岩浆岩εHf(t)值变化较大（–8.4～+12.4）,主要为–4.5～+2.0;地壳模式年龄TDMC(Hf)值为0.49～ 1.80 Ga,大多为1.15～1.55 Ga。整体而言,三叠纪岩浆岩物源以中元古代壳源物质的再造为主,新生地壳（＜1.0 Ga）和古元古代地壳有所参与,但比例小。从岩浆活动早期（252～238 Ma）到中期（238～226 Ma）再到晚期（226～212 Ma）,εNd(t)值在岩浆活动早期（特别是在早三叠世）较高,正的εHf(t)值占据很大比例,物源中存在较多的新生物质;中期以较低的εNd(t)值和负的εHf(t)值为主,Hf模式年龄显示出现古元古代物质;晚期Nd–Hf模式年龄揭示较古老的壳源组分增多。这种岩浆岩物源演变趋势,与东昆仑东段三叠纪具俯冲到同碰撞再到碰撞后的构造演化背景一致。     

安徽金寨银水寺铅锌矿床流体包裹体和同位素地球化学特征

银水寺铅锌矿床位于大别造山带北缘,是该区最大的矽卡岩型矿床。矿体主要发育在中元古界庐镇关岩群仙人冲组大理岩与郑堂子组千枚岩之间的层间破碎带以及正长花岗斑岩与大理岩的接触带中。矿床先后经历了四个成矿阶段,矽卡岩阶段(Ⅰ)、石英.白钨矿阶段(Ⅱ)、石英.硫化物阶段(Ⅲ)、碳酸盐阶段(Ⅳ)。矽卡岩阶段(Ⅰ)主要发育绿帘石、阳起石、石英、绿泥石、磁铁矿及少量金属硫化物等;石英.白钨矿阶段(Ⅱ)主要发育石英、方解石、萤石及少量白钨矿和金属硫化物;石英.硫化物阶段(Ⅲ)广泛发育闪锌矿、方铅矿、黄铜矿等金属硫化物及石英、方解石、萤石、绿泥石等;碳酸盐阶段(Ⅳ)主要发育方解石、石英及少量黄铁矿。矿床中发育三种类型流体包裹体,包括富CO2水溶液包裹体(AC类)、气液两相水溶液包裹体(L类)和含子晶多相包裹体(S型)。根据流体包裹体岩相学、显微测温、激光拉曼研究结果,矽卡岩阶段主要有富CO2包裹体和气液两相水溶液包裹体,均一温度为314~400℃、盐度变化范围较大(1.1%~19.3%NaCleqv);石英.白钨矿阶段发育气液两相水溶液包裹体、含子晶多相包裹体和富CO2包裹体,后两者均一温度相近(263~349℃)、盐度差异较大(32.8%~41%NaCleqv和0.8%~6.1%NaCleqv),表明流体发生了沸腾作用;石英.硫化物阶段主要发育气液两相水溶液包裹体,均一温度为230~332℃,盐度为0.2%~8.9%NaCleqv;碳酸盐阶段只发育气液两相水溶液包裹体,显示低温(162~245℃)、低盐度(0.2%~5.6%NaCleqv)的特征。矿床不同成矿阶段石英、绿帘石中流体包裹体中水H-O同位素研究结果表明,δ18Ofluid值从早到晚逐渐减小,其中矽卡岩阶段为–1.3‰~4.7‰、石英.硫化物阶段为–5.1‰~–3.1‰,表明银水寺矿床早期成矿流体主要为岩浆来源,并在成矿过程中不断有大气降水的加入。石英流体包裹体中CO2的C同位素测试结果表明,矽卡岩阶段δ13CV-PDB值为–9.2‰,石英.硫化物阶段为–25.8‰~–15.4‰,表明早期成矿流体中碳质主要来自岩浆,石英-硫化物阶段有大量有机碳加入,其可能与流体和富含有机质的地层反应有关。矿石中主要金属硫化物的δ34S值(1.7‰~4.4‰)显示了深源硫的特征。Pb同位素变化范围集中(206Pb/204Pb=16.55~16.705,207Pb/204Pb=15.369~15.459,208Pb/204Pb=37.463~37.767),显示壳幔混源的特点。随着成矿作用的进行,岩浆流体与碳酸盐围岩地层发生水岩交代反应形成矽卡岩,该过程造成了成矿矽卡岩阶段磁铁矿和少量闪锌矿的沉淀;断裂活动造成热液体系压力下降,流体发生沸腾,CO2、HF进入气相并逃逸促使矿床中钨的沉淀;同时大气降水沿裂隙灌入,混合作用导致流体的温度、盐度降低,Cl–浓度下降,造成矿床中铅锌的大面积沉淀。     

Geochemical Constraints on the Origin of Volcanic Rocks from the Andean Northern Volcanic Zone, Ecuador

Whole-rock geochemical data on basaltic to rhyolitic samplesfrom 12 volcanic centers are used to constrain the role of continentalcrust in the genesis of magmas formed beneath the anomalouslywide subduction-related volcanic arc in Ecuador. Relativelyhomogeneous, mantle-like, isotopic compositions across the arcimply that the parental magmas in Ecuador were produced largelywithin the mantle wedge above the subduction zone and not byextensive melting of crustal rocks similar to those upon whichthe volcanoes were built. Cross-arc changes in ¹⁴³Nd/¹⁴⁴Nd and7/4Pb are interpreted to result from assimilation of geochemicallymature continental crust, especially in the main arc area, 330–360km from the trench. Mixing calculations limit the quantity ofassimilated crust to less than 10%. Most andesites and dacitesin Ecuador have adakite-like trace element characteristics (e.g.Y <18 ppm, Yb <2 ppm, La/Yb >20, Sr/Y >40). Availablewhole-rock data do not provide a clear basis for distinguishingbetween slab-melting and deep crustal fractionation models forthe genesis of Ecuador adakites; published data highlightinggeochemical evolution within individual volcanoes, and in magmaticrocks produced throughout Ecuador since the Eocene, appear tosupport the deep fractionation model for the genesis of mostevolved Ecuadoran lavas. A subset of andesites, which displaya combination of high Sr (>900 ppm), Nd >4·1 and7/4Pb <6·0, appear to be the best candidates amongEcuador lavas for slab-melts associated with the subductionof the relatively young, over-thickened, oceanic crust of theCarnegie Ridge. KEY WORDS: andesite; Ecuador; trace elements; isotopes; adakite     

东昆仑东段到木提岩体成因及构造意义：来自年代学及地球化学的约束

到木提岩体位于东昆仑造山带东段,主要岩性有二长花岗岩、花岗闪长岩及闪长岩。笔者对新发现的闪长岩进行了锆石U–Pb测年和岩石地球化学测试,以确定其形成时代及岩石成因,结合二长花岗岩和花岗闪长岩的岩石地球化学特征,综合探讨到木提岩体的侵位时代、岩石成因及构造演化程。LA–ICP–MS锆石U–Pb测年获得的闪长岩206Pb/238U年龄为（244.6±1.8）Ma,到木提闪长岩体结晶时代为早三叠世。二长花岗岩和花岗闪长岩的地球化学特征显示：里特曼指数小于3.3,具钙碱性–高钾钙碱性特征;铝饱和指数A/CNK值均小于1.1;岩石中P2O5含量普遍较低,且与SiO2含量呈负相关性;富集K、Rb、La等LILE,亏损Nb、Ta、Ti、P等HFSE。地球化学特征表明,到木提岩体属于I型花岗岩。综合分析认为,东昆仑东段到木提岩体是下地壳岩石发生部分熔融形成的火山弧花岗岩,阿尼玛卿洋俯冲作用可以持续到早—中三叠世,俯冲过程中形成区域性的地幔岩浆底侵就是导致下地壳熔融的热源,且幔源岩浆不同程度混入到到木提岩浆演化中,岩浆演化中伴有一定的结晶分异发生。