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31.
Aromatic hydrocarbons from benzene extracts of New Albany Shale were characterized. A biomarker that has a molecular weight of 546 and a structural configuration consistent with that of an alkyl-aromatic hydrocarbon (C40H66) was tentatively identified. It was found that the relative concentrations of the biomarker are indicative of differing levels of thermal maturity of the shale organic matter. A 40-carbon bicyclic carotenoid (C40H48) is proposed as the geochemical precursor of this biomarker. Thermal maturity of the shale organic matter can also be differentiated by observing differences in “fingerprints” as obtained by field-ionization mass spectrometry on the aromatic hydrocarbon fraction. Using this technique, we found that the more mature shale samples from southeastern Illinois contain more low molecular weight extractable aromatic hydrocarbons and the less mature shale samples from northwestern Illinois contain more high molecular weight extractable aromatic hydrocarbons. It was demonstrated that field-ionization and tandem mass spectrometric techniques through fingerprint and individual compound identification, are useful for shale aromatic hydrocarbon fraction characterization and for thermal maturation interpretation. 相似文献
32.
Immature Torbanite and the resistant biopolymer (PRB A) isolated from extant B. braunii were previously compared using bulk spectroscopic methods. In the present work, analysis of 400°C pyrolysis products and pyrolysis residues provided further information on their structure and possible relationships. It appears that such polymers are based upon unbranched, saturated, cross-linked hydrocarbon chains up to C31. In addition to these bridging structures, a substantial part of the alkyl chains is singly bound, as esters of unbranched, saturated or cis unsaturated, even fatty acids. These esters are sterically protected, against chemical degradations, by the network of the bioand geopolymer.Quantitative and qualitative observations derived from 400°C pyrolysis confirm that the chemical structure of PRB A and immature Torbanite are closely related. The pyrolysis residues show a similar evolution and numerous common features are noted, with respect to the nature and the distribution of the major constituents of the pyrolysates (hydrocarbons and fatty acids). Accordingly, Botryococcus provides what seems to be the first example of a close structural relationship between a biopolymer produced in large amounts by an extant alga and the geopolymer of an immature kerogen. The essential role of PRB A in Torbanite formation is ascertained. Moreover, it is found that the resistant biopolymer does not undergo important structural changes during the first stages of diagenesis. Thus, owing to steric protection, the esters of immature Torbanite show a distribution quite close to the one of PRB A esters, with exclusively even constituents and a large contribution of unsaturated acids.Recent observations pointed to the possible genesis of some algal kerogens principally by selective preservation of resistant macromolecules. Such a type of formation is clearly predominant in Torbanite, where the bulk of the fossil organic matter corresponds to a selectively preserved and weakly altered, resistant biopolymer, while incorporation of lipids into the kerogen structure during diagenesis seems to play a minor role. 相似文献
33.
34.
Hydrocarbons in surface sediments from the Changjiang (Yangtze River) Estuary, East China Sea 总被引:9,自引:0,他引:9
Sedimentary aliphatic (AH) and polycyclic aromatic hydrocarbons (PAHs) were studied in the Changjiang Estuary and the adjacent East China Sea. Total AH ranged from 2.20 to 11.82 μg g−1 and consisted of n-alkanes and a dominant petroleum-related unresolved complex mixture (UCM). Within the n-alkanes, terrestrial plant wax compounds prevailed at nearly all stations. Of the PAHs, biogenic perylene dominated at stations receiving riverine inputs. Anthropogenic PAHs originating from combustion/pyrolysis processes varied from 17 to 157 ng g−1, while fossil PAH concentrations ranged from 42 to 187 ng g−1. Both biogenic and anthropogenic hydrocarbons are primarily derived from riverine discharges and accumulate at shallow-water stations. Distinct phase associations lead, nevertheless, to different sedimentation patterns. Fossil PAHs are enhanced at offshore stations where they are introduced directly by shipping activities. Biomarker fingerprints ascribe their source to Chinese crude oils. The overall levels of anthropogenic hydrocarbons are low compared to relevant areas worldwide and reveal a low/moderate level of hydrocarbon pollution. 相似文献
35.
Polycyclic aromatic hydrocarbons and their molecular diagnostic ratios in urban atmospheric respirable particulate matter 总被引:2,自引:5,他引:2
María del Rosario Sienra Nelson G. Rosazza Margarita Prndez 《Atmospheric Research》2005,75(4):267-281
Atmospheric concentrations of polycyclic aromatic hydrocarbons (PAHs) in Santiago de Chile city were evaluated to study particulate PAHs profiles during cold and spring weather periods. Urban atmospheric particulate matter PM10 was collected using High Volume PM10 samplers. Fifteen samples of 24 h during austral winter and 20 samples of 24 h during spring, 2000 were collected at two sampling sites (North–East and Central areas of the city) whose characteristics were representative of the prevailing conditions. Seventeen PAHs were quantified and total PAHs concentration ranged from 1.39 to 59.98 ng m−3, with a seasonal variation (winter vs. spring ratio) from 0.5 to 12.6 ng m−3. Molecular diagnostic ratios were used to characterize and identify PAHs emission sources such as combustion and biogenic emissions. Results showed that the major sources of respirable organic aerosol PM10 in Santiago are mobile and stationary ones. 相似文献
36.
南岭山地湖泊多环芳烃的大气沉降历史记录 总被引:1,自引:0,他引:1
高大山脉对大气环流具有阻挡或屏障作用.通过分析测定南岭山地湖泊沉积物中多环芳烃(PAHs)的垂直分布,结合210Pb定年,探讨了大气PAHs污染在南岭山地的沉积历史.结果显示,沉积物中的PAHs主要以低环数化合物为主,其中尤以菲的含量为最高.在剖面深度0~28 cm范围内,总多环芳烃的含量范围为86~778 ng/g.自1970年开始,PAHs含量持续增加,其中20世纪80、90年代中后期PAHs含量略有降低;在2000年后,沉积柱中的PAHs含量呈急剧增加之势态.多环芳烃在大气迁移过程中发生了组成分异,沉积物中相对富集轻组分(低环数)PAHs,与颗粒物结合的大气干湿沉降是PAHs向偏远山地积的主要途径. 相似文献
37.
大兴安岭摩天岭雨养泥炭沼泽多环芳烃分布特征与来源分析 总被引:3,自引:0,他引:3
运用气相色谱—质谱(GC-MS)技术对大兴安岭摩天岭(47°22′23″N,120°38′45″E)雨养泥炭沼泽泥炭柱中的多环芳烃(PAHs)污染物进行了分析。结果表明,研究区雨养泥炭沼泽表层PAHs总含量的质量比为1 874.4 ng/g,与国内外雨养泥炭沼泽表层相比,其污染水平相对较高。由于研究区气候冷湿,雨养泥炭沼泽中的有机质腐殖化程度较低,有机碳含量较高,这和其PAHs含量的相关性较小。研究区样品中检测出的PAHs主要以2~3环的多环芳烃为主;由PAHs分子标志物指标分析结果可知,研究区雨养泥炭沼泽PAHs污染物的主要来源是当地森林火灾与大气远距离沉降;沉降的PAHs污染物是原油开采、石油生产和化石燃料燃烧的共同贡献。在距地表15~34 cm处,柱状剖面层的PAHs含量显著增加,这是由于1987年和1998年大兴安岭发生森林火灾树木燃烧所致。 相似文献
38.
天津地区典型土壤剖面饱和烃分布特征 及环境意义 总被引:2,自引:0,他引:2
分析了天津地区不同环境功能区7 条土壤剖面中饱和烃含量、组成及部分地球化学参数 的变化规律, 比较了不同土壤剖面饱和烃在纵向上的变化特征。结果表明, 市区( 南开区) 及近郊 区( 武清区, 北辰区和宁河县交界处) 表层土饱和烃含量最高, 其他剖面含量较低; 随深度增大, 饱 和烃含量均有所降低, 但不同剖面变化幅度不同, 表层含量较高的剖面随深度增大, 饱和烃含量 降低幅度较大, 反之则较小。根据部分典型地球化学参数的纵向变化特征, 推测表层土壤饱和烃 主要为石油源和植物源的混合源, 且市区和郊区主要受石油源控制。不同土壤剖面表层土污染源 存在差别。同一剖面表层土壤( <30cm) 不同层次的样品的饱和烃污染源较为接近; 剖面深部( > 30cm) 不同层次样品中正构烷烃不同于表层, 且成因复杂, 既受来源于土壤中有机质降解产物的 影响, 又受表层土中饱和烃纵向迁移作用的影响。对于甾、萜类化合物, 表层土壤中饱和烃含量较 高的剖面, 深层土壤受表层土壤甾、萜类污染物迁移作用的影响; 表层土壤中饱和烃含量较低的 剖面, 深层土壤受表层土壤甾、萜类污染物影响较小。 相似文献
39.
沉积有机质激光热裂解色谱质谱探针分析技术的尝试及其前景探讨 总被引:1,自引:1,他引:1
激光热裂解-色谱-质谱分析方法具有从技术层面上融合分子地球化学方法和有机岩石学方法的潜能。通过抚顺煤镜质组分和树脂体的研究实例,介绍了激光热裂解-色谱-质谱探针分析的基本原理及测试方法。抚顺煤显微组分的微区热裂解产物特征中,镜质组和树脂体热解产物的正烷烃、烷基萘和四氢化萘的总体面貌相似,但树脂体中正烷烃含量较低,而烷基四氢化萘明显较高,这可能反映显微组分形成过程中发生过低分子烃类在各显微组分之间的混合作用。除此之外,还把激光热裂解-色谱-质谱探针技术与传统的分子地球化学方法、有机岩石学方法进行比较。探讨了激光热裂解-色谱-质谱探针技术的应用前景以及尚待解决的技术问题。落射到样品表面的激光束能量(温度)和控制和激光辐射时间的,激光束斑大小、热解产物量、色谱-质谱检验灵敏度极限三者关系等,都是限制新技术应用的技术问题。 相似文献
40.
鼎湖山自然保护区大气气溶胶中的PAHs 总被引:6,自引:2,他引:6
多环芳烃(PAHs)是环境中分布广泛、危害人类健康的有机化合物,通过对鼎湖山自然保护区自然地理和大气气溶胶中苯并(a)芘分析认为,春季样品中大气气溶胶中PAHs主要来源于高等植物排放,夏季来源于珠江三角洲经济区化石燃烧排放。 相似文献