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71.
T. Masuda S. Nakayama N. Kimura K. Onodera A. Okamoto 《Journal of Structural Geology》2004,26(12):2203-2209
A rare metachert pebble containing amphibole grains with microboudin structures in a wide range of orientations provides an opportunity to perform stress analysis in two orthogonal orientations on the foliation surface. The sample was analysed by the microboudin method to infer the triaxial stress state during microboudinage. Stress parameters proportional to the far-field differential stress were determined for sodic amphibole grains in the two orientations. The ratio of the stresses in the two orthogonal orientations (σ1−σ2)/(σ1−σ3) was calculated to be 0.64, indicating that σ2 lies closer to the midpoint between σ1 and σ3 than to σ3. 相似文献
72.
适用于大旋转角的三维基准转换的一种简便模型 总被引:33,自引:0,他引:33
基于大角度的空间直角坐标转换,提出了以方向余弦为参数、适用于任何角度旋转的空间直角坐标转换的简明计算方法。 相似文献
73.
石墨炉原子吸收光谱法测定土壤样品中镉 总被引:5,自引:0,他引:5
采用磷酸氢二铵作基体改进剂塞曼扣背景石墨炉原子吸收光谱法测定土壤样品中镉,方法检出限DL=0.012μg/g,精密度RSD在3.55%~7.33%,满足了土壤样品中镉测定的镉质量要求。 相似文献
74.
75.
Sandro Fadda 《Geostandards and Geoanalytical Research》2005,29(1):143-156
Major concentrations of Al2O3, Fe2O3, MgO, CaO, Na2O and K2O, minor levels of TiO2, P2O5 and thirty petrologically, geochemically and environmentally significant trace elements have been determined in microwave oven acid leachates of whole powdered coal samples by direct current plasma‐atomic emission spectrometry (DCP‐AES). A single sample preparation procedure was suitable for all the determinations with no additional dilution step for major elements solution. Dried samples (0.5 g) were treated in low‐pressure PFA digestion vessels with HF/HCl/HNO3/HClO4 acids to quantitatively extract the analytes from the bulk material, while leaving the major part of organic matrix as a residue. The major constituents of geological samples, in particular the easily ionised elements (EIEs) such as alkali and alkaline earths, may complicate the instrumental determinations in DCP‐AES because of differential enhancements of elemental emission intensities and stray light interferences. Taking account of these factors, the coal matrix is considered to have very low major oxide totals as compared to many other common geo‐environmental and related materials (rocks, sediments, soil, ashes etc.). The sample size employed here, while yielding a relatively concentrated solution to cover a wide range of elemental determinations, provided a sample matrix that significantly diminished interferences for DCP measurements. The need for closely matching the unknowns and calibrators was eliminated except for overall acidity and an excess quantity of caesium for EIE buffering. Calibration of the spectrometer was accomplished by simple aqueous single element solutions as high concentration calibrators in addition to a reagent blank as a low concentration calibrator. Two point working curves were established to allow for the maximum concentrations of each element expected in the unknowns. The precision of determinations under routine conditions as well as the reproducibility of the leaching and precision of instrumental measurements have been evaluated. Relative standard deviations (RSD) were of 1–2% for those elements whose concentrations in solid samples were well above the limits of quantification. Method detection limits in the buffered solutions were also evaluated. To evaluate the accuracy of the microwave oven‐DCP method a suite of eight certified coal reference materials of differing rank, were analysed with good agreement with the certified and/or available published data. Results are presented for the uncertified major oxides in the AR series reference materials. 相似文献
76.
Mineralogy and geochemistry of a Late Permian coal in the Dafang Coalfield, Guizhou, China: influence from siliceous and iron-rich calcic hydrothermal fluids 总被引:16,自引:2,他引:16
Shifeng Dai Chen-Lin Chou Mei Yue Kunli Luo Deyi Ren 《International Journal of Coal Geology》2005,61(3-4):241-258
This paper describes the influence of siliceous and iron-rich calcic low-temperature hydrothermal fluids (LTHF) on the mineralogy and geochemistry of the Late Permian No. 11 Coal (anthracitic, Rr=2.85%) in the Dafang Coalfield in northwestern Guizhou Province, China. The No. 11 Coal has high contents of vein ankerite (10.2 vol.%) and vein quartz (11.4 vol.%), with formation temperatures of 85 and 180 °C, respectively, indicating that vein ankerite and vein quartz were derived from low-temperature calcic and siliceous hydrothermal fluids in two epigenetic episodes. The vein quartz appears to have formed earlier than vein ankerite did, and at least three distinct stages of ankerite formation with different Ca/Sr and Fe/Mn ratios were observed.The two types of mineral veins are sources of different suites of major and trace metals. Scanning electron microscope and sequential extraction studies show that, in addition to Fe, Mg, and Ca, vein ankerite is the dominant source of Mn, Cu, Ni, Pb, and Zn in the coal, and the contents of these five elements are as high as 0.09% and 74.0, 33.6, 185, and 289 μg/g, respectively. In contrast, vein quartz is the main carrier mineral for platinum-group elements (PGEs) Pd, Pt, and Ir in the coal, and the contents of Pd, Pt, and Ir are 1.57, 0.15, and 0.007 μg/g, respectively. Sequential extraction showed a high PGE content in the silicate fraction, up to 10.4 μg/g Pd, 1.23 μg/g Pt, and 0.05 μg/g Ir, respectively. It is concluded that the formation of ankerite and quartz and the anomalous enrichment of trace elements in the No. 11 Coal in the Dafang Coalfield, Guizhou, result from the influx of calcic and siliceous low-temperature hydrothermal fluids. 相似文献
77.
James C. Hower Cortland F. Eble Jeffrey C. Quick 《International Journal of Coal Geology》2005,62(4):223-236
Mercury emissions from US coal-fired power plants will be regulated by the US Environmental Protection Agency (USEPA) before the end of the decade. Because of this, the control of Hg in coal is important. Control is fundamentally based on the knowledge of the amounts of Hg in mined, beneficiated, and as-fired coal. Eastern Kentucky coals, on a reserve district level, have Hg contents similar to the USA average for coal at mines. Individual coals show greater variation at the bench scale, with Hg enrichment common in the top bench, often associated with enhanced levels of pyritic sulfur. Some of the variation between parts of eastern Kentucky is also based on the position relative to major faults. The Pine Mountain thrust fault appears to be responsible for elemental enrichment, including Hg, in coals on the footwall side of the thrust.Eastern Kentucky coals shipped to power plants in 1999, the year the USEPA requested coal quality information on coal deliveries, indicate that coals shipped from the region have 0.09 ppm Hg, compared to 0.10 ppm for all delivered coals in the USA. On an equal energy basis, and given equal concentrations of Hg, the high volatile bituminous coals from eastern Kentucky would emit less Hg than lower rank coals from other USA regions. 相似文献
78.
A set of Pennsylvanian coals from the North American coal basins, ranging in vitrinite reflectance from 0.65% to 1.75%, was examined, with special emphasis on the optical properties of pseudovitrinite. The results suggest that pseudovitrinite originates from the same material as telocollinite. Slits in the pseudovitrinite seem to have originated in situ due to low-temperature oxidation of woody material; their opening might have been facilitated by devolatilization during coalification. The dominant orientation of the slits is perpendicular to bedding. The intensity and orientation of the slits in pseudovitrinite could be important factors in predicting coalbed gas extraction from coal. 相似文献
79.
对薄壁金刚石钻头胎体进行了性能分析和配方设计探讨,尤其根据被钻切介质对钻头胎体性能的要求作了较详细的分析,从理论分析结合实践经验筛选出了钻切建筑石材和各种钢筋砼的钻头胎体配方,在生产中满足了钻头工作条件的要求。 相似文献
80.
Transient seepage analysis in zoned anisotropic soils based on the scaled boundary finite‐element method 下载免费PDF全文
The scaled boundary finite‐element method, a semi‐analytical computational scheme primarily developed for dynamic stiffness of unbounded domains, is applied to the analysis of unsteady seepage flow problems. This method is based on the finite‐element technology and gains the advantages of the boundary element method as well. Only boundary of the domain is discretized, no fundamental solution is required and singularity problems can be modeled rigorously. Anisotropic and non‐homogeneous materials satisfying similarity are modeled with no additional efforts. In this study, firstly, formulation of the method for the transient seepage flow problems is derived followed by its solution procedures. The accuracy, simplicity and applicability of the method are demonstrated via four numerical examples of transient seepage flow – three of them are available in the literature. Homogenous, non‐homogenous, isotropic and anisotropic material properties are considered to show the versatility of the technique. Excellent agreement with the finite‐element method is observed. The method out‐performs the finite‐element method in modeling singularity points. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献