长江中下游湖泊沉积物铅污染记录——以洪湖、固城湖和太湖为例

2002～2005年在长江中下游的洪湖、固城湖和太湖分别采集了沉积物柱样钻孔,测定了总有机碳（TOC）和金属元素包括Pb,Al,Fe,Ti等,并采用²¹⁰Pb和¹³⁷Cs进行了近代沉积物定年。研究结果表明,洪湖钻孔平均沉积速率为0.15cm/a,固城湖平均沉积速率在0.067cm/a,太湖平均沉积速率为0.35～0.41cm/a。根据湖泊沉积物中铅元素与参考元素（Al,Fe和Ti）浓度和TOC的相关关系建立了回归方程,线性关系极显著（p<0.001）。根据回归方程获取了钻孔中铅的背景值变化,研究表明近代沉积物中金属铅不仅仅来源于自然的作用,而人类活动导致铅的累积发生时间都在20世纪70年代,从一个侧面也说明利用沉积物铅含量变化进行断代存在可能性。对太湖钻孔而言,其污染程度要高于洪湖和固城湖。研究结果表明近30年来洪湖和固城湖人为造成湖泊沉积物铅累积量在不断增加,其沉积物铅污染有进一步加重的趋势,应受到科学家和管理部门的关注。     

基于相关系数匹配的混合像元分解算法

遥感影像中的混合像元不仅影响地物识别和分类的精度,而且已成为遥感科学向定量化发展的主要障碍.为此,人们已经提出了多种混合像元分解算法,其中应用最为广泛的是最小二乘法.该方法虽然具有意义明确、简单易行等特点,但也易受局部噪声、大气效应、环境辐射等因素的影响.本文将混合像元分解问题归结为一个基于光谱匹配的非线性最优化问题,并针对最小二乘法的不足提出了一种新的基于相关系数匹配(spectral correlation matching, SCM)的混合像元分解技术.通过在北京市北三环及其以北区域内案例的研究表明:在城市区域内,利用图像选取终端端元的办法,基于相关系数匹配的混合像元分解算法的总体精度高于带全约束的最小二乘法(LS)的分解结果.对比分析表明:在目标光谱的绝对值整体放大或缩小而光谱形状得到了很好的保持、及局部噪声使得光谱值显著变化但光谱形状得到了一定程度保持时,基于光谱形状的相关系数法可以得到比基于光谱绝对值的最小二乘法精度更高的分解结果.     

MODIS数据自适应火点检测的改进算法

在MODIS火点检测算法基础上提出一种自适应火点检测的改进算法,并对改进算法进行的构建详细描述.改进的算法按照直方图统计来选择进行非火点排除的中红外通道亮温阈值,利用背景像素相对增温法判断疑似火点,提高了火点的识别能力.另外改进算法对云覆盖下的火点也有一定的识别能力.选择中国小火点发生频繁的广东地区进行改进算法的检验,结果表明火点检测效果理想.     

煤中铂族元素赋存的地质研究进展

对煤中铂族元素的质量分数、赋存状态、来源及其异常富集的地质因素等进行了详细的阐述,并提出了今后研究的重点.研究资料表明,煤中不仅普遍含有铂族元素,甚至可以产生异常富集现象;铂族元素常以水溶态、离子交换态、碳酸盐态、有机态、硅铝化合物态、硫化物态等形式赋存于煤中;导致煤中铂族元素异常富集的机理主要有:岩浆热液作用、低温热液作用和同沉积火山灰作用3种.     

汞元素的石油地质意义

油气中都含有汞元素组分,汞的物理化学性质决定其可以从油气藏中向上垂向运移,根据采样介质类型及样品预处理的手段不同,地表中汞的分析方法可分为壤气、热释汞及土壤总汞分析方法。壤气汞、热释汞及土壤总汞指标都有着很好的示油气意义,同时也有着示断裂带的地质意义。     

黔西北威-赫-纳-织-水地区铅锌(铜)矿带上 重力异常反映的地质信息

研究黔西北威宁—赫章—纳雍—织金—水城地区,铅锌(铜)矿带上分布的1∶20万区域重力异常特征,及其与地质、构造、岩体、化探等异常的对应规律及其关系,能对该区此类矿产的成矿规律、成矿部位和成矿特点的研究有所帮助,提出下一步找矿方向上的参考建议。     

Benthic nutrient fluxes in the intertidal flat within the Changjiang （Yangtze River） Estuary

In an annual cycle from March 2005 to February 2006, benthic nutrient fluxes were measured monthly in the Dongtan intertidal flat within the Changjiang （Yangtze River） Estuary. Except for NH4^＋, there always showed high fluxes from overlying water into sediment for other four nutrients. Sediments in the high and middle marshes, covered with halophyte and consisting of macrofauna, demonstrated more capabilities of assimilating nutrients from overlying water than the low marsh. Sampling seasons and nutrient concentrations in the overlying water could both exert significant effects on these fluxes. Additionally, according to the model provided by previous study, denitrification rates, that utilizing NO3- transported from overlying water （Dw） in Dongtan sediments, were estimated to be from -16 to 193 μmol·h^-1·m^-2 with an average value of 63 μmol·h^-1·m^-2 （n=18）. These estimated values are still underestimates of the in-situ rates owing to the lack of consideration of DN, i.e., denitrification supported by the local NO3^- production via nitrification.     

Distribution Characteristics of Sulfur and the Main Harmful Trace Elements in China’s Coal

To promote the rational development and use of clean coal resources in China, data on the regional and age distribution of sulfur, arsenic and other harmful elements in Chinese coal was broadly collected, tested for content, and analyzed. Coal in northwestern China is characterized by low to extremely low levels of sulfur; the coal of the Taiyuan Formation in northern China mainly has high-sulfur content; that of the Shanxi Formation is mainly characterized by low sulfur coal; and the Late Permian coal in southern China has overall higher sulfur content; other regions have low sulfur coal. The average content of harmful trace elements in the bulk of China＇s coal is similar to the corresponding content in the coal of the North America and the rest of the world, whereas the content of various elements （Hg, Sb and Se） is different in magnitude to the corresponding percentage in the crust. The average content of the elements Cr, Se, Co, Be, U, Br in Late Permian coal in S China ranks first in the country whereas the average content of Hg and CI in the coals of Late Carboniferous to Early Permian age in N China are the highest. The average content of Mn in Early and Middle Jurassic coal is higher in NW China. The high content of harmful elements in some coal should cause particular concern both in the development and utilization of coal.     

Multifractal Analysis of Element Distribution in Skarn-type Deposits in the Shizishan Orefield, Tongling Area, Anhui Province, China

A series of element concentrations sampled from four drill cores with a length about 1000 m into different skarn-type deposits were selected from the Shizishan orefield, central Tongling, southeastern part of Anhui Province. Using the multifractal method, the distribution and migration characteristics of the major and trace elements are analyzed. The multifractal spectrum of the major elements is left-skewed, whereas the spectrum of the trace elements is right-skewed, which shows that in the process of skarn formation, the trace elements were enriched only locally, and major elements transported within a much larger range. The correlation coefficients of the multifractal parameters Aa （width of the multifractal spectrum） of the four drill cores are relatively low, but the correlation coefficients of the multifractal parameters R （spectrum symmetry parameter） and Af are relatively higher, indicating that although the non-homogeneous intensity of the distribution of elements is inconsistent, their spatial accumulation patterns are almost the same during the ore-forming process. The statistics of the mnltifractal parameters of various elements in the different locations show that the ore-forming processes and element migration pattern in the Shizishan orefield are consistent, and that the migrations of trace elements and major elements exhibit some differences.     

RBF网络在地质样品非线性基体效应校正中的应用

基于RBF(Radial Basis Function)网络的正交最小平方算法,对攀枝花地质样品进行动态非线性基体效应校正.首先采用EDXRF仪器对样品进行测量,并对样品的荧光计数进行归一化,设计出自动分类模型和动态非线性数据基体效应校正模型的二级串联结构,用自组织神经网络(SOFM)进行分类,然后用RBF网络预测了未知样品元素Ti的百分含量.结果表明:对所预测样本的Ti的百分含量与化学分析相比的误差均小于0.5%.由此可见,用RBF方法可以有效地对地质样品进行非线性基体效应校正,能够达到工矿生产的要求.