Attenuation of aqueous metal transport at two natural acid rock drainage occurrences in the Yukon Territory, Canada

Naturally acidic drainage associated with pyritic black shale has been observed in many locations in the Yukon Territory. While not necessarily linked to known mineral deposits, most of these natural acid rock drainage occurrences show elevated dissolved concentrations of trace elements, especially zinc, nickel, copper, cadmium and arsenic. Based on field observations, microbial investigation, chemical analyses and geochemical modeling, the fate and transport of potentially deleterious elements at two natural acid drainage occurrences with slightly different settings are examined. The Macintosh Creek is a small, acidic stream （pH 2.98-3.40）, 2 km long, located in the Macmillan Pass area of east-central Yukon amidst known sedimentary exhalative massive sulfide mineralization but remains undisturbed by exploration activities. Its trace metal content is apparently derived from groundwater discharges, which gave as much as 5.0, 2.5, 0.7, 0.13 and 0.03 mg/L ofZn, Ni, Cu and As, respectively. Interaction and sorption reactions with algal mats, biofilms and iron oxyhydroxides appear to be the dominant mechanisms attenuating aqueous contaminant transport along the stream. Cryogenic precipitation further consolidates the ferricrete formation and reduces the mobility of the sorbed metals. The tributaries of the Engineering Creek along the Dempster Highway in northern Yukon drain through a series of dolomite, phyllite, argillite, limestone, black shale, sandstone and conglomerate with no known concentration of mineralization. In this area, the water chemistry fully reflects the local geology with acidic streams invariably associated with black shale occurrences. Groundwater seeps in the headwaters area of the km-180 Creek completely enclosed in black shale gave pH 3.0 and as much as 148, 39, 2.9 and 9.1 mg/L of Zn, Ni, Cu and As, respectively. Sorption with iron oxyhydroxide and organic matter appear to dominate the attenuation of contaminant transport along the stream. However, once entered into carbonate-dominated terrains, secondary carbonate minerals exercise additional geochemical control on the local water chemistry as a result of neutralization.     

In situ time resolved synchrotron powder diffraction study of thaumasite

Structural changes during dehydration and subsequent decomposition in thaumasite Ca₃Si(SO₄)(CO₃)(OH)₆·12 H₂O were studied by in situ synchrotron powder diffraction between 303 and 1,098 K. Evolution of the crystal structure was observed through 28 structure refinements, by full profile Rietveld analysis performed in the P6₃ space group, between 300 and 417 K, whereupon the thaumasite structure was observed to breakdown. Within this temperature range, the cell parameters of thaumasite increased as a function of temperature in a nearly linear fashion up to about 393 K, at which temperature, a slight slope change was observed. Above 400 K, the thermogravimetric analysis revealed that the dehydration process proceeded very rapidly while the refined occupancy of water molecules dropped below a critical level, leading to instability in the thaumasite structure. At a same time, a remarkable change in the unit cell parameters occurring at about 417 K indicated that the crystal structure of thaumasite collapsed on losing the crystallization water and it turned amorphous. This result indicated that the dehydration/decomposition of thaumasite was induced by the departure of the crystallization water. At about 950 K, anhydrite and cristobalite crystallized from the thaumasite glass.     

A Connectivity Index for Discrete Fracture Networks

Connectivity is an important measure for assessing flow transport in rock, especially through fractures. In this paper, rock fracture systems are modelled by a discrete fracture model simulated by a marked point process. A connectivity index is then introduced to quantify the connectivity between any two points in space. Monte Carlo simulation is used to evaluate the connectivity index for stationary cases and relationships between the connectivity index and the parameters of the discrete fracture model are analysed. The average number of intersections per fracture, X_f, and the fracture intensity, P12 (P32), are calculated and the relationships between these parameters and the connectivity index are investigated, concluding that X_f is the more suitable parameter for the classification of rock mass flow properties. The relationships between the connectivity index and the percolation state of the fractured medium are also discussed. An edge correction is briefly discussed and a practical example is used to demonstrate the method of computing the connectivity index.     

要十分重视另一类型地质灾害的防治

文章提出另一类型地质灾害,即化学型地质灾害的定义及其分类。并认为化学型地质灾害不像物理型地质灾害那样发生瞬时灾害,而有一个延缓过程,但是一旦发生,难于挽救。化学型地质灾害体的主体是化学元素,开展地球化学调查,研究化学元素的赋存规律、土壤及沉积物承受各类元素的极限、各类元素活化的条件是揭示诱发化学型地质灾害机理的关键。因此要十分重视与加强化学型地质灾害的调查、研究、监测与治理工作。     

遥控飞艇数字航空摄影系统

提出快速获得航空影像并及时制作DOM、DLG的一种手段.介绍遥控飞艇数字摄影系统的工作原理,探讨存在的问题.     

藏南地区金和锑矿床(点)类型及其时空分布特征

本文首次对藏南地区金和锑矿床(点)地质特征、成因类型和空间分布特点进行了总结，对金和锑成矿作用与中新生代构造一岩浆活动的关系进行了论证，对区域地壳演化过程中金和锑成矿动力学机制进行了讨论。该区的金和锑矿床(点)可按容矿围岩划分为：①变质岩为主要容矿围岩矿床(点)，包括金和金一锑矿床(点)；②沉积岩为主要容矿围岩矿床(点)，包括金、锑、金一锑和锑多金属矿床(点)；③火山岩为主要容矿围岩矿床(点)，以金一银矿床为代表。根据金和锑矿床(点)空间分布特点和地质特点，将本区划分为4个矿化集中区：拉昂错一马攸木一帕羊金矿化集中区(A)，然勒金和锑矿化集中区(B)，洛扎一措美锑矿化集中区(C)和邛多江金一锑矿化集中区(D)。各矿化集中区内大多数金和锑矿床(点)与燕山晚期～喜马拉雅早期富碱火成岩具密切时空分布关系，它们是古板块对接碰撞期和碰撞期后大规模构造一岩浆活动的产物。近东西向挤压性和南北向张性断裂交汇部位以及富碱火成岩发育区是寻找金和锑矿床(点)的有利场所。     

内蒙古东胜砂岩型铀矿后生成矿与油气关系

发育于内蒙古鄂尔多斯盆地北部中侏罗统直罗组辫状河相杂砂岩体内的砂岩型铀矿，有一系列较为特殊的与放射性铀成矿有直接或间接关系的成矿地质现象：绿色化蚀变带、漂白退色化带、二次胶结钙化砂岩团块及钙化砂岩断续层与“钙化木”后生蚀变现象；在与铀矿化和与油气的关系认识上存在一定分歧。初步分析了它们的形成、成因及与铀成矿的关系及其找矿意义。     

层次分析法(AHP)在三江平原地质环境质量评价中的应用

应用层次分析法(AHP)对影响三江平原环境地质质量的岩石、土壤和水3个子系统分别进行评价，通过分析影响各子系统的主要因子，建立子系统层次结构模型和质量指数数学模型，得出各子系统的质量指数，从而评价出各个子系统的质量状况。在此基础上，建立地质环境系统质量评价的层次结构模型和数学模型，计算出地质环境质量指数，并对该地区的质量状况进行评价，得出三江地区总体环境地质状况是好的结论。     

黄土坡面侵蚀产沙时空演变的REE示踪技术研究

室内交叉布设不同的稀土氧化物,通过人工模拟次降雨,在同一试验条件下,对坡面侵蚀沿顺坡方向和深度方向的演变过程同时展开研究。结果表明:REE示踪技术对定量研究土壤侵蚀具有较高的精度;降雨前期,片蚀与细沟侵蚀发育程度基本相当;后期细沟侵蚀占据坡面侵蚀的主导地位,其侵蚀平均加速度和平均侵蚀率分别是片蚀的15倍、9倍;试验结束,细沟侵蚀占据坡面总侵蚀的90%;本试验条件下,坡面下1/3区域为侵蚀活跃带。     

中国农业干旱脆弱性分区研究

根据各地水资源的特点、农业受旱成灾的情况及水利设施抗旱能力,确定农业干旱脆弱性分区的原则和指标,构造层次分析模型。应用MapInfo6.0软件绘制了中国农业干旱脆弱性分区图,结果表明:在全国340个农业干旱脆弱性分区中,极严重脆弱区47个,严重脆弱区104个,一般脆弱区175个,轻度脆弱区14个。