智能制造行业分析与诊断方法研究

工业4.0快速发展时代,随着新一代信息技术的不断发展,传统制造业面临着严峻的挑战。为推进制造业高质量发展,智能制造已成为全球主要国家制造业竞争的焦点问题。通过分析开展智能制造诊断的必要性和紧迫性,提出了一种规范化诊断方法以提高企业效益,并针对现阶段智能制造诊断工作中出现的问题,给出了下一步的研究方向。     

从7-ADCA生产过程中环境友好的回收苯乙酸

采用新工艺回收7-氨基-3-脱乙酰氧基头孢烷酸(7-ADCA)生产中产生的苯乙酸,并对苯乙酸回收过程中产生的废硫酸进行处理。采用硫酸(9 8%)洗涤二氯甲烷,硫酸与二氯甲烷适宜的体积比为1∶50,洗涤好的二氯甲烷中含苯乙酸4%。蒸馏出二氯甲烷,趁热向熔融苯乙酸中加入母液,降温析出苯乙酸。晾干的苯乙酸为白色鳞片状,含量大于99%,苯乙酸母液补充部分清水套用到下一批析出苯乙酸。废浓硫酸用芬顿试剂氧化,控制80℃氧化4h,双氧水和七水硫酸亚铁重量比为6∶1,废浓硫酸COD下降85%以上。氧化结束后向废硫酸中加入铁粉和双氧水,制得聚合硫酸铁。     

超高效液相色谱—串联质谱法快速同时检测茶叶中7种香料

基于超高效液相色谱—串联质谱(UHPLC-MS/MS),建立了同时检测茶叶中7种可能非法添加的香料(茴香烯、香豆素、胡椒酚甲醚、指甲花醌、甲基丁香酚、蒲勒酮和反式肉桂醛)的定性、定量方法。茶叶样品经过乙腈—水混合溶剂提取,涡旋振荡,适当稀释并加入无水硫酸钠、十八烷基键合硅胶(C₁₈)和N-丙基乙二胺(PSA)进行净化,涡旋离心后,上清液过膜待测。以Kinetex C₁₈色谱柱分离,在多反应检测扫描(MRM)模式下经MS/MS进行基质外标法定量检测。试验结果表明,7种目标物在0.8~1 600.0 μg/L范围内呈良好线性,线性相关系数(R2)均大于0.999。方法的检出限为0.02~0.03 mg/kg,定量限为0.05~0.10 mg/kg,平均回收率为82.5%~102.5%,日内、日间精密度分别小于16%和18%。该方法快速、可靠、灵敏度高,用于检测市面流通的100个茶叶样品,结果检出了反式茴香脑、香豆素和胡椒酚甲醚等物质,最大浓度值分别为65.0,2.0,72.2 mg/kg。     

某污水处理厂MBR膜系统改造与运行管理

某污水处理厂设计规模为10万t/d,采用AAO+MBR工艺,设计出水水质满足《城镇污水处理厂污染物排放标准》(GB 18918-2002)一级A标准。由于运行时间较长,MBR运行系统存在产能下降、膜丝断丝脱落、污堵和清洗频次以及强度增加等问题,严重影响正常生产运行。针对MBR系统运行中存在的问题,文中提出具体改造建议,并总结运行经验,进一步优化MBR膜系统的运行维护管理,为其他污水厂MBR膜系统运行问题提供解决思路和维护管理经验。     

A dense and compact laser cladding layer with solid metallurgical bonding significantly improved corrosion resistance of Mg alloy for engineering applications

Although Mg alloy attracts great attention for engineering applications because of high specific strength and low density, low corrosion resistance limits its extensive use. In this study, Mg–Al–Zn–Mn alloy was treated via a laser cladding process to generate a dense and compact laser cladding layer with solid metallurgical bonding on the substrate for improving corrosion resistance, effectively hindering the corrosion pervasion into Mg alloy. The corrosion current density declined from 103 μA/cm² for Mg alloy to 13 μA/cm² for the laser cladding layer in NaCl aqueous solution. Moreover, the laser cladding layer was slightly corroded in comparison with Mg alloy in NaCl aqueous solution. Besides, the microhardness of the cladding layer reached a mean value of 170.5 HV, 3.1 times of Mg alloy (56.8 HV) due to the in situ formation of hardening intermetallic phases. Wear resistance of laser cladding layer was also obviously improved. These results demonstrated that the laser cladding layer obviously enhanced anticorrosion property of Mg alloy for engineering applications.     

K4,4,p的点可区别的IE-全染色(p≥1008)

该文利用色集事先分配法、构造染色法、反证法探讨了完全三部图K_4,4,p (p≥1008)的点可区别IE-全染色问题，确定了K_4,4,p (p≥1008)的点可区别IE-全染色数。     

智能变电站设备管控大数据分析系统研究

结合数据挖掘、大数据技术在电力系统中的应用现状，分析和设计了一种智能变电站设备管控大数据分析系统。对变电站设备运行状态的大数据特征及基本框架进行了分析，并重点阐述了变电站设备运行状态大数据分析系统的数据集成与预处理、数据存储与处理、设备状态评估模型以及数据可视化展示。实验结果表明，所设计的大数据分析系统能够大幅度提升变电站设备数据分析智能化水平，为变电站管控稳定运行提供更加有效和实用性的技术支撑。     

FDC在TFT-LCD中的应用案例研究

针对x因子不明确的品质不良,以TFT-LCD某产品不良为例,提出了FDC大数据分析方法。与实际生产过程相结合,经过数据收集和过滤、数据降维和主成分分析过程,找到该品质不良的强相关因子。通过对强关联因子进行DOE实验设计,明确关键因子管控线,提高产品生产力。     

Unveiling the role of Fe3O4in polymer spin valve near Verwey transition

The spinterface formed between ferromagnetic(FM)electrode and organic materials is vital for performance optimization in organic spin valve(OSV).Half-metallic Fe₃O₄with drastic change in structure,conductivity and magnetic property near Verwey transition can serve as an intrinsic spinterface regulator.However,such modulating effect of Fe₃O₄in OSV has not been comprehensively investigated,especially below the Verwey transition temperature(Tv).Here,we highlight the important role of Fe₃O₄electrode in reliable-working and controllable Fe₃O₄/P3HT/Co polymer spin valves by investigating the magnetoresistance(MR)above and below 7V.In order to distinguish between different contributions to charge transport and related MR responses,the systematic electronic and magnetic characterizations were carried out in full temperature range.Particularly,the first-order metal-insulator transition in Fe₃O₄has a dramatic effect on the MR enhancement of polymer spin valves at 7V.Moreover,both the conducting mode transformation and MR line shape modulation could be accomplished across 7V.This research renders unique scenario to multimodal storage by external thermodynamic parameters,and further reveals the importance of spin-dependent interfacial modification in polymer spin valves.