用于矿山等极端环境中的高精度定位算法

高精度室内定位技术在矿山、建筑、施工等多种极端环境下都有需求。基于超宽带通信(Ultra Wideband,UWB)的室内定位技术能够提供较高的定位精度,但超宽带信号易受到障碍物的干扰,并且在类似矿山等极端环境中,障碍物不可避免。因此,超宽带非视线传输(Non-Line-of-Sight,NLoS)测距成为当前的一个研究热点。当前研究大多集中在识别和消除非视线传输对超宽带测距的影响上,实际应用中,大多数情形下超宽带信号根本无法穿透障碍物,会导致定位标签只能够与2个或1个信标节点通信,但完成三边定位至少需要3个信标节点。为此,提出了一种基于目标行为分析的定位算法,该算法能够在短时间内仅剩余一个信标节点与标签通信时,也可实现高精度定位。该算法以超宽带通信为基础,使用信号飞行时间(Time of Flight,TOF)算法测距并定位。通过分析信号正常时的目标运动轨迹来判断其速度和方向,当信号不正常时(可通信的信标节点减少),可利用预测的速度和方向参数来实现辅助定位。将该算法部署在一个基于超宽带定位的系统中进行了测试,结果表明:当能够与标签通信并完成TOF算法的信标节点数量少于3个时,基于NLoS传输识别和消除的算法无法完成定位,而基于目标行为分析的定位算法依然能够实现定位,在单信标节点区域的平均定位误差为0.93 m,最大误差为1.41 m,在2个信标节点测距的区域,平均定位误差为0.64 m,最大误差为1.2 m。     

槽波地震勘探技术在瓦斯富集区探测中的应用研究

为查清糯东煤矿11705工作面内部煤厚变化，并圈出工作面瓦斯治理高风险区域，为工作面安全高效生产提供指导，采用槽波地震透射法对11705工作面进行探测。联合槽波速度解释与能量解释两种方法，辨析透射槽波的质量，将质量差的槽波射线分别绘制在平面图上，采用射线交汇的方法划分工作面的开采风险分布区域。探测成果与实验室中解吸法的瓦斯测定成果进行了对比，结果表明，煤与瓦斯突出矿井槽波速度与瓦斯富集区存在一定相关性，在槽波高速区、波速急剧变化带或高低速相间分布区，瓦斯含量可能较高；被四周高速区所包围的低速区域瓦斯含量较高。上述结论为国内同类型矿井瓦斯富集区探测提供了借鉴。     

煤泥浮选中矿物颗粒间相互作用力的研究进展

煤泥浮选是选煤流程中的一个重要环节,改善煤泥浮选效果是提高煤炭高效洁净利用和企业经济效益的关键,煤泥浮选过程的强化越来越受到选煤行业的重视。论文总结了当前煤泥浮选体系中矿物颗粒间相互作用力的最新研究方法和研究进展,综述了浮选药剂、电解质、矿浆pH值、钙镁离子、机械搅拌、磁化处理、电化学处理、超声波处理以及微生物对矿物颗粒间相互作用力的影响规律及机理,对实现煤泥的高效分选有重要的参考价值。     

Discovery of the Tiancilactone Antibiotics by Genome Mining of Atypical Bacterial Type II Diterpene Synthases

Although genome mining has advanced the identification, discovery, and study of microbial natural products, the discovery of bacterial diterpenoids continues to lag behind. Herein, we report the identification of 66 putative producers of novel bacterial diterpenoids, and the discovery of the tiancilactone (TNL) family of antibiotics, by genome mining of type II diterpene synthases that do not possess the canonical DXDD motif. The TNLs, which are broad‐spectrum antibiotics with moderate activities, are produced by both Streptomyces sp. CB03234 and Streptomyces sp. CB03238 and feature a highly functionalized diterpenoid skeleton that is further decorated with chloroanthranilate and γ‐butyrolactone moieties. Genetic manipulation of the tnl gene cluster resulted in TNL congeners, which provided insights into their biosynthesis and structure–activity relationships. This work highlights the biosynthetic potential that bacteria possess to produce diterpenoids and should inspire continued efforts to discover terpenoid natural products from bacteria.     

Mass-Producible,Quasi-Zero-Strain,Lattice-Water-Rich Inorganic Open-Frameworks for Ultrafast-Charging and Long-Cycling Zinc-Ion Batteries

Low-cost and high-safety aqueous Zn-ion batteries are an exceptionally compelling technology for grid-scale energy storage. However, their development has been plagued by the lack of stable cathode materials allowing fast Zn²⁺-ion insertion and scalable synthesis. Here, a lattice-water-rich, inorganic-open-framework (IOF) phosphovanadate cathode, which is mass-producible and delivers high capacity (228 mAh g⁻¹) and energy density (193.8 Wh kg⁻¹ or 513 Wh L⁻¹), is reported. The abundant lattice waters functioning as a “charge shield” enable a low Zn²⁺-migration energy barrier, (0.66 eV) even close to that of Li⁺ within LiFePO₄. This fast intrinsic ion-diffusion kinetics, together with nanostructure effect, allow the achievements of ultrafast charging (71% state of charge in 1.9 min) and an ultrahigh power density (7200 W kg⁻¹ at 107 Wh kg⁻¹). Equally important, the IOF exhibits a quasi-zero-strain feature (<1% lattice change upon (de)zincation), which ensures ultrahigh cycling durability (3000 cycles) and Coulombic efficiencies of 100%. The cell-level energy and power densities reach ≈90 Wh kg⁻¹ and ≈3320 W kg⁻¹, far surpassing commercial lead–acid, Ni–Cd, and Ni–MH batteries. Lattice-water-rich IOFs may open up new opportunities for exploring stable and fast-charging Zn-ion batteries.     

CuO对白云石烧结性能的影响

本文研究了CuO对白云石烧结性能的影响,结果表明:CuO添加到白云石中,高温烧结时,产生低熔点CaO-CuO液相,促进白云石的烧结。当煅烧温度为1600℃,无CuO添加剂时,制备的镁钙砂体积密度为3.23 g/cm~3,显气孔率为3.4%。当CuO添加量为1.5%时,制备的镁钙砂体积密度提高到3.30 g/cm~3,显气孔率为1.6%。