Proton-exchanged 36 degrees Y-X LiTaO3 waveguides for surface acoustic wave

A nontoxic proton source, octanoic acid, was adopted to fabricate proton-exchanged (PE) waveguides in 36 degrees Y-X lithium tantalate (LiTaO3) substrates. The PE ability of octanoic acid on LiTaO3, the penetration depth, was investigated by secondary-ion mass spectrometry (SIMS). The penetration depth of hydrogen ion exhibited an obviously step-like profile, which will be excellent for waveguide application. The relationship between waveguide depth (d) and exchanging time (t) was represented by d = 0.0653 X square root of t at T = 200 degrees C. To deserve to be mentioned, the octanoic acid has a slight dissociation coefficient and low activation energy, thus the accurate waveguide depth control can be obtained. For the application of acoustic wave guided acousto-optic devices, the leaky surface acoustic wave (LSAW) properties of PE 36 degrees Y-X LiTaO3 waveguides were investigated. The phase velocity slightly decreased with the increase of kd, where k was wavenumber. An indispensable parameter of acoustic wave device, the temperature coefficient of frequency (TCF), calculated from the frequency change of the output of LSAW delay line showed an increase with increased kd.     

Synthesis and surface acoustic wave properties of AlN films deposited on LiNbO3 substrates

The c-axis-oriented aluminum nitride (AlN) films were deposited on z-cut lithium niobate (LiNbO₃) substrates by reactive RF magnetron sputtering. The crystalline orientation of the AlN film determined by x-ray diffraction (XRD) was found to be dependent on the deposition conditions such as substrate temperature, N₂ concentration, and sputtering pressure. Highly c-axis-oriented AlN films to fabricate the AlN/LiNbO₃-based surface acoustic wave (SAW) devices were obtained under a sputtering pressure of 3.5 mTorr, N₂ concentration of 60%, RF power of 165 W, and substrate temperature of 400°C. A dense pebble-like surface texture of c-axis-oriented AlN film was obtained by scanning electron microscopy (SEM). The phase velocity and the electromechanical coupling coefficient (K²) of SAW were measured to be about 4200 m/s and 1.5%, respectively. The temperature coefficient of frequency (TCF) of SAW was calculated to be about -66 ppm/°C     

Effect of Rapid Thermal Annealing on Sputtered CaCu<Subscript>3</Subscript>Ti<Subscript>4</Subscript>O<Subscript>12</Subscript> Thin Films

Calcium copper titanium oxide (CaCu₃Ti₄O₁₂, abbreviated to CCTO) films were deposited on Pt/Ti/SiO₂/Si substrates at room temperature (RT) by radiofrequency magnetron sputtering. As-deposited CCTO films were treated by rapid thermal annealing (RTA) at various temperatures and in various atmospheres. X-ray diffraction patterns and scanning electron microscope (SEM) images demonstrated that the crystalline structures and surface morphologies of CCTO thin films were sensitive to the annealing temperature and ambient atmosphere. Polycrystalline CCTO films could be obtained when the annealing temperature was 700°C in air, and the grain size increased signifi- cantly with annealing in O₂. The 0.8-μm CCTO thin film that was deposited at RT for 2 h and then annealed at 700°C in O₂ exhibited a high dielectric constant (ε′) of 410, a dielectric loss (tan δ) of 0.17 (at 10 kHz), and a leakage current density (J) of 1.28 × 10⁻⁵ A/cm² (at 25 kV/cm).     

Humidity Effect on the High-Tc (Pb,Bi)SrCaCuO Superconductor

The effect of humidity on the bismuth superconductor is investigated under 90% humidity at 30°C for 250 h. Nearly none of the peaks of high- T _c phase (2223) can be observed in the X-ray pattern after the test. The silver contact resistance of the sample also increases prominently in the time interval from 60 h to 100 h. When the humidity-tested sample is heated again under sintering conditions (845°C for 50 h in air), the high- T _c phase appears again.     

Surface acoustic wave properties of proton-exchanged LiNbO3 waveguides with SiO2 film

Surface acoustic wave (SAW) properties of proton-exchanged (PE) z-cut lithium niobate (LiNbO3) waveguides with silicon dioxide (SiO2) film layers were investigated using octanoic acid. The distribution of hydrogen measured by secondary ion mass spectrometry (SIMS) showed a step-like profile, which was assumed to be equal to the waveguide depth (d). The SiO2 film was deposited on z-cut LiNbO3 waveguide by radio frequency (rf) magnetron sputtering. We investigated the important parameters for the design of SAW devices such as phase velocity (Vp), insertion loss (IL) and temperature coefficient of frequency (TCF) by a network analyzer using thin-film aluminum interdigital transducer electrodes on the upper SiO2 film surface. The experimental results showed that the Vp of SAW decreased slightly with the increase of h/lambda, where h was the thickness of SiO2 films and lambda was the wavelength. The IL of SAW increased with increased h/lambda. The TCF of SAW calculated from the frequency change of the output of SAW delay line showed an evident decrease with the increase of h/lambda. The TCF for PE z-cut LiNbO3 was measured to be about -54.72 ppm/degreees C at h/lambda = 0.08. It revealed that the SiO2 films could compensate and improve the temperature stability as compared with the TCF of SAW on PE samples without SiO2 film.     

Direct adaptive iterative learning control of nonlinear systems using an output-recurrent fuzzy neural network

In this paper, a direct adaptive iterative learning control (DAILC) based on a new output-recurrent fuzzy neural network (ORFNN) is presented for a class of repeatable nonlinear systems with unknown nonlinearities and variable initial resetting errors. In order to overcome the design difficulty due to initial state errors at the beginning of each iteration, a concept of time-varying boundary layer is employed to construct an error equation. The learning controller is then designed by using the given ORFNN to approximate an optimal equivalent controller. Some auxiliary control components are applied to eliminate approximation error and ensure learning convergence. Since the optimal ORFNN parameters for a best approximation are generally unavailable, an adaptive algorithm with projection mechanism is derived to update all the consequent, premise, and recurrent parameters during iteration processes. Only one network is required to design the ORFNN-based DAILC and the plant nonlinearities, especially the nonlinear input gain, are allowed to be totally unknown. Based on a Lyapunov-like analysis, we show that all adjustable parameters and internal signals remain bounded for all iterations. Furthermore, the norm of state tracking error vector will asymptotically converge to a tunable residual set as iteration goes to infinity. Finally, iterative learning control of two nonlinear systems, inverted pendulum system and Chua's chaotic circuit, are performed to verify the tracking performance of the proposed learning scheme.     

Surface scattering mechanisms of tantalum nitride thin film resistor

In this letter, we utilize an electrical analysis method to develop a TaN thin film resistor with a stricter spec and near-zero temperature coefficient of resistance (TCR) for car-used electronic applications. Simultaneously, we also propose a physical mechanism mode to explain the origin of near-zero TCR for the TaN thin film resistor (TFR). Through current fitting, the carrier conduction mechanism of the TaN TFR changes from hopping to surface scattering and finally to ohmic conduction for different TaN TFRs with different TaN microstructures. Experimental data of current–voltage measurement under successive increasing temperature confirm the conduction mechanism transition. A model of TaN grain boundary isolation ability is eventually proposed to influence the carrier transport in the TaN thin film resistor, which causes different current conduction mechanisms.     

Charge-discharge characteristics of polyacetylene solid-state batteries

Summary The performances of solid-state batteries using polyacetylene, (CH)_x, as electrode material have been investigated. Two kinds of solid electrolytes, RbAg₄I₅ and Ag₂₆I₁₈W₄O₁₆, have been used with silver anodes. Both types of cells are able to discharge at room temperature. The performances of cells such as internal resistance, electromotive force, discharging ability, capacity, etc., have been measured under different conditions. The secondary effect of the solid-state batteries is investigated also. Moreover, the differences between the two kinds of cells have been compared and discussed.