Indole‐based polymer and its silver nanocomposite as advanced antibacterial agents: synthetic path,kinetics of polymerization and applications

Atom transfer radical polymerization of 1‐allylindole‐3‐carbaldehyde (AIC) was studied by employing 2‐bromoisobutyryl bromide as initiator in toluene. It led to controlled radical polymerization of AIC, with an increase of molecular weight along with the conversion of the monomer, and a relatively narrow molar mass distribution was obtained, as determined by gel permeation chromatography. The living nature of poly(1‐allylindole‐3‐carbaldehyde) (PAIC) was confirmed by the chain extension polymerization whereas ¹H NMR analysis showed that the major population of PAIC retained the chain‐end functional group. PAIC and its silver nanocomposite were found to be biologically active against some tested bacterial pathogens. Minimum inhibitory concentration tests revealed that PAIC exhibited antibacterial activity against Staphylococcus aureus, Proteus mirabilis and Klebsiella pneumonae whereas PAIC/Ag nanocomposite showed antibacterial activity against Enterococcus faecalis and K. pneumonae. © 2012 Society of Chemical Industry     

Failure analysis of titanium alloy (Ti6Al4V) fastener used in aerospace application

Titanium alloy fasteners are being used in space programme. These fasteners are coated with MoS₂, which serves the purpose of solid lubricant. During the trial assembly of flight spin motor to the bracket mounted on subsystem, one of the two fasteners failed such that the head of the bolt had sheared off the shank. Metallographic analysis carried out on the failed fasteners revealed variations in the microstructures all along the shank axis. Microstructure consisted of equiaxed primary alpha in transformed beta matrix within lower portion of the shank, while it was elongated primary alpha with little bulging all along prior beta grain boundaries as well as acicular alpha at some other location towards the head side, features, typical of, as if worked above beta transus temperatures.This paper highlights the details of investigations carried out on the failed fasteners.     

Review of Life-Cycle Assessment Applications in Building Construction

Life-cycle assessment (LCA) has been used to assess product development processes “from cradle to grave” for many years. With the current push toward sustainable construction, LCA has gained importance as an objective method to evaluate the environmental impact of construction practices. A substantial amount of construction-related LCA work has been published recently; however, most of this work has been fragmented and a systematic compilation of this literature has not been undertaken. This article presents a structured review of building construction-related LCA literature, classified under four categories: LCA applications for construction products selection; LCA applications for construction systems/process evaluation; LCA tools and databases related to the construction industry; and LCA methodological developments related to the construction industry. Current challenges for using LCA in construction are discussed and potential areas for future research are highlighted. This review and similar efforts may provide the construction industry and associated researchers the necessary background to make better-informed construction decisions and assist the development of an agenda for further research.     

Dynamic User Equilibrium Model for Combined Activity-Travel Choices Using Activity-Travel Supernetwork Representation

Integrated urban transportation models have several benefits over sequential models including consistent solutions, quicker convergence, and more realistic representation of behavior. Static models have been integrated using the concept of Supernetworks. However integrated dynamic transport models are less common. In this paper, activity location, time of participation, duration, and route choice decisions are jointly modeled in a single unified dynamic framework referred to as Activity-Travel Networks (ATNs). ATNs is a type of Supernetwork where virtual links representing activity choices are added to augment the travel network to represent additional choice dimensions. Each route in the augmented network represents a set of travel and activity arcs. Therefore, choosing a route is analogous to choosing an activity location, duration, time of participation, and travel route. A cell-based transmission model (CTM) is embedded to capture the traffic flow dynamics. The dynamic user equilibrium (DUE) behavior requires that all used routes (activity-travel sequences) provide equal and greater utility compared to unused routes. An equivalent variational inequality problem is obtained. A solution method based on route-swapping algorithm is tested on a hypothetical network under different demand levels and parameter assumptions.     

Implication of unequal rivet load distribution in the failures and damage tolerant design of metal and composite civil aircraft riveted lap joints

Riveted lap joints are being used widely in civil aircraft structures. Conventional design procedures assume that the joint can be designed as if all rivets carry load equally. As found in literature associated with fatigue and fracture, forensic studies on structural failures, this assumption is not entirely valid. In this paper, the regulatory codes for civil aircraft as applicable to riveted joints in the form of FAR 25 regulations are briefly reviewed. The regulatory code discusses safety factors in an implied way, but has little specific recommendations for riveted joints. However, studies on the failures of specific aircraft illustrated in this paper add to the argument that both static strength and life are affected by the initial design procedures for the riveted joints. In this paper, finite element models for metal–metal, composite–metal, composite–composite lap joints are studied. A three row lap joint used in commercial aircraft and which was part of failure studies is also examined. Unequal rivet loads and in cases, nearly 50% more than conventional design has been seen in linear finite element analysis. Elasto-plastic analysis using rivet flexibility shows re-distribution of loads. Based on these observations, the effect of rivet loads on life estimation including the use of concepts such as by-pass stresses is discussed. These results have implications for static strength at ultimate load, damage tolerance and fail safety and are discussed in this paper. Next, in a composite–composite lap joint, the influence of ply-angle on the rivet loads is studied. Also, a composite–metal lap joint is studied for the rivet load distribution and life estimation. It is found that the load shared by the rivet rows in a composite–metal lap joint are not symmetric and therefore are more susceptible to cracking and subsequent failure as the unequal distribution can cause some of the rivet loads to be high. In conclusion, the issue of fail safe and damage tolerant design of civil aircraft structures with riveted joints are addressed, especially the implication of unequal load distribution on the failures of such joints and it is suggested that these unequal rivet load distributions be catered for at the early design stage itself via finite element analysis and the possibility of an over-arching safety factor could be considered that incorporates both ultimate load and damage tolerance conditions.     

Catalytic hydrogenation for improvement of GaAs/Ge solar cell efficiency

Hydrogen passivation on MOCVD grown p-GaAs epilayers on Ge substrate have been studied by plasma and catalytic hydrogenation and the results were compared. The conversion efficiency of the GaAs/Ge solar cells was found to increase by 10% after catalytic hydrogenation at AM1.5. This increase in efficiency is probably due to passivation of surface dangling bonds.     

Excess coffee consumption in simulated complex work settings: detriment or facilitation of performance?

Twenty-four managers who normally consume between 400 and 1,000 mg of caffeine per day participated in all-day quasi-experimental simulations. In a crossover, doubleblind design, they made complex managerial decisions either on treatment with their typical daily dose of caffeine or on treatment with 400 mg of caffeine in excess of daily consumption. The effect of caffeine treatment on various validated performance indicators was investigated. The impact of excess caffeine consumption was mild. Increased caffeine facilitated speed of response to incoming information but decreased utilization of opportunity. No significance was obtained for other measures of managerial effectiveness (such as activity, breadth, strategy, and emergency response).