Validation of MERIS LAI and FAPAR products for winter wheat-sown test fields in North-East Bulgaria

Progress in deriving land surface biophysical parameters in a spatially explicit manner using remotely sensed data has greatly enhanced our ability to model ecosystem processes and monitor crop development. A multitude of satellite sensors and algorithms have been used to generate ready-to-use maps of various biophysical parameters. Validation of these products for different vegetation types is needed to assess their reliability and consistency. While most of the current satellite biophysical products have spatial resolution of one kilometre, a recent effort utilizing data from the Medium Resolution Imaging Spectrometer (MERIS) provided leaf area index (LAI), Fraction of Absorbed Photosynthetically Active Radiation (FAPAR), and other canopy parameters in a resolution as fine as 300 m over the European continent. This resolution would be more appropriate for application at the regional scale, particularly for crop monitoring. This higher-resolution MERIS product has been evaluated in a limited number of studies to date. This article aims to validate LAI and FAPAR from the MERIS 10-day composite BioPar BP-10 product over winter wheat fields in northeast Bulgaria. The ground measurements of LAI and FAPAR were up-scaled and 30 m resolution reference raster layers were created using empirical relationships with Landsat TM (RMSE = 0.06 and RMSE = 0.22 for FAPAR and LAI, respectively). MERIS FAPAR and LAI were found to have significant correlation with FAPAR and LAI from the reference raster layers (R² = 0.84 and R² = 0.78, respectively). When MERIS Green LAI was calculated (incorporating the fraction of vegetation and brown vegetation cover from the BioPar BP-10 product), better correspondence with LAI values from the reference raster layer was achieved, with RMSE and bias reduced by 30–35%. The results from this study confirm the findings of previous validations showing that MERIS Green LAI tends to overestimate LAI values lower than 1. As a conclusion of the study, the BioPar BP-10 product was found to provide reliable estimates of FAPAR and acceptably accurate estimates of LAI for winter wheat crops in North-East Bulgaria.     

Validation of LAI and assessment of winter wheat status using spectral data and vegetation indices from SPOT VEGETATION and simulated PROBA-V images

Due to the information gap between the VEGETATION sensors and Sentinel-3 mission, the Belgian state decided to build a small satellite, Project for Onboard Autonomy-Vegetation (PROBA-V), to ensure the continuity of the data record for vegetation studies. In this study, simulated PROBA-V data generated by the Landsat Thematic Mapper (TM) were used to evaluate the potential of this mission to assess winter wheat status. The root mean square error (RMSE) of PROBA-V's leaf area index (LAI), which was generated using the exponential method and the interpolation method, is 0.33 and 0.96 for March 2011 and 1.40 and 3.33 for May 2011, respectively. Système Pour l'Observation de la Terre (SPOT) VEGETATION's LAI does not show a significant relationship with the reference LAI values except for the LAI values during the stem elongation 100% phenological stage generated using the exponential method (correlation coefficient, r = 0.91; p = 0.01). For the tillering and stem elongation 100% phenological stages, linear regression models for the fraction of absorbed photosynthetically active radiation (FAPAR) with PROBA-V's normalized difference vegetation index (NDVI) were developed (coefficient of determination, R ², of 0.94 and 0.88). Exponential models for LAI (R ² of 0.91 and 0.93) and fresh weight of above-ground biomass (AGBf) (R ² of 0.90 and 0.93) with PROBA-V's near-infrared (NIR) and visible and near-infrared bands (VNIR B2) were developed accordingly. The assessment of winter wheat status showed that the highest and the lowest values of PROBA-V's simulated data (SD), i.e. NDVI, normalized difference water index (NDWI), and LAI of Field 2 and Field 4, correspond to the ground-measured biometric parameters.     

Analysis and integration of fuel cell combined cycles for development of low-carbon energy technologies

Integrated and combined cycles (ICC, CC) traditionally involve gas and steam turbines only. The paper analyses the further integration of high-temperature fuel cells (FC) having high electrical efficiency reaching up to 60% compared with 30–35% for most gas turbines. The previous research on FC hybrids indicates achieving high efficiencies and economic viability is possible. The ICC of various FC types—their performance and the potential for utilisation of renewables—are analysed considering also power generation capacity and site heat integration context. Further research and development with industrial relevance are outlined focusing on CO₂ emissions reduction.     

Two‐component “Onionlike” micelles with a PPO core,a PDMAEMA shell and a PEO corona: formation and crosslinking

BACKGROUND: Chemical or physical crosslinking of supramolecular assemblies gives them stability in a wide range of environments. Much attention is paid to multilayer (onion‐like) polymeric micelles because their functionality is higher than classic core‐shell micelles. This work reports on the formation and crosslinking of onion‐like micelles prepared by mixing two different block copolymers containing a crosslinkable poly(dimethylaminoethyl methacrylate) (PDMAEMA) block. RESULTS: Block copolymers of a crosslinkable PDMAEMA block were synthesized by atom transfer radical polymerization of 2‐(dimethylamino)ethyl methacrylate (DMAEMA) from poly(propylene oxide) (PPO) or poly(ethylene oxide) (PEO) macroinitiators. The (PDMAEMA₁₃)‐block‐PPO₆₉‐block‐(PDMAEMA₁₃) triblock formed wormlike core‐shell micelles, which were converted into ellipsoidal onion‐like micelles on mixing with the PEO₄₅‐block‐P(DMAEMA₈‐co‐MMA₄) diblock. Onion‐like micelles were crosslinked by quaternization of DMAEMA units. CONCLUSION: Formation of onion‐like micelles by mixing two different AB (ABA) and B′C block copolymers and their subsequent crosslinking is a valuable approach towards stabilized supramolecular assemblies of a higher complexity and functionality than the individual constitutive components. Copyright © 2008 Society of Chemical Industry     

Mathematical model of gentamicin sulfate release from a bioactive textile material as a transdermal system under in vitro conditions

A mathematical model was developed to estimate the release of gentamicin sulfate from a bioactive textile material as a transdermal system for wound dressing. The gentamicin sulfate released from the antibiotic/chitosan hydrogel complexes was measured in vitro by the Franz diffusion cell technique. The diffusive transport of gentamicin sulfate through three connected compartments, that is, chitosan hydrogel, membrane, and solution, was considered by the formulation of a model based on Fick's second law. Initially, the total amount of gentamicin sulfate was placed within an already swollen chitosan hydrogel. The value of the diffusivity coefficient of the drug through the chitosan hydrogel was calculated for every initial amount of the active substance. For the initial concentration of gentamicin sulfate, which was lower than 2.81 × 10⁴ μg/mL, the diffusion coefficient was approximately constant. A higher amount of gentamicin sulfate in the hydrogel reduced its own transport as a consequence of an increase in the intensity of the interaction field between the molecules of gentamicin sulfate. The model provides the possibility of optimizing the process of drug release by ensuring a compromise between a higher value of the diffusivity coefficient and a desirable amount of gentamicin sulfate and a constant concentration within the solution over 48 h. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010     

Entrapment of Saccharomyces cerevisiae cells in u.v. crosslinked hydroxyethylcellulose/poly(ethylene oxide) double-layered gels

Double-layered gels, consisting of hydroxyethylcellulose cryogel core and poly(ethylene oxide) hydrogel shell, were synthesized with u.v. irradiation, using the same photoinitiator, (4-benzoylbenzyl) trimethylammoniumchloride (BBTMAC) for the both layers. The gels were characterized by measuring their rheological parameters, gel fraction yield, the degree of equilibrium swelling and diffusion coefficient. The diffusion coefficients for glucose and ethanol through the hydroxyethylcellulose cryogel were 3.9 × 10^?6 cm²/s and 0.97 × 10^?5 cm²/s, respectively. The applicability of these double-layered gels as carriers for immobilization was investigated by entrapment of Saccharomyces cerevisiae cells. The immobilization efficiency and cell retention were determined in batch fermentation for ethanol production from glucose. The operational stability of the gels was evaluated in batch fermentation with three consecutive runs. The ethanol yield was in the range from 60% to 77% of the theoretical yield.     

Analysis of feedback-loop interactions with actuator and sensor parasitics

Feedback system design is often simplified by neglecting sensor and actuator dynamics. It is of practical importance to investigate the effects of such ‘parasitics’, especially when feedback gain is high. In this paper, we employ singular perturbations to model and analyze the interaction of sensor-actuator dynamics with the fast modes created by high feedback gain.     

Area decomposition for electromechanical models of power systems

Coherency and time scale properties of power system models are shown to be related by the dichotomic solution of a matrix Riccati equation. A grouping algorithm is proposed which reduces the area decomposition problem to obtaining a basis for the slow subsystem and performing a Gaussian elimination. Since the slow coherency measure allows for a lack of coherency in fast parts of machine transients, the resulting area decomposition is independent of fault locations. The procedure is illustrated by a 16-machine example.     

Singular perturbation analysis of systems with sustained high frequency oscillations

Using singular perturbation techniques, a system with high frequency oscillations is decomposed into two lower order subsystems, one containing only the slowly varying part and the other containing only the fast oscillatory part. Eigenvalue and state approximations achieved by the subsystems are given. A mass-spring-damper example shows that a stiff spring can be regarded as a perturbation of a rigid rod and an interconnected power system example illustrates the occurrence of coherency and inter-machine oscillations.