Microstructural study of aged ferrite powders for sensing layers

Nanosized powders of La_0.80Sr_0.20Fe_0.95Cu_0.05O_3?w were investigated in terms of structural, morphological, chemical and surface properties by using several characterization techniques. The XPS and IR measurements showed the presence of surface hydroxide and carbonates species. After calcination of the powders at 900 °C the amount of carbonates decreased but was still significant. The sensing activity of thick film based on La_0.80Sr_0.20Fe_0.95Cu_0.05O_3?w was tested as a function of relative humidity and the results indicate that (i) after one year of ambient storage the sensing material lost quite completely its sensitivity to humidity, (ii) the sensing activity of the film was mostly re-activated after a thermal treatment at 900 °C for 2 h, and (iii) the huge shift of the detection limit to low RH caused by the presence of 5 mol% Cu is also restored.     

Effects of nutrient supplementation on fermentation kinetics, H2S evolution, and aroma profile in Verdicchio DOC wine production

Different yeast nutrient additions were studied for the 2008 and 2009 vintages of Verdicchio grape juice fermentation. Addition of yeast derivatives at the beginning of fermentation and/or different amounts of diammonium phosphate at various times within the first half of fermentation were examined, with initial yeast assimilable nitrogen concentrations set at 200 and 250 mg l^?1. Supplementation with glutathione in combination with this nitrogen addition was also evaluated. Fermentation rates were monitored throughout these fermentations carried out under different nutrient conditions. H₂S production during fermentation and synthesis of volatile compounds in the finished wines were quantified; the wines also underwent sensory evaluation. The fermentation kinetics were almost exclusively influenced by the inorganic nitrogen supplementation with diammonium phosphate. H₂S evolution was more affected by assimilable nitrogen than glutathione. Diammonium phosphate significantly reduced H₂S production, with a further reduction in the presence of yeast derivative. This nitrogen supplementation yielded higher concentrations of acetate esters, and in particular of isoamyl acetate (fruity aromas), which positively influences the analytical and aroma profile of wines and results in a general reduction in 2-phenylethanol production (floral aromas). Overall results (two harvesting times and vintages) indicate that the management with diammonium phosphate and yeast derivative supplementation improves the kinetics of fermentation and provides a good tool to reduce H₂S formation and increase the analytical and sensory quality of Verdicchio wine.     

Infrastructures for the environment of multiagent systems

The notion of environment is receiving an increasing attention in the development of multiagent applications. This is witnessed by the emergence of a number of infrastructures providing agent designers with useful means to develop the agent environment, and thus to structure an effective multiagent application. In this paper we analyse the role and features of such infrastructures, and survey some relevant examples. We endorse a general viewpoint where the environment of a multiagent system is seen as a set of basic bricks we call environment abstractions, which (i) provide agents with services useful for achieving individual and social goals, and (ii) are supported by some underlying software infrastructure managing their creation and exploitation. Accordingly, we focus the survey on the opportunities that environment infrastructures provide to system designers when developing multiagent applications.     

Formulation of equations in terms of scalar functions for lumped non-linear networks

A general method is presented of formulating the Lagrangian and anti-Lagrangian equations for networks consisting of non-linear RLCM (M = memristor) multiports with hybrid representation. The formulation is obtained with no restriction on the network topology. An explicit procedure is given to construct the scalar functions needed. This procedure is based on the concept of L and H functions introduced. The Brayton-Moser equations in a generalized form can be directly obtained from the anti-Lagrangian equations. From these equations, new equations of Brayton-Moser type can also be derived. The invariance property of Lagrangian and anti-Lagrangian equations under a transformation of variables is also discussed.     

Player behavior and traffic characterization for MMORPGs: a survey

Massively Multiplayer Online Role-Playing Games (MMORPGs) are one of the most exciting and most rapidly expanding genres of online games. This survey presents state-of-the-art and current research efforts in measuring, characterizing, and modeling the player behavior and the network traffic, as well as the relationships between them. We also tabulate the measurement, modeling and analysis results regarding network traffic and player behavior found in literature, with key information regarding each dataset. Finally, we list currently confirmed claims and open research questions in the area of MMORPGs.     

A new method for computing fuzzy functional dependencies in relational database systems

In this paper, we present a new method for computing fuzzy functional dependencies between attributes in fuzzy relational database systems. The method is based on the use of fuzzy implications. A literature analysis has shown that there is no algorithm that would enable the identification of attribute relationships in fuzzy relational schemas. This fact was the motive for development a new methodology in the analysis of fuzzy functional dependencies over a given set of attributes. Solving this, not so new problem, is not only research challenge having theoretical importance, but it also has practical significance. Possible applications of the proposed methodology include GIS, data mining, information retrieval, reducing data redundancy in fuzzy relations through implementation of logical database model, estimation of missing values etc.     

Design,manufacture and geometric verification of rapid prototyped microfluidic encapsulations by computed tomography

This paper presents the dimensional verification of encapsulations used to package microfluidic devices manufactured using a 3D printer of photopolymerisable resin. This characterisation has been performed by computed tomography (CT) by comparing newly manufactured encapsulations and samples that have been subjected to test conditions. Thus, it has been possible to draw conclusions both on the deviations of the nominal geometry of the encapsulations and on how this might affect their performance. This paper presents a scheme of dimensional verification from the point clouds obtained by CT. Finally, a combined threshold and scale factor correction technique of the tomography images is shown. This method is based on the simultaneous measurement of objective and master parts with known geometry. The results reveal the improvements achievable in the accuracy, given a particular machine configuration. The conclusions facilitate the improvement of the geometric design of these devices regarding their behaviour under test conditions.     

Wetting and surface tension measurements on gold alloys

The surface tension and the density of some gold alloys have been measured and their wetting behaviour investigated in relation to different ceramic supports. Relationships between surface tension and density as a function of temperature are proposed.     

A biochemical approach to adaptive service ecosystems

Emerging network scenarios call for innovative open service frameworks to ensure capability of self-adaptability and long-lasting evolvability. In this paper, we assess the need for such innovative service frameworks, and discuss how their engineering should get inspiration from natural ecosystems, i.e., by modelling services as autonomous individuals in an ecosystem of other services and data sources. We introduce a reference conceptual architecture with the goal of clarifying the concepts expressed and framing the several possible nature-inspired metaphors that could be adopted to realise the idea. On this basis, we go into details about one of such possible approaches, in which the rules governing the ecosystem are inspired by biochemical mechanisms. A case study is also introduced to exemplify the potentials of the presented biochemical approach and to experiment with some representative biochemistry-inspired patterns of adaptive service organisation and evolution.     

Time-Resolved Soft X-ray Diffraction Reveals Transient Structural Distortions of Ternary Liquid Crystals

Home-based soft X-ray time-resolved scattering experiments with nanosecond time resolution (10 ns) and nanometer spatial resolution were carried out at a table top soft X-ray plasma source (2.2–5.2 nm). The investigated system was the lyotropic liquid crystal C₁₆E₇/paraffin/glycerol/formamide/IR 5. Usually, major changes in physical, chemical, and/or optical properties of the sample occur as a result of structural changes and shrinking morphology. Here, these effects occur as a consequence of the energy absorption in the sample upon optical laser excitation in the IR regime. The liquid crystal shows changes in the structural response within few hundred nanoseconds showing a time decay of 182 ns. A decrease of the Bragg peak diffracted intensity of 30% and a coherent macroscopic movement of the Bragg reflection are found as a response to the optical pump. The Bragg reflection movement is established to be isotropic and diffusion controlled (1 μs). Structural processes are analyzed in the Patterson analysis framework of the time-varying diffraction peaks revealing that the inter-lamellar distance increases by 2.7 Å resulting in an elongation of the coherently expanding lamella crystallite. The present studies emphasize the possibility of applying TR-SXRD techniques for studying the mechanical dynamics of nanosystems.