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991.
992.
Masaki M Aritake K Tanaka H Shoyama Y Huang ZL Urade Y 《Molecular nutrition & food research》2012,56(2):304-308
Crocus sativus L. (saffron) has been traditionally used for the treatment of insomnia and other diseases of the nervous systems. Two carotenoid pigments, crocin and crocetin, are the major components responsible for the various pharmacological activities of C. sativus L. In this study, we examined the sleep-promoting activity of crocin and crocetin by monitoring the locomotor activity and electroencephalogram after administration of these components to mice. Crocin (30 and 100 mg/kg) increased the total time of non-rapid eye movement (non-REM) sleep by 60 and 170%, respectively, during a 4-h period from 20:00 to 24:00 after its intraperitoneal administration at a lights-off time of 20:00. Crocetin (100 mg/kg) also increased the total time of non-REM sleep by 50% after the administration. These compounds did not change the amount of REM sleep or show any adverse effects, such as rebound insomnia, after the induction of sleep. 相似文献
993.
Yasuo Hirose Hirokazu Matsuda Go Matsubara Masaki Hojo Fumihide Inamura 《Composites Part A》2012,43(8):1318-1325
A new type of crack arrester concept, named the splice-type crack arrester, was invented and applied to a core–core splice in a foam core sandwich panel in order to suppress interfacial crack growth. An analytical evaluation of this crack arrester including parametric studies was carried out. It was confirmed by finite element (FE) analysis that interfacial crack propagation was suppressed by a decrease in the energy release rate at the crack tip under constant loading owing to the splice-type crack arrester as the crack tip approached the edge of the arrester. Through this study, it was revealed that the leading edge of the splice-type crack arrester, its shape and material, have strong effects on the crack suppression capability. 相似文献
994.
JuanJuan Xing Masaki Takeguchi Miyoko Tanaka Yoshiko Nakayama 《Journal of Materials Science》2012,47(13):5254-5262
The NiO/YSZ interface prepared by depositing NiO on a single crystal YSZ (111) substrate has been investigated by transmission
electron microscopy. As deposited, a very thin nickel layer ascribing to the nonstoichiometry at the very beginning growth
of NiO and an amorphous silica phase resulting from silicon segregation were present at the interface. The orientational relationship
of NiO (1[`1] 1) (1\overline{1} 1) //Ni (1[`1] 1) (1\overline{1} 1) //YSZ (1[`1] 1) (1\overline{1} 1) with NiO [110]//Ni [110]//YSZ [110] was observed. The microstructural and chemical changes at the NiO/YSZ interface after
being heated in vacuum and hydrogen indicated different reduction mechanisms. In vacuum, the reaction
\textNiO ? \textNi + 1/ 2 \text O 2 ( \textg ) {\text{NiO}} \to {\text{Ni}} + 1/ 2 {\text{ O}}_{ 2} \left( {\text{g}} \right) was prevailing at the interface between NiO and pre-existing Ni, which led to the thickening of nickel layer. In hydrogen, the reduction initiated on the NiO surface was dominant,
following the chemical equation H2 + OO (NiO) → H2O (g) + VO
.. (NiO) + 2e (Ni). 相似文献
995.
So-Yeon Park Masahiro Ebihara Yasuhiro Kubota Kazumasa Funabiki Masaki Matsui 《Dyes and Pigments》2009,82(3):258-267
The solid-state fluorescence intensity of coumarin dyes depends on the substituents present at the 4- and 7-positions. 7-(Diethylamino)coumarins showed higher solid-state fluorescence quantum yield (Φf(ss) = 0.29–0.40) than 7-aminocoumarins (0.01). In the case of julolydyl coumarins, a 4-methyltetramethyljulolydyl derivative also displayed high Φf(ss) (0.34), this being greater than that observed for both 4-(perfluoroalkyl)tetramethyljulolydyl (0.09 and 0.10) and 4-methyljulolydyl derivatives (0.01). X-ray crystallographic analysis suggested that coumarin dyes bearing network hydrogen bonds and/or π–π stacking show weak solid-state fluorescence whereas coumarin dyes having isolated monomer- and dimer-type stacking show intense fluorescence. 4-(Perfluoroalkyl)tetramethyljulolydyl derivatives displayed medium fluorescence intensity owing to isolated monomer-type packing with little intermolecular interactions operating between adjacent molecules. 相似文献
996.
Ke‐Jian Jiang Kazuhiro Manseki You‐Hai Yu Naruhiko Masaki Kazuharu Suzuki Yan‐lin Song Shozo Yanagida 《Advanced functional materials》2009,19(15):2481-2485
Here, the fabrication of quasi‐solid‐state TiO2/dye/poly(3‐hexylthiophene) (P3HT) solar cells is reported, in which the dyes with oleophilic thienyl groups were employed and ionic liquid (IL), 1‐ethyl‐3‐methylimidazolium (EMIm) containing lithium bis(trifluromethanesulfone)amide (Li‐TFSI) and 4‐tert‐butylpyridine (t‐BP) are assembled with dyed TiO2 surfaces. One of the devices gave a high conversion efficiency of up to 2.70% under 1 sun illumination. The excellent performance is ascribed to successful molecular self‐organization at interface of the dye molecules and P3HT, and to the efficient charge separation and diffusion acquired by introduction of the IL coupled with Li‐TFSI and t‐BP. 相似文献
997.
Takeguchi M Hashimoto A Shimojo M Mitsuishi K Furuya K 《Journal of electron microscopy》2008,57(4):123-127
A stage-scanning system is composed of a specially designed transmission electron microscopy specimen holder equipped with a piezo-driven specimen stage, power supplier and control software. This system enables the specimen to be scanned three-dimensionally, and therefore confocal scanning transmission electron microscopy (STEM) can be performed with a fixed electron-optics configuration. It is demonstrated that stage-scanning confocal STEM images can be obtained with the lateral atomic resolution and the specimen can be moved three-dimensionally with high precision. 相似文献
998.
Masaki Honda Toshiyasu Sowa Yuki Kawashima 《European Journal of Lipid Science and Technology》2020,122(5)
The effects of heating and photo‐irradiation on the stability of all‐E‐isomer‐rich and Z‐isomer‐rich xanthophylls, astaxanthin and its structurally related xanthophylls, adonirubin, and adonixanthin, are investigated. The xanthophylls with high Z‐isomer content are prepared from their high‐purity all‐E‐isomers by thermal isomerization and filtering techniques, that is, total Z‐isomer ratios of adonirubin, astaxanthin, and adonixanthin are 80.9%, 89.5%, and 72.5%, respectively. The all‐E‐ and Z‐isomer‐rich xanthophylls dissolved in ethanol are stored at 4, 30, and 50 °C in the dark and at 30 °C under photo‐irradiation using a fluorescent light for 21 days. In the all‐E‐isomer‐rich xanthophylls, as the storage temperature increases, the total Z‐isomer ratio becomes higher, whereas in the Z‐isomer‐rich xanthophylls, the all‐E‐isomer ratio becomes higher. Photo‐irradiation slightly promotes Z‐isomerization in (all‐E)‐xanthophylls, but highly promotes all‐E‐isomerization in Z‐isomer‐rich xanthophylls. In addition, photo‐irradiation prevents thermal Z‐isomerization of (all‐E)‐xanthophylls. Moreover, it is found that some xanthophyll Z‐isomers such as (9Z)‐astaxanthin are more stable than that of the other Z‐isomers against heating and photo‐irradiation. These findings can contribute not only to establishing suitable storage conditions for Z‐isomer‐rich xanthophylls, but also to developing control techniques for the E/Z‐isomer ratio of the xanthophylls. Practical Applications: The fundamental data on the stability of xanthophyll isomers against heating and photo‐irradiation and finding stable xanthophyll Z‐isomers are very important to develop xanthophyll materials rich in the Z‐isomers. Moreover, this study clearly shows that the heat treatment enhances the Z‐isomerization of xanthophylls, whereas the photo‐irradiation enhances the all‐E‐isomerization and prevents thermal Z‐isomerization of them. This information can be utilized in technology for arbitrarily controlling E/Z‐isomerization of xanthophylls. 相似文献
999.
1000.