Antinucleating action of polystyrene on the isothermal cold crystallization of poly(ethylene terephthalate)

The effect of polystyrene (PS) on the kinetics of the cold crystallization of poly(ethylene terephthalate) (PET) was thoroughly investigated. The PET/PS blends were essentially immiscible, as observed by dynamic mechanical thermal analysis, which showed two distinct glass‐transition temperatures, and by scanning electron microscopy. The neat PET and its blends were isothermally cold‐crystallized at various temperatures, and the kinetic parameters were determined with the Avrami approach. PET and its blends presented values of the Avrami exponent close to 2, and the kinetic constant increased with the crystallization temperature increasing. For all the crystallization temperatures studied, the presence of only 1 wt % PS significantly reduced the rate of cold crystallization of PET. A further increase in the PS concentration did not show any significant influence. The blends presented higher values of the activation energy for cold crystallization, which was estimated from Arrhenius plots. The equilibrium melting temperature of neat PET was determined on the basis of the linear Hoffman–Weeks extrapolative method to be ～ 255°C. This value decreased in the presence of PS, and this suggested limited solubility between PET and PS. From the spherulitic growth equation proposed by Hoffman and Lauritzen, the nucleation parameter was obtained, and it was shown to be higher for the neat PET than for the blends. Moreover, a transition of regimes (I → II) was observed in both PET and its blends. From the investigations conducted here, it is clear that PS in small amounts causes a reduction in the rate of PET crystallization, acting as an antinucleating agent. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009     

Online Identification of Horizontal Two-Phase Flow Regimes Through Gabor Transform and Neural Network Processing

The fundamental objective of this work is the development of a specialist system capable of diagnosing different configurations of horizontal two-phase flow regimes. It is important to emphasize that this knowledge is of capital importance to the efficient operation of facilities for the manipulation and transportation of multiphase fluids, and it represents one of the most important challenges in petrochemical and thermonuclear industries today. The working principle of the proposed methodology is based on the signals acquired by a rapid response pressure gradient sensor and their decomposition into Gabor coefficients, followed by processing through a previously trained artificial neural network. The implementation is accomplished in such a way that the diagnosis operation is performed online, from the acquisition of the signal to its post-processing. An experimental campaign was conducted at the facilities of the Thermal and Fluids Engineering Laboratory (NETeF) at the University of São Paulo in order to validate the proposed methodology. Experimental pressure gradient signals were obtained for all main horizontal air-water flow regimes (stratified smooth, stratified wavy, intermittent, annular, and bubbly) produced in a 12 m long test section with an internal diameter of 30 mm. Results show that the percentage of correct flow regime diagnosis in steady-state conditions is practically 100%, provided the detection level is adequately set.     

Large eddy simulation of pollen transport in the atmospheric boundary layer

This paper presents a framework to simulate pollen dispersal by the wind based on the large eddy simulation (LES) technique. Important phenomena such as the pollen emission by the plants and the ground deposition are parameterized by the lower boundary condition. The numerical model is validated against previously published experiments of point source releases of glass beads and pollen grains in the atmospheric boundary layer. The numerical model is used together with experimental data of pollen emission and downwind deposition from a natural field obtained near Washington, DC, in the summer of 2006. The combined analysis of experimental and numerical data allows to elucidate the emission/transport/deposition process in considerable detail. In particular, the relative fractions of pollen deposited inside the source field and airborne at the edge of the field can be quantified. The use of LES allows quantification of important intermittent deposition events far from the source field.     

Polycrystalline fluorine-doped tin oxide as sensoring thin film in EGFET pH sensor

The Extended Gate Field Effect Transistor (EGFET) is a device composed of a conventional ion-sensitive electrode and a MOSFET device, which can be applied for the measurement of ion content in a solution. The EGFET is fabricated connecting the sensitive membrane to a commercial MOSFET. We investigated the use of fluorine-doped tin oxide films (FTO) as sensitive membrane to EGFET. The commercial FTO shows a low resistivity and a crystalline structure, both determined using conductivity set-up and X-ray diffraction experiments, respectively. So far, it has been known that an amorphous structure is desirable to obtain high sensitivity. Despite of the a crystalline structure, we have fabricated the FTO as EGFET for pH sensor and carried out experiments in order to obtain the response of the device inserted into solutions with pH values from 2 up to 12. In this range, we have quantified a sensitivity of 50 mV/pH, which may have large potential applications as pH and biosensors. In addition, both the film and the structure of the sensor are cheaper and easier to make than in common techniques.     

Unsteady Bed Shear Stresses Induced by Navigation: Laboratory Observations

Time-dependent bed shear stresses induced by the passage of a barge tow have been measured with hot film shear stress sensors in a 1:25 scale model. Conditions typical of those observed for Upper Mississippi River navigation traffic were simulated in the experimental facility. Two sets of experiments were carried out: the first set consisted of simultaneous shear stress measurements at different locations for a variety of flow depths and boat operating conditions, providing space-time distributions of ensemble averaged wall shear stresses. The second set included a large number of realizations gathered for one particular flow condition at a single position, allowing analysis of the time evolution of the turbulence characteristics (i.e., standard deviation) of the bed shear stresses. The results of the first set of experiments show that for all the experimental conditions the basic patterns of the shear stress are similar, with two regions of high shear stress associated with the passage of the bow and the stern of the barge tow, respectively. Analysis of the second set of experiments showed that, as a result of the passage of the barge tow, the bed-shear stress standard deviation departs from the values commonly observed under steady, uniform, open-channel flow conditions. This behavior has important implications for sediment transport.     

Analyzing and monitoring aluminum smelter performance via web browsers

Conclusion Based on our experience at Albras, where the system is still in operation and being expanded upon, web browsers will play only a greater role as a tool for spreading useful information to decision makers in the plant environment. Authors’ Note: A more detailed explanation of the system described here can be found at www.atan.com.br. In development is an interface that will allow every visitor to browse freely through simulated process data. Marcelo de Souza Baltar earned his B.S. in electronic engineering at Universidade Federal de Minas Gerais, Brazil, in 1993. He is a system engineer at the Aluminum Division of Atan Automation Systems. Ernani Fernandes Vargas da Silva is a senior programmer at the Aluminum Division of Atan Automation Systems. Constantino Seixas Filho earned his M.S. in computer science at Universidade Federal de Minas Gerais, Brazil, in 1985. He is an assistant professor of the Electronics Department of Universidade Federal de Minas Gerais and is research and development director at Atan Automation Systems.     

Electrochemical and morphological characterization of poly(12-pyrrol-1′-yl dodecanoic acid)

12-Pyrrol-1′-yl dodecanoic acid was prepared and electrochemically polymerized on ITO electrodes by three different methods. The electrochemical and morphological properties of poly(12-pyrrol-1′-yl dodecanoic acid) films were investigated by cyclic voltammetry, galvanostatic charge–discharge curves and AFM, which characteristics varied as function of deposition method. Films deposited by potentiodynamic and galvanostatic methods showed capacitive properties and are promising for application in polymeric capacitors.