Residence Time Distribution and Specific Mechanical Energy in Solid-State Shear Pulverization: Processing-Structure-Property Relationships in a Chilled Extruder

Solid-state shear pulverization (SSSP) is a continuous polymer processing methodology based on a modified twin-screw extruder. The unique application of low barrel temperatures and mechanochemistry has contributed to the development of an extensive range of polymer-based materials, from environmentally responsible polymer blends to nanocomposites, for more than 30 years. The complex processing-structure-processing relationships in SSSP can be elucidated by way of integrated, measured covariants that capture the interplay between numerous processing parameters. Residence time distribution and specific mechanical energy are evaluated in a base case polypropylene (PP) study under a full factorial experiment involving screw design, screw speed, and throughput parameters. These factors are in turn correlated to dispersion morphology and thermal property results from a parallel study based on a model PP/carbon black composite. This investigation highlights the tunability of SSSP processing parameters for tailored output with desired purposes and applications. In particular, enhanced residence distribution can be achieved with low screw speed and high throughput settings, leading to high levels of material mixing and shear. POLYM. ENG. SCI., 60:503–511, 2020. © 2019 Society of Plastics Engineers     

Breakdown of YBCO thin films during current limiting and methods of improving current limiting performance

We performed fault current limiting tests using YBCO thin films and investigated the reasons for their breakdown during current limiting. There were two patterns of film breakdown. One occurred immediately after current limiting and the other occurred during current limiting. In film breakdown, the quench propagation speed showed almost no change with increasing energy consumption per unit time, but the energy consumption per unit area increased with increasing energy consumption per unit time. Therefore, local areas of the film reached the melting point and arcing occurred. It is therefore concluded that the performance of the films can be improved by decreasing the energy consumption per unit time. Connecting a parallel capacitor to the film in order to limit the energy consumption per unit time is proposed and tested as a measure to improve the current limiting performance of thin films. © 2008 Wiley Periodicals, Inc. Electr Eng Jpn, 166(1): 20–27, 2009; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/eej.20709     

Examination of flying height of magnetic head slider in simulations and measurements at nanometer-order spacing

This paper describes a comparison with the experimental flying heights and the simulated flying heights, which were calculated by using the linearized Boltzmann equation and the conventional modified Reynolds equations. The experiments were measured under the ambient pressure from atmospheric pressure to 6.7 × 10^?3 MPa. The calculated results of the linearized Boltzmann equation were almost the same as the experimental results from the high spacing range to the low spacing range of 10 nm. At the slider spacing of 10 nm, it was confirmed that the difference between the experimentally measured results and the calculated results of the linearized Boltzmann equation was less than 5%, and the differences in the conventional slip flow approximation equations were over 30%.     

Downscaling mesoscale meteorological models for computational wind engineering applications

Considerable interest exists in joining the capabilities of mesoscale meteorological models (MMM) with those of computational wind engineering (CWE) models to produce realistic simulations, which address emerging issues in wind engineering and environmental applications. The model equations are similar for MMM and CWE, but there are significant differences in the objectives and approaches. Complete synthesis of these models is still premature and computational burdens are enormous. Appropriate procedures for joining these models have not been established yet and measurement data required for verification is limited.For convenience in presentations and discussions, coupling methods are divided into four groups: (1) coupling MMM and CWE models for up-scaling or downscaling, (2) up-scaling a CWE model to include the mesoscale meteorological influences, (3) downscaling an MMM to include the CWE capabilities, and (4) a combination of the above three approaches. Mochida et al. (this issue) focuses on up-scaling CWE from an engineering point of view and the present paper focuses on downscaling MMM from a meteorological point of view.Topics addressed here are (1) to understand the differences in the purposes and approaches of MMM and CWE models and (2) to identify issues and explore ways of coupling MMM and CWE modeling capabilities.     

Formulation of four Katsevich algorithms in native geometry

We derive formulations of the four exact helical Katsevich algorithms in the native cylindrical detector geometry, which allow efficient implementation in modern computed tomography scanners with wide cone beam aperture. Also, we discuss some aspects of numerical implementation.     

Effects of the depth of NO and N2O productions in soil on their emission rates to the atmosphere: analysis by a simulation model

Many factors are concerned in the changing forms of nitrogen compounds in soil, so it is not easy to make precise models to simulate the concentration profiles of soil nitric oxide (NO) and nitrous oxide (N₂O) and their emission rates under various soil conditions. We prepared a simple mathematical simulation model based on soil concentration profiles of NO and N₂O. The profiles were measured at lysimeters filled with Andosol soil and fertilized with ammonium sulfate at rate of 200 kgNha^-1, incorporating to plow layer (Hirose & Tsuruta, 1996). In this model, diffusion of gases in soil followed Fick's law and the diffusion coefficient was adopted from Sallam et al. (1984). The gas production rate was set up at constant value in the site of gas production, and the gaseous consumption followed Michaelis-Menten kinetics. By changing only the depth of NO and N₂O production in soil in this model, we obtained the following results.(1) When the depth of gas production was set at near the soil surface (NO: 0–10 cm, N₂O: 0-8 cm), the emission rates of both gases corresponded with the results of the lysimeter-measurement.(2) When the depth of gas production was shifted down 10 cm deeper (NO: 10–20 cm, N₂O: 10-18 cm), the gas emission rate of NO decreased to 1.3% of (1), while that of N₂O was almost the same as (1).(3) In the case that the total intensity of produced gases was not changed from (1) or (2), but that the extent of gas productions expanded 3 times wider (NO: 0–30 cm, N₂O: 0–24 cm) than (1) or (2), the emission rates of NO and N₂O became 26% and 95% of (1), respectively.The above results suggest the possibility of mitigating NO emission by setting the site of gaseous production in deeper soil, e.g. by means of deep application of fertilizer.     

Efficient Conversion of D-Glucose to D-Fructose in the Presence of Organogermanium Compounds

D-Glucose and D-fructose are isomers of commonly consumed monosaccharides. The ratio of conversion of D-glucose to D-fructose by glucose isomerase (xylose isomerase) is not more than 50 %. However, addition of an equimolar ratio of the organogermanium compound poly-trans-[(2-carboxyethyl)germasesquioxane] (Ge-132) or its derivative increases the conversion ratio to 80 %. In contrast, use of the Lobry de Bruyn–Alberda van Ekenstein transformation with heating results in a lower conversion ratio, less than 30 %, whereas addition of an equimolar concentration of Ge-132 or its derivative to this reaction mixture increases the ratio to 73 %. Therefore, in this study, we aimed to further analyze the affinity between organogermanium compounds (i.e., Ge-132 and its derivatives) and sugar using ¹H-nuclear magnetic resonance (NMR) spectrometry. For the dimethyl derivative of Ge-132, the complex formation ratios at 0.25 M (mixing ratio 1:1) were 19 and 74 % for D-glucose and D-fructose, respectively. Additionally, the complex formation constants between monosaccharides and Ge-132 were 1.2 and 46 M^-1 for D-glucose and D-fructose, respectively. The complex formation capacity was approximately 40-fold higher for D-fructose than for D-glucose. Therefore, we concluded that the high affinity for the product of isomerization may promote isomerization, and that promotion of sugar isomerization using organogermanium compounds is an effective method for conversion of D-glucose to D-fructose.     

Universal Strategy for Efficient Electron Injection into Organic Semiconductors Utilizing Hydrogen Bonds

Molecular n‐dopants that can lower the electron injection barrier between organic semiconductors and electrodes are essential in present‐day organic electronics. However, the development of stable molecular n‐dopants remains difficult owing to their low ionization potential, which generally renders them unstable. It is shown that the stable bases widely used in organic synthesis as catalysts can lower the electron injection barrier similar to that in conventional n‐doping in organic optoelectronic devices. In contrast to conventional n‐doping, which is based on the electron transfer from dopants with low ionization potential, the reduction of the injection barrier caused by adding bases is determined by the formation of hydrogen bonds between the hosts and the bases, providing energy‐level‐independent electron injection. The observation of the efficient electron injection induced by hydrogen bonding affords new perspectives on the method for controlling the behavior of electrons unique to organic semiconductors.