Beryllium Analytical Signal Using ERIAD Mass-Spectrometry for Various Sample Preparation Methods

Inorganic Materials - The significance of the problem of determining the concentration of beryllium in solutions is substantiated. A method of ERIAD mass-spectrometry (atmospheric pressure...     

How operators make use of wide-choice adaptable automation: observations from a series of experimental studies

The present paper is concerned with the design of adaptable automation. It analyses the aggregated data from five experiments (N = 154) to examine which automation levels operators prefer, how often they switch between them, and whether performance is associated with frequent switching or the automation levels being used. Using wide-choice adaptable automation (i.e. up to six levels were offered), the experiments were conducted using a PC-based simulation of a complex work environment. The results showed that about 95% of operators had a clearly preferred automation level, which they used for more than 50% of the time. They strongly preferred intermediate automation levels over levels at the higher and lower ends of the scale. Most operators switched rarely between levels and when they did, they usually made small adjustment rather than large changes. Several implications for the design of adaptable automation were derived from the empirical data.     

Hot working behavior of a WE54 magnesium alloy

The plastic deformation and recrystallization behavior of the commercial magnesium alloys WE54 was analyzed using the strain rates 0.01, 0.1, 1, and 5 s^?1 in the temperature range from 400 to 550 °C. The dependence of the flow stress on the temperature and the strain rate was modeled using the Garofalo hyperbolic sine equation. Thereby, the activation energy for plastic deformation of 224 kJ mol^?1 was determined considering the flow stress at a strain of 0.5. The analysis revealed a stress exponent of 3.2. Furthermore, processing maps were generated by plotting the efficiency of power dissipation and the instability parameter considering different instability criteria as a function of the temperature and the strain rate. Depending on these parameters the extent of the recrystallization and the localization of the nucleation varied, significantly. At 400 °C, the recrystallization is very limited and was observed at grain boundaries (GB), shear bands (SB), and twin boundaries (TW). Increasing temperatures result in an increased recrystallized fraction, while lower strain rates promote grain boundary nucleation and reduce the amount of SBN and TW. The prediction of the processing map was verified by large scale extrusion trials, which proof that the evaluation of hot compression data can provide an effective tool to establish viable processing parameters.     

Fatigue lifetime study of piezoceramic patch transducers

This study investigates the loading limits and fatigue behavior of laminar piezoceramic patch transducers, based on monolithic lead zirconate titanate (PZT) plates encapsulated in epoxy resin matrix. Testing includes tensile and compressive mechanical loading, at different temperatures, as well as electric actuation. The objective is the identification of typical failure mechanisms and suitable models for failure and lifetime analysis. In tensile loading, which is observed to have the strongest influence on the patch lifetime, the relevant failure mechanism in quasi-static and cyclic loading is found to be cracking of the PZT plate, causing degradation of the patch performance. Based on the micro-structural investigations and FE simulation, the fracture toughness of the PZT plate is analyzed and a micro-crack-propagation-based fatigue lifetime model is derived. The effect of the fragmentation of the piezoceramic plate on the patch performance is analyzed by the presented functional length concept, based on the shear lag model, yielding very good quantitative agreement.     

A middleware platform for the dynamic evolution of distributed component-based systems

In this paper, we present a middleware platform that supports the dynamic evolution of distributed component-based systems. It leverages the concept of ontologies to model the context of a system and an intrinsic mechanism is integrated to causally connect the dynamic architecture specification to the running system implementation. The ontological modeling covers both the environmental and the architectural knowledge using semantic data modeling. The intrinsic mechanism can automatically derive a run-time polymorphic architecture object to coordinate the involved components. The ontology based contextual representation and the polymorphic architecture-driven dynamic evolution are the two underpinnings of the platform. A scenario application—including the two primitive evolution actions—with the performance analysis is discussed to illustrate the feasibility.     

Current distribution in a liquid electrospray system with two counter-electrodes

We have experimentally studied the distribution of current in an electrospray system with two counter-electrodes. It is established that, at low values of the total current, its distribution between these electrodes is proportional to the electric field flux to a given electrode. As the total current grows, this proportionality changes toward more uniform distribution, probably, due to increased role of a space charge producing mutual repulsion of charged particles.

     

Gas/liquid oxygen-transfer to flowing lead alloys

For the application of liquid lead or lead-bismuth eutectic as coolant in nuclear reactors, the concentration of dissolved oxygen, determining the compatibility with steels used as construction materials, is of critical importance. In general, oxygen has to be added continuously to the liquid metal, so as to compensate for consumption by oxide formation on the surface of the reactor components. A potential method of keeping the oxygen concentration in a favourable range is transferring oxygen from an oxygen-containing gas, which is investigated on the basis of the experience from operating a gas/liquid transfer device in the CORRIDA loop. Conclusions on oxygen transfer in industrial-scale systems are drawn.     

Influence of Sr2+ on Calcium‐Deficient Hydroxyapatite Formation Kinetics and Morphology in Partially Amorphized α‐TCP

Hydration of partially amorphized α‐TCP powders with Sr²⁺ concentrations ranging from 0 to 10 mol% substitution for Ca²⁺ was analyzed by isothermal calorimetry and quantitative in‐situ XRD. Hydration of both crystalline α‐TCP and amorphous TCP (ATCP) forming CDHA was retarded to an increasing extent with increasing Sr²⁺ content. Sr²⁺ slightly reduced the crystallite size (XRD coherent scattering domains) of the CDHA formed during hydration, while the size of crystals visible under SEM was not noticeably affected. Reaction enthalpies of ΔH_{R(Sr‐α‐TCP→Sr‐CDHA)} = 122 ± 8 J/g_TCP and ΔH_{R(Sr‐ATCP→Sr‐CDHA)} = 257 ± 8 J/g_TCP were determined for the hydration of crystalline α‐TCP and ATCP containing 5 mol% Sr²⁺ substitution for Ca²⁺. This is comparable with the corresponding reaction enthalpies previously obtained for undoped samples, which are 106 ± 7 J/g_TCP for α‐TCP and 250 ± 7 J/g_TCP for ATCP.     

Comparison of thin epitaxial film silicon photovoltaics fabricated on monocrystalline and polycrystalline seed layers on glass

We fabricate thin epitaxial crystal silicon solar cells on display glass and fused silica substrates overcoated with a silicon seed layer. To confirm the quality of hot‐wire chemical vapor deposition epitaxy, we grow a 2‐µm‐thick absorber on a (100) monocrystalline Si layer transfer seed on display glass and achieve 6.5% efficiency with an open circuit voltage (V_OC) of 586 mV without light‐trapping features. This device enables the evaluation of seed layers on display glass. Using polycrystalline seeds formed from amorphous silicon by laser‐induced mixed phase solidification (MPS) and electron beam crystallization, we demonstrate 2.9%, 476 mV (MPS) and 4.1%, 551 mV (electron beam crystallization) solar cells. Grain boundaries likely limit the solar cell grown on the MPS seed layer, and we establish an upper bound for the grain boundary recombination velocity (S_GB) of 1.6x10⁴ cm/s. Copyright © 2014 John Wiley & Sons, Ltd.     

Partial oxidation of methane in hollow‐fiber membrane reactors based on alkaline‐earth metal‐free CO2‐tolerant oxide

The U‐shaped alkaline‐earth metal‐free CO₂‐stable oxide hollow‐fiber membranes based on (Pr_0.9La_0.1)₂(Ni_0.74Cu_0.21Ga_0.05)O_4+δ (PLNCG) are prepared by a phase‐inversion spinning process and applied successfully in the partial oxidation of methane (POM) to syngas. The effects of temperature, CH₄ concentration and flow rate of the feed air on CH₄ conversion, CO selectivity, H₂/CO ratio, and oxygen permeation flux through the PLNCG hollow‐fiber membrane are investigated in detail. The oxygen permeation flux arrives at approximately 10.5 mL/min cm² and the CO selectivity is higher than 99.5% with a CH₄ conversion of 97.0% and a H₂/CO ratio of 1.8 during 140 h steady operation. The spent hollow‐fiber membrane still maintains a dense microstructure and the Ruddlesden‐Popper K₂NiF₄‐type structure, which indicates that the U‐shaped alkaline‐earth metal‐free CO₂‐tolerant PLNCG hollow‐fiber membrane reactor can be steadily operated for POM to syngas with good performance. © 2014 American Institute of Chemical Engineers AIChE J, 60: 3587–3595, 2014