Synthesis of poly(ester amide)s composed of lactic acid and glycolic acid units by the bulk polycondensation of metal halide salts

Thermal polycondensation of the potassium salt of N‐methylchloroacetyl‐6‐aminohexanoic acid (LAHK) was found to be effective in the preparation of a new poly(ester amide) based on lactic acid units with a high yield and a moderate molecular weight. The reaction started in the solid state and proceeded through the formation of potassium chloride salt as the driving force. The use of a monomer having an amide linkage diminished the secondary reactions previously found in the synthesis of polylactide from 2‐halogenopropionates. The polymerization of potassium salt of N‐chloroacetyl‐6‐aminohexanoic acid (GAHK) took place in a similar temperature range as that of the 2‐chloropropionyl derivative; in this way, it was possible to conduct the copolymerization processes. The polymerization kinetics of LAHK and its mixture with GAHK was studied by Fourier transform infrared spectroscopy. The bulk polycondensation reaction was faster for GAHK than for LAHK, but the kinetic differences were not significant enough to prevent copolymerization at a temperature close to 160°C. Therefore, new degradable materials with tuned properties according to the glycolic acid/lactic acid content were obtained. ¹H‐NMR spectroscopy was useful for following the time evolution of the copolymerization process and for determining the final composition. Calorimetric data showed that all of the samples were thermally stable and that decreases in the melting temperature and enthalpy were observed at intermediate compositions. The existence of an eutectic point became proof that effective copolymerization was achieved in the thermal polycondensation process. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43197.     

On estimating the interface normal and curvature in piecewise linear interface calculation-volume of fluid approach for three-dimensional arbitrary meshes

Volume of fluid (VOF) method with its Piecewise Linear Interface Calculation (PLIC) reconstruction algorithm is one of the most popular approaches in numerical simulation of interfacial flows with a wide range of applications in different areas. In an effort to evaluate the similarity of the PLIC-generated planes in comparison with the exact interface, a point-cloud, based on the polygon centers of PLIC planes is extracted, which later is used to form a triangular grid that represents the estimated interface. The main objective of this article is to evaluate the interface geometrical properties based on the extracted triangular grid of the interface. The methods presented in this article, characterized by a higher spatially convergence ratio, are compared with the commonly used methods. The proposed methods are tested for two 3-dimensional general test cases, where an evident improvement is seen in calculation accuracy and spatial convergence of the errors of interface normal vector and curvature.     

Comparison between Ozonation and Photo-Fenton Processes for Pesticide Methomyl Removal in Advanced Greenhouses

So-called “Advanced Greenhouses” are a new approach to the concept of protected agriculture. Among other technological and structural improvements, these facilities give the possibility of recycling the irrigation surplus water, rich in lixiviates, salts, pesticides and its metabolites. After many cycles, the current is so concentrated on those substances that it becomes necessary for the presence of a membrane separation stage which brine, highly concentrated on those named pollutants, has to be treated before being sent to the public sewage system. Advanced Oxidation Processes, among other chemical treatments, can be considered an alternative to process this current effluent. In this work, concentrated aqueous solutions of methomyl as model pesticide (200 mg·L^?1) have been subjected to two of those processes: ozonation and photo-Fenton reaction. Analysis of the elimination of the pesticide itself and the grade of mineralization achieved have shown how, while the ozonation is the most effective process decomposing the pesticide (eliminating the total concentration in 60 minutes), the photo-Fenton reaction mineralizes successfully the 40% of the total organic load (the ozonation only can cope with 20%) but only decompose a 40% of the pesticide. Evolution of biodegradability and toxicity of the effluent along both processes was also analyzed. Intermediates generated both by ozonation and photo-Fenton did not increase the biodegradability of the treated effluents. Nevertheless, while acute toxicity just after 15 minutes of treatment with ozone is notably higher than for raw solution, and it is maintained till the end of the experiment (120 min), though, toxicity along photo-Fenton reaction has two growing and decreasing regions, always shows lower values than the provoked during ozonation. None of the two assayed processes has been proved to increase biocompatibility of highly concentrated methomyl solutions.     

Current distribution and recent development of sessile oak forests in Montseny (1956–2015)

There is a distribution limit of sessile oak (Quercus petraea) in the northern half of the Iberian Peninsula, with its southernmost populations located at the xeric limit for the species. We present here the current distribution of these populations in the Montseny Massif (N.E. Catalonia) and how the surface area they cover has developed over the last 50 years. Using a new high-resolution map (1:5000) we have calculated that Q. petraea currently covers 64.1 ha, and is found between 450 and 1150 m above sea level with a predominantly southern exposure, with the north-facing slopes being dominated by beech forests. With regard to its recent development, 44% of what is now dense forest was, in 1956, much more dispersed while 11% of it consisted of open spaces or shrubs. Such changes clearly show that, in Montseny, Q. petraea is well capable of regenerating its forest canopy as well as colonising adjacent environments.     

A Fittingness Factor-Based Spectrum Management Framework for Cognitive Radio Networks

In order to increase cognitive radios (CRs) operation efficiency, there has been an increasing interest in strengthening awareness level about spectrum utilisation. In this respect, this paper proposes to exploit the fittingness factor concept to capture the suitability of spectral resources exhibiting time-varying characteristics to support a set of heterogeneous CR applications. First, a new knowledge management functional architecture for optimizing spectrum management has been constructed. It integrates a set of advanced statistics capturing the influence of the dynamic radio environment on the fittingness factor. Then, a knowledge manager (KM) exploiting these statistics to monitor time-varying suitability of spectrum resources has been proposed to support the spectrum selection (SS) decision-making process. In particular, a new Fittingness Factor-based strategy combining two SS and spectrum mobility (SM) functionalities has been proposed, following either a greedy or a proactive approach. Results have shown that, with a proper fittingness factor function, the greedy approach efficiently exploits the KM support at low loads and the SM functionality at high loads to introduce significant gains in terms of the user dissatisfaction probability. The proactive approach has been shown to maintain the introduced performance gain while minimizing the signalling requirements in terms of spectrum handover rate.     

Effluent content from albedo degradation and kinetics at different temperatures in the enzymatic peeling of grapefruits

This work studies the variation in the effluent content from the reactor in enzymatic peeling of grapefruits, to determine the loss of soluble solids, reducing sugars and galacturonic acid, the main component from the albedo of the skin to model the solid–liquid transfer in this process. Experiments to study the efficiency of the enzymatic reaction include the effect of the temperature on the kinetics of albedo degradation to find an equation relating both variables and also the activation energy of this process, its value being 36.9 kJ/mol.     

Characterization by culture-dependent and culture-independent methods of the bacterial population of suckling-lamb packaged in different atmospheres

This study offers insight into the dynamics of bacterial populations in fresh cuts of suckling lamb under four different atmospheric conditions: air (A), and three Modified Atmosphere Packaging (MAP) environments, 15%O₂/30%CO₂/55%N₂ (C, commercial), 70%O₂/30%CO₂ (O), and 15%O₂/85%CO₂ (H) for 18 days. Microbial analyses by both conventional methods and PCR-DGGE were performed. Controversial and surprising results emerged from comparing both methods in relation to the genus Pseudomonas. Thus, conventional methods detected the presence of high numbers of Pseudomonas colonies, although PCR-DGGE only detected this genus in air-packaged samples. PCR-DGGE detected higher microbial diversity in the control samples (A) than in the modified atmospheres (C, O, H), having atmosphere H the fewest number of species. Brochothrix thermosphacta, LAB (Carnobacterium divergens and Lactobacillus sakei), and Escherichia spp. were detected in all the atmospheres throughout storage. Moreover, previously undescribed bacteria from lamb meat such as Enterobacter hormaechei, Staphylococcus equorum and Jeotgalicoccus spp. were also isolated in this study by DGGE. Additionally, qPCR analysis was used to detect and characterize strains of Escherichia coli. Virulence genes (stx₁, stx₂ and eae) were detected throughout storage in 97% of the samples. A high CO₂ atmosphere was the most effective packaging combination doubling storage time in comparison with commercial atmosphere.     

Effect of Hanger Flexibility on Dynamic Response of Suspension Bridges

Linearized continuum models of a suspended span with unloaded backstays and of a symmetric three-span suspension bridge are used to study the effects of the flexibility of the hangers on the vertical vibrations of suspension bridges. The models include elastic parabolic cables, flexible distributed hangers with variable length, and a stiffening girder represented by an elastic beam. It is shown that the free vibrations of a suspended span with unloaded backstays are controlled by five dimensionless parameters, while six dimensionless parameters control the response of a symmetric three-span suspension bridge. The results indicate that the flexibility of the hangers has a significant effect on the natural frequencies of the higher modes only when the relative stiffness of the girder is very high. The effects of hanger flexibility on the response of a suspension bridge to localized impulsive loads are also found to be small. These findings confirm the traditional, albeit previously untested, assumption of inextensible hangers. Finally, the threshold amplitudes of free vibrations that would result in the incipient slackening of the hangers are determined.     

Diffusion Coefficient Measurements Under Reduced Gravity Conditions by Means of the Shear Cell Technique. The Impact of Free Surfaces

A recent computational methodology is applied here in order to analyze the impact of free surfaces on the measurement of the interdiffusion coefficients if shear cells are used. Calculations indicate that the above-mentioned impact depends on the intensity of the solutal Marangoni convection but mainly on the number of active Marangoni segments, that is to say, on the extent of the free surface considered. Bulk solutal convection due to reduced gravity levels is not relevant if the gravity vector acts orthogonally to the gradient of concentration.     

Effect of raspberry pomace extracts isolated by high pressure extraction on the quality and shelf‐life of beef burgers

Raspberry pomace extracts isolated with supercritical carbon dioxide (SCE) and pressurised ethanol/water (ETE) were tested in beef burgers. Only ETE additives effectively inhibited lipid oxidation and the growth of microorganisms, as it was observed by measuring the changes of thiobarbituric acid reactive substances, bacterial counts and the content of O₂ and CO₂ during storage in the modified atmosphere package. ETE additives also demonstrated some meat colour preservation effects, which were assessed by the intensity of hamburger colour and metmyoglobin concentration. However, ETE additives did not alter burger's taste at the applied concentrations (up to 1%). It may be concluded that the most effective extracts possessing strong antioxidant and antimicrobial activity may be isolated from raspberry pomace by the pressurised liquid extraction with a hydroethanolic solvent; such extracts may be considered as promising additives in meat products for improving their stability and enriching with beneficial to health phytochemicals.