L-cystein modified bentonite-cellulose nanocomposite (cellu/cys-bent) for adsorption of Cu2+, Pb2+, and Cd2+ ions from aqueous solution

In this study, L-cystein modified bentonite-cellulose (cellu/cys-bent) nanocomposite was synthesized and characterized by XRD, FTIR, SEM with EDS, TGA, and TEM techniques. In order to optimize the process the effect of various operational parameters such as pH, adsorbent dosage, contact time, and temperature were also investigated. The adsorption experiments were carried out in initial concentrations range of 20-100 mg L^?1and the adsorbent affinity for metal ions was found to be in order of Cu²⁺ > Pb²⁺ > Cd²⁺. The optimum pH for adsorption of Cu²⁺ and Cd²⁺ was observed at 5 while for Pb²⁺ it was pH 6. Based on the Langmuir model, the maximum adsorption capacity of Cu²⁺, Pb²⁺, and Cd²⁺ at 50^?C was found to be 32.36, 18.52, and 16.12 mg g^?1, respectively. The Langmuir isotherm and pseudo-second order model were found to be better fitted than the other isotherms and kinetic models. The results of thermodynamic parameters confirmed the process to be endothermic and spontaneous in nature.     

Understanding the Corrosion Inhibition Mechanism of Mild Steel in Hydrochloric Acid by a Triazole Derivative: A Combined Experimental and Theoretical Approach

Protection of Metals and Physical Chemistry of Surfaces - The effect of an heterocycle triazole, namely (1-(4-methoxyphenyl)-1H-1,2,3-triazol-4-yl)methanol (MTM) on the corrosion of mild steel in...     

Vibration of antisymmetric angle-ply composite annular plates of variable thickness

Journal of Mechanical Science and Technology - Based on first order shear deformation theory, free vibrational behaviour of antisymmetric angle-ply composite annular plate is investigated. The...     

Bio‐oil from whole‐tree feedstock in resol‐type phenolic resins

Renewable chemicals are of growing importance in terms of opportunities for environmental concerns over fossil‐based chemicals. Lignocellulosic biomass can be converted into energy and chemicals via thermal and biological processes. Among all the transformation processes available, fast pyrolysis is the only one to produce a high yield of a liquid‐phase product called bio‐oil or pyrolysis oil. Bio‐oil is considered to be a promising substitute for phenol in phenol formaldehyde (PF) resin synthesis. In this work, bio‐based phenolic resins have been formulated, partially substituting phenol by bio‐oils from two Canadian whole‐tree species. The new resins are produced by replacing 25, 50, and 75% of phenol with bio‐oil for each species (three bioresins per species). The aim of this study is to synthesize renewable resins with competitive price and satisfactory quality. The results obtained have shown that substitution degree up to 50% provided reactivity and performance equal or superior to the pure PF resin. They also present a good storage stability, improved shear strength, and thermal stability comparable to the pure PF. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2014 , 131, 40014.     

Structural and magnetic properties of erbium doped nanocrystalline Li–Ni ferrites

A series of nanocrystalline Li_0.25Ni_0.5Fe_2.25−xEr_xO₄ (x=0.00, 0.02, 0.06, 0.08, and 0.10) ferrite powders, having a cubic spinel crystal structure and a low value of coercivity, was synthesized by the sol–gel auto-combustion route. The structure, morphology and magnetic properties of the prepared nanoferrites were characterized by powder X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and the magnetic property measurement system (MPMS). A well-defined single phase spinel structure is confirmed in all the samples by X-ray diffraction analysis. The lattice parameters of the samples increase slightly with increasing the erbium content. The crystallite size of the Er-doped samples is smaller than that of pure Li–Ni ferrite, and decrease regularly in the range of 36.0–14.5 nm. It has been observed that the magnetic properties of these ferrites are strongly influenced by the added erbium content. The magnetic measurements indicate that saturation magnetization (M_s) and coercivity (H_c) decrease gradually with the increase of Er content in the lattice.     

Effect of Ozonated Water Treatment on Fatty Acid Composition and Some Quality Parameters of Olive Oil

The organic olives from Çine-Ayd?n (Turkey) were washed with tap or ozonated water for 2 and 5 min, respectively, and pressed to olive oil. The effects of wash treatments on fatty acid composition and several quality parameters of the oils were determined. The maximum values after 2-min ozonated water washes were 9.58 meqO₂/kg, 0.73%, 2.44 and 0.16 for peroxide, free acid, K₂₃₂ and K₂₇₀ values, respectively, which were under the standard limits for extra-virgin olive oil. Five min of ozonated water washes also yielded acceptable results, except for a slight excess on K₂₃₂ value. Ozonated water washes had almost no effect on fatty acid composition.     

An adaptive and efficient buffer management scheme for resource-constrained delay tolerant networks

Provisioning buffer management mechanism is especially crucial in resource-constrained delay tolerant networks (DTNs) as maximum data delivery ratio with minimum overhead is expected in highly congested environments. However, most DTN protocols do not consider resource limitations (e.g., buffer, bandwidth) and hence, results in performance degradation. To strangle and mitigate the impact of frequent buffer overflows, this paper presents an adaptive and efficient buffer management scheme called size-aware drop (SAD) that strives to improve buffer utilization and avoid unnecessary message drops. To improve data delivery ratio, SAD exactly determines the requirement based on differential of newly arrived message(s) and available space. To vacate inevitable space from a congested buffer, SAD strives to avoid redundant message drops and deliberate to pick and discard most appropriate message(s) to minimize overhead. The performance of SAD is validated through extensive simulations in realistic environments (i.e., resource-constrained and congested) with different mobility models (i.e., Random Waypoint and disaster). Simulation results demonstrate the performance supremacy of SAD in terms of delivery probability and overhead ratio besides other metrics when compared to contemporary schemes based on Epidemic (DOA and DLA) and PRoPHET (SHLI and MOFO).     

Multi‐agent‐based sharing power economy for a smart community

In this paper, a multi‐agent‐based locally administrated power distribution hub (PDH) for social welfare is proposed that optimizes energy consumption, allocation, and management of battery energy storage systems (ESSs) for a smart community. Initially, formulation regarding optimum selection of a power storage system for a home (in terms of storage capacity) is presented. Afterwards, the concept of sharing economy is inducted in the community by demonstrating PDH. PDH is composed of multiple small‐scale battery ESSs (each owned by community users), which are connected together to form a unified‐ESS. Proposed PDH offers a localized switching mechanism that takes decision of whether to buy electricity from utility or use unified‐ESS. This decision is based on the price of electricity at ‘time of use’ and ‘state of charge’ of unified‐ESS. In response to power use or share, electricity bills are created for individual smart homes by incrementing or decrementing respective submeters. There is no buying or selling of power from PDH; there is power sharing with the concept of ‘no profit, no loss’. The objective of the proposed PDH is to limit the purchase of electricity on ‘high priced’ hours from the utility. This not only benefits the utility at crucial hours but also provides effective use of power at the demand side. The proposed multi‐agent system depicts the concept of sharing power economy within a community. Finally, the proposed model is analyzed analytically, considering on‐peak, off‐peak, and mid‐level (mid‐peak) prices of a real‐time price signal during 24 h of a day. Results clearly show vital financial benefits of ‘sharing power economy’ for end users and efficient use of power within the smart community. Copyright © 2017 John Wiley & Sons, Ltd.