Co‐agent mediated functionalization of LDPE/iPP mixtures for compatibilization of WEEE‐recovered polyvinylchloride

Mixtures of low density polyethylene/isotactic polypropylene (LDPE/iPP) 80/20 w/w were functionalized in the melt by using maleic anhydride (MAH) as the functionalizing agent, 2,5‐bis(tert‐butylperoxy)‐2,5‐dimethylhexane (L101) as the peroxide initiator and butyl 3‐(2‐furyl)propenoate (BFA) as a co‐agent suitable to prevent the degradation of iPP and to promote inter‐macromolecular reactions. The use of BFA was aimed at favouring the control of radical‐induced side reactions and the formation of interfacial graft copolymers. The functionalization degree and the modification of macromolecular architecture, which were evaluated by selective solvent extractions combined with IR, DSC and SEM analyses, were modulated by varying the L101/MAH/BFA ratio in the feed. The optimized product in terms of functionalization degree value and processability was successfully tested as compatibilizer in a polyolefin/polyvinylchloride mixture, where the polyvinylchloride component resulted from the management of waste of electrical and electronic equipment (WEEE). © 2016 Society of Chemical Industry     

Measuring gratitude in youth: Assessing the psychometric properties of adult gratitude scales in children and adolescents.

Before the developmental trajectory, outcomes, and related interventions of gratitude can be accurately and confidently studied among the youth, researchers must ensure that they have psychometrically sound measures of gratitude that are suitable for this population. Thus, considering that no known scales were specifically designed to measure gratitude in youth, this study aimed to answer an important question: Are the existing gratitude scales used with adults valid for use with youth? The present study is an empirical investigation, based on a large youth sample (N = 1,405) with ages ranging from 10 to 19 years old, of the psychometric properties of scores of the Gratitude Questionnaire-6 (GQ-6; M. E. McCullough, R. A. Emmons, & J.-A. Tsang, 2002), the Gratitude Adjective Checklist (GAC; M. E. McCullough, R. A. Emmons, & J.-A. Tsang, 2002), and the Gratitude Resentment and Appreciation Test (GRAT)-short form (M. Thomas & P. Watkins, 2003). Single-group and multiple-group confirmatory factor analyses indicated that the factor structures of these gratitude scales resemble those found with adults and were invariant across age groups. Scores of all three gratitude scales revealed acceptable internal consistency estimates (i.e., >.70) across age groups. Results showed that whereas scores of all three gratitude scales were positively correlated with each other for 14- to 19-year-olds, GRAT-short form scores tended to display relatively low correlations with scores of the other two measures for younger children (10–13 years old). Furthermore, the nomological network analysis showed that scores of all three gratitude scales were positively correlated with positive affect and life satisfaction scores across the age groups. The relationships with negative affect and depression scores, however, seemed dependent on the child's age. Pending results from subsequent research recommendations for researchers interested in studying gratitude in youth are offered. (PsycINFO Database Record (c) 2011 APA, all rights reserved)     

Detailing the effects of geometry approximation and grid simplification on the capability of a CFD model to address the benchmark test case for flow around a computer simulated person

This paper details the use of a simplified CFD model to predict the flow patterns around a computer simulated person in a displacement ventilated room. The use of CFD is a valuable tool for indoor airflow analysis and the level of complexity of the model being investigated is often critical to the accuracy of predictions. The closer the computational geometry is to the real geometry of interest, the more accurate the corresponding results are expected to be. High complexity meshes enable elaborated geometries to be resolved. The drawback is, however, their increased computational cost. The Fire Dynamics Simulator (FDS) model (Version 5) enabled to investigate the effects of geometry and computational grid simplification on the accuracy of numerical predictions. The FDS model is based on a three-dimensional Cartesian coordinate system and all solid obstructions are forced to conform to the underlying numerical grid which is a potential limitation when dealing with complex geometries such as those of a human body. Nevertheless, the developed computational model was based exclusively on a three-dimensional rectangular geometry. At the same time, in order to limit the total number of grid cells, a relatively coarser grid than those used for similar simulations was adopted in the investigation. The developed model was then assessed in terms of its capability of reproducing benchmark temperature and air velocity distributions. The extent to which numerical results depend on different simulation settings was detailed and different boundary conditions are discussed in order to provide some guidance on the parameters that resulted to affect the accuracy of the predicted results. The comparison between numerical results and measurements showed that a simplified CFD model can be used to capture the airflow characteristics of the investigated scenario with predictions showing a favourable agreement with experimental data at least in the qualitative features of the flow (the detailed investigation of the local airflow field near the occupant can not be probably conducted apart from considering the real human geometry). Significant influence of simulator geometry and of boundary conditions was found.     

Analytic Self-Consistent Condensates in Quasi-1D Superfluid Fermi Gases in the Andreev Approximation

We present an analytic method to approach Eilenberger equation and the associated Bogoliubov–de Gennes equation for quasi-1D fermionic gases. The problem of finding self-consistent inhomogeneous condensates is reduced to solving a certain class of nonlinear Schrödinger equations, whose most general solitonic solution is indeed available. Previously known solutions can be retrieved by taking appropriate limits in the parameters. The applicability of the method extends to systems with population imbalance and subject to external potential. In particular we show that fermionic zero-modes are robust against population imbalance.     

Mitochondrial alterations and autofluorescent conversion of Candida albicans induced by histatins

The mechanism of the candidacidal activity of histatins 3 and 5 (Hst) is still a matter of debate. Previous studies have indicated that Hst induce cell permeabilization, generation of reactive oxygen species (ROS) by mitochondria, inhibition of the respiratory chain, and energy-dependent cytotoxic release of ATP. On the other hand, the multiplicity of effects and the apparent contrast between experimental data continue to render the mechanism of Hst-induced killing of C. albicans unclear. In this investigation, using fluorescent probes (the potential-sensitive mitochondrial probe tetramethylrhodamine methyl ester perchlorate, TMRM; the ROS-sensitive probe dihydrofluorescein diacetate, DHF; the membrane-impermeant probe, calcein) and autofluorescence data we observed that Hst induce ROS generation by mitochondria undergoing a high energy swelling condition, accompanied by oxidation of cytosolic NAD(P)H and mitochondrial flavoproteins. ROS generation and swelling, attributable to an inhibition of the respiratory chain and to impairment of the K/H-exchanger, were followed by mitochondrial depolarization. Mitochondrial changes were accompanied by massive calcein influx, indicative of cell permeabilization, and prominent alterations of the cell size, shape, and optical density. The loss of proliferative activity was correlated, on a single cell basis, to the acquisition of a lipofuscin-like autofluorescence.     

Green Approach for Joint Management of Geo-Distributed Data Centers and Interconnection Networks

Every time an Internet user downloads a video, shares a picture, or sends an email, his/her device addresses a data center and often several of them. These complex systems feed the web and all Internet applications with their computing power and information storage, but they are very energy hungry. The energy consumed by Information and Communication Technology (ICT) infrastructures is currently more than 4% of the worldwide consumption and it is expected to double in the next few years. Data centers and communication networks are responsible for a large portion of the ICT energy consumption and this has stimulated in the last years a research effort to reduce or mitigate their environmental impact. Most of the approaches proposed tackle the problem by separately optimizing the power consumption of the servers in data centers and of the network. However, the Cloud computing infrastructure of most providers, which includes traditional telcos that are extending their offer, is rapidly evolving toward geographically distributed data centers strongly integrated with the network interconnecting them. Distributed data centers do not only bring services closer to users with better quality, but also provide opportunities to improve energy efficiency exploiting the variation of prices in different time zones, the locally generated green energy, and the storage systems that are becoming popular in energy networks. In this paper, we propose an energy aware joint management framework for geo-distributed data centers and their interconnection network. The model is based on virtual machine migration and formulated using mixed integer linear programming. It can be solved using state-of-the art solvers such as CPLEX in reasonable time. The proposed approach covers various aspects of Cloud computing systems. Alongside, it jointly manages the use of green and brown energies using energy storage technologies. The obtained results show that significant energy cost savings can be achieved compared to a baseline strategy, in which data centers do not collaborate to reduce energy and do not use the power coming from renewable resources.     

High‐pressure behavior of (Cs,K)Al4Be5B11O28 (londonite): A single‐crystal synchrotron diffraction study up to 26 GPa

The compressional behavior and the P‐induced deformation mechanisms at the atomic scale of (Cs,K)Al₄Be₅B₁₁O₂₈ (londonite, a ~7.31 Å and space group P3m) were investigated by in situ single‐crystal synchrotron X‐ray diffraction with a diamond anvil cell up to 26 GPa. No phase transition was observed within the P‐range investigated: this material exhibits isotropic compression (i.e., with cubic symmetry) in response to the applied pressure. Fitting the P–V data with a Birch‐Murnaghan isothermal equation of state, we obtained: V₀=390.8(3) ų, K_P0=212(7) GPa (β₀=1/K_P0=0.0047(1) GPa^?1) and K′=4.6(6). A series of structural refinements, based on the high‐pressure intensity data, were performed. The stiffness of londonite (similar to that of carbides) is governed by its close‐packing structure, and in particular by the very low compressibility of B‐ and Be‐tetrahedra and the modest compressibility of the Al‐octahedra. The Cs‐polyhedra are the most compressible units of the structure. The effects of pressure can be accommodated by intrapolyhedral compression or deformation, leading to a modest bulk compression. The high amount of boron in londonite (B₂O₃ ~50 wt%) makes its synthetic counterpart a potential neutron absorber. In addition, the high content of Cs makes londonite‐type materials as potential hosts for nuclear waste.     

Characterization of 12 Capsicum varieties by evaluation of their carotenoid profile and pungency determination

In this research 12 different varieties of Capsicum cultivars belonging to three species (Capsicum chinense, Capsicum annuum, Capsicum frutescens) and of various colour, shape, and dimension have been characterised by their carotenoids and capsaicinoids content. The berries were cultivated in the region Emilia-Romagna, in Northern Italy. The native carotenoid composition was directly investigated by an HPLC-DAD-APCI-MS methodology, for the first time. In total, 52 carotenoids have been identified and considerable variation in carotenoid composition was observed among the various cultivars investigated. Among the cultivars with red colour, some Habanero, Naga morich and Sinpezon showed an high β-carotene content, whereas Serrano, Tabasco and Jalapeno showed an high capsanthin content and the absence of β-carotene. Habanero golden and Scotch Bonnet showed a high lutein, α-carotene and β-carotene amounts, and Habanero orange was rich in antheraxanthin, capsanthin and zeaxanthin. Cis-cryptocapsin was present in high amount in Habanero chocolate.     

Rumination, emotion, and forgiveness: Three longitudinal studies.

In 3 studies, the authors investigated whether within-persons increases in rumination about an interpersonal transgression were associated with within-persons reductions in forgiveness. Results supported this hypothesis. The association of transient increases in rumination with transient reductions in forgiveness appeared to be mediated by anger, but not fear, toward the transgressor. The association of rumination and forgiveness was not confounded by daily fluctuations in positive affect and negative affect, and it was not moderated by trait levels of positive affectivity, negative affectivity, or perceived hurtfulness of the transgression. Cross-lagged associations of rumination and forgiveness in Study 3 more consistently supported the proposition that increased rumination precedes reductions in forgiveness than the proposition that increased forgiveness precedes reductions in rumination. (PsycINFO Database Record (c) 2010 APA, all rights reserved)