Comparison of morphology and properties of polyelectrolyte complex particles formed from chitosan and polyanionic biopolymers

Beads containing a chitosan core and a polyelectrolyte complex (PEC) shell were formed by the dropwise addition of chitosan to solutions containing sodium alginate, gellan, pectin, κ‐carrageenan, or poly(acrylic acid). Hydrogel cores were formed by crosslinking chitosan with genipin, a natural bifunctional crosslinker. The shell thickness was generally only a few molecules thick and was impermeable to the transport of macromolecules but not low molecular weight molecules. Increasing the number of anionic groups and the strength of the chitosan–polyanion interaction through selection of different anionic species increased the mechanical strength of the PEC shell by increasing the number of interaction points in the shell. Because the core and shell swelled differentially, with the shell able to swell much less than the core, increasing the shell strength increasingly constrained the degree of swelling that could be attained for the entire bead. The degree of swelling could therefore be controlled via the mechanical properties of the shell, which could in turn be explained by the molecular structure of the PEC shell. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 98: 1581–1593, 2005     

Effect of surface properties of different food contact materials on the efficiency of quaternary ammonium compounds residue recovery and persistence

Residues of quaternary ammonium compounds (QACs) remaining after sanitising were evaluated for a number of materials used in food plants. The residues were collected by swabs and measured using a spectrophotometric method. Surface topography and energy affected the QACs recovery. Highest percentage of QACs recovery was achieved for the tile material (102.2%) which had the most hydrophilic properties and least irregularities in surface topology, followed by stainless steel (82.1%). Meanwhile, the lowest recovery occurred in PVC (42.1%) and resin (44.3%) that exhibited hydrophobic characteristics and abrupt changes in height profile in a given surface area. Monitoring of QACs residues deposited on the surfaces after 7 days showed that the recovery of QACs in PVC and resin reduced significantly (P < 0.05), supposing that QACs might be degraded or interacted with the materials. However, no significant changes in residue recovery were observed for tiles and stainless steel surfaces after 7 days.     

Limits for hydrogen leaks that can support stable flames

Quenching and blowoff limits of hydrogen diffusion flames on small burners were observed. Four burner types, with diameters as small as 8 μm, were considered: pinhole burners, curved-wall burners, tube burners, and leaky fittings. In terms of mass flow rate, hydrogen had a lower quenching limit and a higher blowoff limit than either methane or propane. Hydrogen flames at their quenching limits were the weakest flames recorded to date, with mass flow rates and heat release rates as low as 3.9 μg/s and 0.46 W. The quenching limit for a hydrogen flame at a 6 mm leaky compression fitting was found to be 28 μg/s. This limit was independent of supply pressure (up to 131 bar) and about an order of magnitude lower than the corresponding limits for methane and propane.     

Quality and antioxidant capacity of fresh‐cut apple wedges enriched with honey by vacuum impregnation

The effect of vacuum impregnation (VI) of fresh‐cut apple wedges with honey, in presence and absence of a browning inhibitor on physicochemical, sensory and antioxidant properties over 7 days of storage at 2–4 °C was studied. Infusion of wedges with honey resulted in very little weight change indicating loss of internal water and ingress of honey carbohydrates into the wedges, hence the correlation coefficients with soluble solids content (r = ?0.91) and dry matter (r = ?0.77). Water infused samples showed the highest water uptake resulting in an increase in weight of 30%. Browning (P < 0.001) and firmness (P < 0.001) of apple wedges were the quality parameters most affected by VI. Samples dipped in browning inhibitor prior AS1 showed slightly better performance than undipped wedges with regard to browning and firmness. Total phenol content and antioxidant activity were significantly (P < 0.001) lower for honey infused apple wedges.     

Effects of texture and temperature on the kinetic of aroma release from model dairy custards

The structure of a foodstuff, and its perceived texture, are important characteristics involved in the sensory availability of flavour compounds released during the food consumption. This study identifies the effect of texture on the dynamic release of aroma compounds under simulated oral conditions (temperature and shearing). Two custard desserts, with two levels of texture but the same composition, flavoured with four aroma compounds, were analysed. The rheological behaviour of the custards and the release of aroma compounds (SPME analysis) were simultaneously followed, using a mouth simulator. The custard with the lowest texture level showed the highest kinetic release for all aroma compounds studied. With fast increase of temperature (10–25 °C), the decrease in viscosity of the custards and its impact on flavour release seemed to be less important than the heat transfer inside the products and its effect on partition of aroma compounds.     

Chilled ceilings and displacement ventilation

Displacement ventilation and chilled ceiling systems have been promoted as being ‘greener’ alternatives to other common forms of air conditioning system. They have been viewed by some of the building services industry as a welcome departure from the traditional ‘North American’ systems of air conditioning most frequently adopted to date, and could be viewed as a more suitable alternative for use in the moderate climatic conditions of the UK.This paper reviews some of the authors' recent and current work on the performance of these systems in office environments.     

Phase-locked injection laser arrays with variable stripe spacing

A phase-locked injection laser array is described which utilizes variations in spacing of identical lasing elements to vary the coupling between them. In general, phase-locked arrays have been fabricated as periodic structures with uniform coupling, although arrays with different element sizes have been described. An important advantage of the variable spacing array (VSA) structure over those designs is that the fundamental array mode can be readily matched to a uniform pumping profile across the entire array aperture. This allows the variable spacing arrays to be optimized for high-power operation. A coupled-mode analysis indicates that excellent matching of fundamental array mode to a uniform gain distribution can be obtained. However, for some array geometries the operation of array modes other than conventional 0 and 180° phase shift modes is enhanced. Variable spacing arrays have exhibited phase-locked behavior to CW outputs as high as 80 mW (7 elements) and single longitudinal mode operation to powers > 50 mW. Observation of the array emission patterns confirms the results of the coupled-mode analysis.