Mössbauer Analysis and Cation Distribution of Zn Substituted BaFe<Subscript>12</Subscript>O<Subscript>19</Subscript> Hexaferrites

Barium hexaferrite is a well-known hard magnetic material. Doping using nonmagnetic cation such as Zn²⁺ were found to enhance magnetization owing to preferential tetrahedral site (4 f ₁) occupancy of the zinc. However, the distribution of cations in hexaferrites depends on many factors such as the method of preparation, nature of the cation, and chemical composition. Here, Zn-doped barium hexaferrites (Ba_1?xZn_xFe₁₂O₁₉) were synthesized by sol-gel method. In this study, we summarized the magnetic properties of Ba_1?xZn_xFe₁₂O₁₉ (x = 0, 0.1, 0.2, 0.3) BaM, investigated by Mössbauer spectroscopy. Moreover, cation distribution was also calculated for all the products. Mössbauer parameters were determined from 57Fe Mössbauer spectroscopy and according to it, the replacement of Ba-Zn affects all parameters such as isomer shift, the variation in line width, hyperfine magnetic field, and quadrupole splitting. Cation distribution revealed the relative area of undoped BaM, 12k, 2a, and 4 f ₂ positions which are close to theoretical values.     

Mapping past,current and future energy research trend in Pakistan: a scientometric assessment

This work describes the contribution of researchers in the field of the energy from Pakistan in the period 1990–2016. A scientometric approach was applied to analyze the scientific publications in the field using the Scopus Elsevier database. Different aspects of the publications were analyzed, such as publication type, major research areas, journals, citations, authorship pattern, affiliations as well as the keyword occurrence frequency. The present research trends are analyzed and future research directions are outlined. The impact factor, h-index and number of citations were used to investigate the strength of active institutes, authors, and journals in the field of the energy in Pakistan. From 1990 to 2016, 991 articles have been published by 2139 authors from 213 research institutes. The total number of citations and impact factor are 10,287 and 2301 respectively, corresponding to 10 citations per paper and an impact factor of 2.32 per publication. The research articles originate primarily from COMSATS, NUST, PIEAS, and PINSTECH. Pakistan has published 60% of publication with the collaboration of the foreign institutes, mainly from the United States, the United Kingdom, China and Malaysia. The core research activities in the field are mainly focused on resource assessment, energy policy, energy efficiency, feasibility study, energy economics, and performance assessment. The most productive journal, author, institution, are renewable & sustainable energy review, Shahbaz M., and COMSATS, respectively.     

Single-molecule devices: materials,structures and characteristics

This review article provides a brief survey of materials, structures and current state-of-the-art techniques used to measure the charge conduction characteristics of single molecules. Single molecules have been found to exhibit several unique functionalities including rectification, negative differential resistance and electrical bistable switching, all of which are necessary building blocks for the development and configuration of molecular devices into circuits. Conjugated organic molecules have received considerable interest for their low fabrication cost, three dimensional stacking and mechanical flexibility. Furthermore, the ability of molecules to self-assemble into well-defined structures is imperative for the fabrication of molecule based circuits. The theoretical formalisms are presented for studying single-molecule Coulomb blockade effects, ballistic transport in a molecular chain and electromagnetic coupling between a surface-plasmon field and a single molecule. Moreover, the experimental current–voltage results are discussed using basic principles of carrier transport mechanisms.     

Identifying the Origin of Ti3+ Activity toward Enhanced Electrocatalytic N2 Reduction over TiO2 Nanoparticles Modulated by Mixed-Valent Copper

The ambient electrocatalytic N₂ reduction reaction (NRR) enabled by TiO₂ has attracted extensive recent attention. Previous studies suggest the formation of Ti³⁺ in TiO₂ can significantly improve the NRR activity, but it still remains unclear what kinds of Ti³⁺ are effective. Herein, it is demonstrated that mixed-valent Cu acts as an effective dopant to modulate the oxygen vacancy (V_O) concentration and Ti³⁺ formation, which markedly improves the electrocatalytic NRR performance. In 0.5 m LiClO₄, this electrocatalyst attains a high Faradic efficiency of 21.99% and a large NH₃ yield of 21.31 µg h⁻¹ mg_cat.⁻¹ at –0.55 V vs reversible hydrogen electrode, which even surpasses most reported Ti-based NRR electrocatalysts. Using density function theory calculations, it is evidenced that mixed-valent Cu ions modulate the TiO₂ (101) surface with multiple oxygen vacancies, which is beneficial for generating different Ti³⁺ 3d¹ defect states localized below the Fermi energy. N₂ activation and adsorption are effectively strengthened when Ti³⁺ 3d¹ defect states present the splitting of e_g and t_2g orbitals, which can be modulated by its coordination structure. The synergistic roles of the three ion pairs formed by the V_O defect, including Cu¹⁺–Ti⁴⁺, Ti³⁺–Ti⁴⁺ and Ti³⁺–Ti³⁺, are together responsible for the enhanced NRR performance.     

Standard potentials of the silver-silver iodide electrode in aqueous mixtures of ethanol and propan-2-ol at different temperatures. Free energies and entropies of transfer of hydroiodic acid at 25°

Standard potentials of E^θ of the silver-silver iodide electrode in ethanol + water and propan-2-ol + water mixtures have been determined from the emf of the cell Pt, H₂ (g, 1 atm)|HI(itm), solvent| Agl-Ag at seven temperatures ranging from 10 to 40° for ethanol and from 5 to 35° for propan-2-ol. Free energies ΔS^gq_itt of transfer HI obtained therefrom have been briefly discussed in the light of ion-solvent interactions and solvent structure.     

An Improved Harmonic Load Flow Formulation

Abstract

The paper contributes an improved harmonic load flow formulation with fewer convergence problems but the same accurate results as traditional formulations. The proposed formulation approaches the harmonic load flow problem as a single nonlinear equation system where the harmonic bus voltage influence on nonlinear load behavior is considered and harmonic bus voltages at linear buses are not included as unknowns. This formulation allows any sort of nonlinear load to be considered and uses the Newton-Raphson method with true Jacobian matrix to reduce the inherent increase in the number of iterations caused by the presence of highly distorted bus voltages. The numerical results obtained when solving a three-bus network operating under highly distorted bus voltages using traditional harmonic load flow formulations and the improved formulation are comparatively discussed.     

Generation of electrical energy using lead zirconate titanate (PZT-5A) piezoelectric material: Analytical,numerical and experimental verifications

Energy harvesting is the process of attaining energy from the external sources and transforming it into usable electrical energy. An analytical model of piezoelectric energy harvester has been developed to determine the output voltage across an electrical circuit when it is forced to undergo a base excitation. This model gives an easy approach to design and investigate the behavior of piezoelectric material. Numerical simulations have been carried out to determine the effect of frequency and loading on a Lead zirconate titanate (PZT-5A) piezoelectric material. It has been observed that the output voltage from the harvester increases when loading increases whereas its resonance frequency decreases. The analytical results were found to be in good agreement with the experimental and numerical simulation results.     

Industrial symbiosis: high purity recovery of metals from Waelz sintering waste by aqueous SO2 solution

Sintering operation in the production of Zn, Cd, and Pb by Waelz process produces a powdery waste containing mainly (about 70%) ZnO, CdO, and PbO. The waste may be referred to as Waelz sintering waste (WSW). The aim of this study is to develop a process for the separation and recovery of the metals from WSW with high purities. The process is based on the dissolution of the WSW in aqueous SO2 solution. The research reported here concentrated on the effect of some important operational parameters on dissolution process. The parameters investigated and their ranges were as follows: SO(2) gas flow rate (V); 38-590 ml/min, stirring speed (W); 100-1000 rpm, reaction temperature (T); 13-60 degrees C, reaction time (t); 1-16 min, and solid-liquid ratio (S/L); 0.1-0.5 g/ml. The results showed that the dissolution rate increased with increasing W, V, and S/L and decreasing T. The best dissolution conditions were found to be V=325 ml/min, W=600 rpm, t=6 min, T=21 degrees C, and S/L=0.1g/ml. Separation of Zn from Cd involved precipitation of ZnSO3 from a mixture solution. The best pH level for the precipitation was observed to be 6.     

Cofilin Signaling in the CNS Physiology and Neurodegeneration

All eukaryotic cells are composed of the cytoskeleton, which plays crucial roles in coordinating diverse cellular functions such as cell division, morphology, migration, macromolecular stabilization, and protein trafficking. The cytoskeleton consists of microtubules, intermediate filaments, and actin filaments. Cofilin, an actin-depolymerizing protein, is indispensable for regulating actin dynamics in the central nervous system (CNS) development and function. Cofilin activities are spatiotemporally orchestrated by numerous extra- and intra-cellular factors. Phosphorylation at Ser-3 by kinases attenuate cofilin’s actin-binding activity. In contrast, dephosphorylation at Ser-3 enhances cofilin-induced actin depolymerization. Cofilin functions are also modulated by various binding partners or reactive oxygen species. Although the mechanism of cofilin-mediated actin dynamics has been known for decades, recent research works are unveiling the profound impacts of cofilin dysregulation in neurodegenerative pathophysiology. For instance, oxidative stress-induced increase in cofilin dephosphorylation is linked to the accumulation of tau tangles and amyloid-beta plaques in Alzheimer’s disease. In Parkinson’s disease, cofilin activation by silencing its upstream kinases increases α-synuclein-fibril entry into the cell. This review describes the molecular mechanism of cofilin-mediated actin dynamics and provides an overview of cofilin’s importance in CNS physiology and pathophysiology.     

A review on the role of materials science in solar cells

The demand for energy of modern society is constantly increasing. The desire for environmental-friendly alternative energy resources with the least dependency on fossil fuels is growing. Solar energy is an important technology for many reasons and is worthy of urgent attention. Indeed, it has experienced rapid growth over the last few years. It is expected to become truly main stream when the breakeven of high performance is achieved and its cost becomes comparable with other energy sources. Various approaches have been proposed to enhance the efficiency of solar cells. This paper reviews some current initiatives and critical issues on the efficiency improvement of solar cells from the material sciences and chemistry perspectives.