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91.
MiquelA. Perics David Castellnou Israel Rodríguez Antoni Riera Lluís Sol 《Advanced Synthesis \u0026amp; Catalysis》2003,345(12):1305-1313
A functional analogue of (R)‐2‐piperidino‐1,1,2‐triphenylethanol was synthesized and anchored to different polymeric supports by a position remote from the active region. This strategy, leading to what we call a tail‐tied ligand, allows for the achievement of the optimal transition state geometry in the catalytic process. The catalytic activity of the resulting heterogenized ligands was investigated by online FTIR analysis. The optimum polymer was assayed in the addition reaction of diethylzinc to a large family of aldehydes rendering essentially intact high catalytic activity and enantioselectivity compared to its homogeneous counterpart. 相似文献
92.
Preparation of conjugated linoleic acid from safflower oil 总被引:5,自引:0,他引:5
David W. L. Ma Antoni A. Wierzbicki Catherine J. Field Michael T. Clandinin 《Journal of the American Oil Chemists' Society》1999,76(6):729-730
Synthetically prepared mixtures of conjugated linoleic acid (CLA) are widely used in animal and cell culture studies to investigate
the potential effects of the Δ9c, 11t-18:2 isomer found in food products from ruminant animals. Alkali isomerization of linoleic acid is a common method used in
the synthesis of a mixture of CLA isomers containing predominantly the Δ9c, 11t-18:2 and Δ10t, 12c-18:2 isomers. Some biological activity might also be mediated by the Δ10t, 12c-18:2 isomer. Currently few published methodologies exist describing procedures for the enrichment of these two isomers. A
method is described herein to take advantage of an inexpensive oil, safflower oil, for use in synthesis of CLA and a procedure
to enrich the Δ10t, 12c-18:2 isomer. 相似文献
93.
Antoni Femenia James A Robertson Keith W Waldron Robert R Selvendran 《Journal of the science of food and agriculture》1998,77(4):511-518
By-products arising from vegetable processing activities have been assessed in relation to their potential application as sources of dietary fibre supplements in refined foods. Sources used were fresh cauliflower, globe artichoke and chicory witloof. Non-starch polysaccharide (NSP) content and composition of selected parts of each plant source have been measured from alcohol insoluble residues (AIR) and by fibre analysis, complemented by methylation analysis to characterise structural features of component polysaccharides. Results indicate that cauliflower upper stem NSP was similar to the floret (∽25 g kg−1 fresh weight) and each was rich in pectic polysaccharides. Cauliflower lower stem was enriched in NSP (∽66 g kg−1) due mainly to cellulose and xylan deposition, which resulted in a proportionate decrease in pectic polysaccharides. Artichoke stem (∽38 g NSP kg−1) was similar to the receptacle (∽34 g NSP kg−1) but bracts were heavily lignified. Chicory root and leaf bud were each rich in pectic polysaccharides but NSP content was much higher in the root (∽46 g kg−1) than the leaf (∽8 g kg−1). Results indicate that processing by-products, eg cauliflower upper stem, artichoke stem and chicory root, could prove useful as sources of pectic polysaccharide-rich supplements. However, polysaccharide composition and glycosidic linkage pattern also identified important structural differences between sources. The importance of ‘fibre type’ when considering development of food supplements is discussed. © 1998 SCI. 相似文献
94.
95.
Lactobacillus delbrueckii subsp lactis strain CIDCA 133 inhibits nitrate reductase activity of Escherichia coli 总被引:3,自引:0,他引:3
The aim of the present work was to investigate the effect of strain CIDCA 133 on the nitrate reductase activity of a non-pathogenic Escherichia coli strain. Suspensions containing different ratios of the strains under study were coincubated in MRS or MRS without glucose. In some experiments lactobacilli were killed by UV treatment. The nitrate reductase activity was determined by using a diazotization reaction for nitrite. Presence of live lactobacilli leads to a dose-response diminution in the specific nitrate reductase of E. coli even when no acidification occurred. Killing of lactobacilli by UV treatment completely abolished the anti-nitrate reductase effect. In addition, the effect was only partially observed with filtered spent culture supernatants of lactobacilli. Lactobacillus delbrueckii subsp lactis strain CIDCA 133 is able to antagonize the nitrate reductase activity of E. coli. This effect is neither due to a diminution of the viability of E. coli nor is depending on the acidification of the medium by the lactobacilli. Viability is needed for maximal anti-nitrate reductase activity. Modulation of undesirable enzymatic activities of intestinal microorganisms by means of selected microorganisms constitutes a further insight on the mechanisms by which probiotics lead to beneficial effects. Administration of probiotic strains able to modulate microbial intestinal activities could lead to a protection of the host against harmful effects of some members of the intestinal microflora. 相似文献
96.
Mediterranean diets supplemented with virgin olive oil and nuts enhance plasmatic antioxidant capabilities and decrease xanthine oxidase activity in people with metabolic syndrome: The PREDIMED study 下载免费PDF全文
97.
Daniel Casellas Antoni Lara David Frómeta David Gutiérrez Sílvia Molas Lluís Pérez Johannes Rehrl Clemens Suppan 《Metallurgical and Materials Transactions A》2017,48(1):86-94
The edge fracture is considered as a high risk for automotive parts, especially for parts made of advanced high strength steels (AHSS). The limited ductility of AHSS makes them more sensitive to the edge damage. The traditional approaches, such as those based on ductility measurements or forming limit diagrams, are unable to predict this type of fractures. Thus, stretch-flangeability has become an important formability parameter in addition to tensile and formability properties. The damage induced in sheared edges in AHSS parts affects stretch-flangeability, because the generated microcracks propagate from the edge. Accordingly, a fracture mechanics approach may be followed to characterize the crack propagation resistance. With this aim, this work addresses the applicability of fracture toughness as a tool to understand crack-related problems, as stretch-flangeability and edge cracking, in different AHSS grades. Fracture toughness was determined by following the essential work of fracture methodology and stretch-flangeability was characterized by means of hole expansions tests. Results show a good correlation between stretch-flangeability and fracture toughness. It allows postulating fracture toughness, measured by the essential work of fracture methodology, as a key material property to rationalize crack propagation phenomena in AHSS. 相似文献
98.
99.
Abstract The non-diffractive vector Bessel beams of an arbitrary order are examined as both the solution to the vector Helmholtz wave equation and the superposition of vector components of the angular spectrum. The transverse and longitudinal intensity components of the vector Bessel beams are analysed for the radial, azimuthal, circular and linear polarizations. The radially and azimuthally polarized beams are assumed to be formed by the axicon polarizers used with the initially unpolarized or linearly polarized light. Conditions in which the linearly polarized Bessel beams can be approximated by the scalar solutions to the wave equation are also discussed. 相似文献
100.
Producers, retailers and other food chain actors increasingly recognize that consumer concerns for good animal welfare represent a business opportunity that could be profitably incorporated into their commercial strategies. Therefore, during the last decade, numerous trade groups (producers, processors, retailers and restaurant chains) have developed certification systems with their suppliers which include elements of animal welfare. The Welfare Quality® project has developed an integrated and standardised welfare assessment system based on twelve welfare criteria grouped into four main principles (good feeding, good housing, good health and appropriate behaviour) according to how they are experienced by animals. One of the innovations of the Welfare Quality® assessment system is that it focuses more on outcome measures (e.g. directly related to animal body condition, health aspects, injuries, behaviour, etc.). This paper has the objective to discuss the rationale behind the welfare assessment and to describe the Welfare Quality® assessment of pigs and cattle at the slaughterhouse. 相似文献