Desorption isotherms,net isosteric heat and the effect of temperature and water activity on the antioxidant activity of two varieties of onion (Allium cepa L)

The standard static gravimetric method was used to determine moisture desorption isotherms (MDIs) of two onion varieties (Goudami and Galmi Violet) at 30 °C, 45 °C and 60 °C in the water activity ranging from 0.055 to 0.83. The combined effects of temperature and water activity on the antioxidant activities of the onion varieties were also studied. GAB, Oswin, Smith and BET equations were tested to fit the experimental data. The net isosteric heat of sorption was calculated. Equilibrium moisture content (EMC), total phenolic content (TPC) and antiradical activity were also measured. The isotherm and the EMC vary significantly with the onion variety and drying temperature, irrespective of water activity (a_w). Desorption isotherms were best described by the GAB model. The maximum net isosteric heats for Galmi Violet (32.58 kJ mol^?1) were greater than those of Goudami (23.50 kJ mol^?1) at each EMC. The TPC and antiradical activity of the Galmi Violet were significantly (P ≤ 0.05) higher than that of the Goudami at all investigated temperatures and water activities.     

Defect structures in silicon merged epitaxial lateral overgrowth

Merging of two epitaxial lateral overgrowth fronts has been achieved to produce thin silicon-on-insulator (SOI) structures. The electronic quality of the material is generally of high quality; however, at the merger interface are defects associated with improper merging. Defects at the oxide/silicon interface and the merging interface were characterized using transmission electron microscopy. Device performance indicated the need for a process modification to improve the material quality for potential electronic applications.     

Regeneration of spent earth in aqueous medium

A simple method of regeneration of spent earth at a relatively low temperature has been developed. Deoiled spent earth was regenerated in the form of a slurry using water as an aqueous phase, in the temperature range of 170–270°C. The effects of temperature, slurry concentration and cycle of regeneration have been studied. An attempt has been made to discern the controlling mechanism. Regenerated earth from the present method does not impart any malodor to the oil as against theramlly regenerated earth.     

Analysis of iron- and sulfur-oxidizing bacteria in a treatment plant of acid rock drainage from a Japanese pyrite mine by use of ribulose-1, 5-bisphosphate carboxylase/oxygenase large-subunit gene

Iron- and sulfur-oxidizing bacteria in a treatment plant of acid rock drainage (ARD) from a pyrite mine in Yanahara, Okayama prefecture, Japan, were analyzed using the gene (cbbL) encoding the large subunit of ribulose-1, 5-bisphosphate carboxylase/oxygenase (RubisCO). Analyses of partial sequences of cbbL genes from Acidithiobacillus ferrooxidans, Acidithiobacillus thiooxidans and Acidithiobacillus caldus strains revealed the diversity in their cbbL gene sequences. In contrast to the presence of two copies of form I cbbL genes (cbbL1 and cbbL2) in A. ferrooxidans genome, A. thiooxidans and A. caldus had a single copy of form I cbbL gene in their genomes. A phylogenetic analysis based on deduced amino acid sequences from cbbL genes detected in the ARD treatment plant and their close relatives revealed that 89% of the total clones were affiliated with A. ferrooxidans. Clones loosely affiliated with the cbbL from A. thiooxidans NB1-3 or Thiobacillus denitrificans was also detected in the treatment plant. cbbL gene sequences of iron- or sulfur-oxidizing bacteria isolated from the ARD and the ARD treatment plant were not detected in the cbbL libraries from the treatment plant, suggesting the low frequencies of isolates in the samples.     

Thermal Analysis of Orthotropic Pin Fins With Contact Resistance: A Closed-Form Analytical Solution

Light weight composite fins are considered to deal with thermal management problems for many microelectronic components. These composite fins are inherently anisotropic, therefore cannot be handled by a traditional one-dimensional approach; however, these materials can be designed to provide high thermal conductivity values in the desired direction to handle application-specific demands. In this article, we present analytical solutions for temperature distribution and heat transfer rate for orthotropic two-dimensional pin fins subject to convective-tip boundary condition and the contact resistance at the fin base. The generalized results are presented in terms of fin aspect ratio (fin length-to-radius ratio) and three dimensionless fin parameters that relate the internal conductive resistance to three convective resistances discussed in terms of dimensionless variables such as contact, tip, and axial Biot numbers, in addition to the axial-to-radial conductivity ratio. Several special cases including the insulated tip boundary condition are presented. It is demonstrated that the temperature distribution and heat transfer rate from the two-dimensional isotropic annular fin introduced earlier in the literature, can easily be recovered from the benchmark solutions presented in this article. Furthermore, dimensionless heat transfer rates are presented for the pin fins with contact resistance that can help to solve design and optimization problems of many natural-to-forced convection composite fins that are typically encountered in many microelectronic applications.     

Influence of multiple nitriding on the case hardening of H13 tool steel: experimental and numerical investigation

Controlled gas nitriding represents one of the most important factors in enhancing the service life of AISI H13 steel dies used for the hot extrusion of aluminum alloys. Such surface-hardening treatment is used repeatedly to re-harden the die surface, which has been exposed to high temperature and abrasion by extruding the aluminum alloy, resulting in the wearing away of the existing nitride layer. Therefore, after certain extrusion cycles, dies require re-nitriding. In the present work, the influence of repeated nitriding on AISI H13 steel is studied. Single-, double-, and triple-nitrided samples, treated under controlled two-stage gas nitriding process, have been included in the study to evaluate their nitride layer morphology, hardness, case depth, and quality. Both experimental and numerical results are presented and compared. In the experimental part, the nitride layers are characterized using different techniques including optical microscopy, scanning electron microscopy, X-ray diffraction analysis, microhardness analysis, and energy-dispersive spectrometry technique. A sequentially coupled heat diffusion analysis of re-nitriding treatments are also conducted numerically using finite element code, ABAQUS. The numerically predicted results are in close agreement with experimental results in terms of nitride layer growth and nitrogen concentration distribution in the diffusion zone. The experimental results reveal that multiple-nitriding treatment on H13 steel has a significant effect on compound layer thickness and its phases, diffusion zone depth and its microstructure, hardness–depth profile, and nitride case depth. It was found that excessive cumulative nitriding time during multiple-nitriding treatment results in greater nitride depth and a significant increase in hardness with deeper effect due to the dense and deeper precipitation of nitrides in the diffusion zone. Multiple-nitrided samples show oxidation and porosity in the near-surface part of the nitrided layer due to the interaction of iron with oxygen of the air upon decomposition of iron nitrides in the compound layer during re-nitriding. This results in reduced toughness and hardness in the near-surface part of the nitride layers.     

Molecular Shape Recognition through Self-Assembled Molecular Ordering: Evaluation with Determining Architecture and Dynamics

The relationship between molecular gel-forming compound-based double-alkylated l-glutamide-derived functional group-integrated organic phase (Sil-FIP) structure and chromatographic performance is investigated and compared with widely used alkyl phases (C(30), polymeric and monomeric C(18)) as references. The functional group-integrated molecular gel on silica is chemically designed newly in a way that the weak interaction sites are integrated with high orientation and high selectivity can be realized by multiple interactions with the solutes. Its functions can be emphasized by being immobilizable with a terminal carboxyl group and the fact that five amide bonds including β-alanine subunit are integrated per molecule. Furthermore, its self-assembling function can be detected by monitoring of the chiroptical property. Temperature-dependent circular dichroism (CD) intensity was determined as an indicator of chirality for the gel forming compounds. (13)C cross-polarization magic angle spinning (CP/MAS) NMR spectra of the Sil-FIP phase indicate that predominance of gauche conformations exists at higher temperature (above 30 °C). (29)Si CP/MAS NMR were carried out to investigate the degree of cross-linking of the silane and silane functionality of the modified silica. Temperature-dependent (13)C CP/MAS NMR and suspended-state (1)H NMR measurements of the Sil-FIP phase exhibit the dynamic behavior of the alkyl chains. To correlate the NMR and CD results with temperature-dependent chromatographic studies, standard reference materials (SRM 869b and SRM 1647e), column selectivity test mixture for liquid chromatography was employed. Additional shape selectivity text mixtures were also used to clarify the mechanism of shape selectivity performance of Sil-FIP compared with commercially available columns. The evaluation with the spectroscopic and chromatographic analyses presents very important information on the surface morphology of the new organic phase and the molecular recognition process. Integrated and ordered functional groups were investigated to be the main driving force for very high molecular shape selectivity of the Sil-FIP phase.     

Superparamagnetic iron oxide nanoparticle attachment on array of micro test tubes and microbeakers formed on p-type silicon substrate for biosensor applications

A uniformly distributed array of micro test tubes and microbeakers is formed on a p-type silicon substrate with tunable cross-section and distance of separation by anodic etching of the silicon wafer in N, N-dimethylformamide and hydrofluoric acid, which essentially leads to the formation of macroporous silicon templates. A reasonable control over the dimensions of the structures could be achieved by tailoring the formation parameters, primarily the wafer resistivity. For a micro test tube, the cross-section (i.e., the pore size) as well as the distance of separation between two adjacent test tubes (i.e., inter-pore distance) is typically approximately 1 μm, whereas, for a microbeaker the pore size exceeds 1.5 μm and the inter-pore distance could be less than 100 nm. We successfully synthesized superparamagnetic iron oxide nanoparticles (SPIONs), with average particle size approximately 20 nm and attached them on the porous silicon chip surface as well as on the pore walls. Such SPION-coated arrays of micro test tubes and microbeakers are potential candidates for biosensors because of the biocompatibility of both silicon and SPIONs. As acquisition of data via microarray is an essential attribute of high throughput bio-sensing, the proposed nanostructured array may be a promising step in this direction.     

Low-temperature growth of well-aligned ZnO nanorods/nanowires on flexible graphite sheet and their photoluminescence properties

We have grown large-scale well-aligned ZnO nanorods/nanowires on commercial flexible graphite sheet (FGS) at low temperature via chemical vapor deposition method. The products were characterized by X-ray diffraction, scanning electron microscopy, and high-resolution transmission electron microscopy. The effects of the growth temperature and oxygen flow rate on the morphology of ZnO nanostructures have been investigated. The growth mechanism of ZnO is found to be a self-catalytic vapor–solid process assisted by the immiscibility of ZnO with graphite. The as-grown ZnO/FGS products show strong green emission and their photoluminescence properties can be tuned by changing growth condition or annealing treatment.