Paradoxes of masochism.

Presents 5 paradoxes of masochism, which delineate intrapsychic and interpersonal patterns in which pain and "unpleasure" seem to become aims. Elements of the apparent contradictions inherent in masochistic disorders and some of their transference and countertransference implications are discussed. The 5 paradoxes highlight (1) intrapsychic conflict around issues of drive and defense, (2) conflict between autonomy and gratification through depending on others, (3) pain inherent in the quest for perfection, (4) pain associated with attachment to the object, and (5) pleasure evokes physical pain and injury, a screen for early dire physical trauma. Case material illustrates each paradox. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Biosorption of nickel ions from aqueous solutions by natural and modified peanut husks: equilibrium and kinetics

The toxicity and non‐biodegradation of heavy metals, as well as their tendency to accumulate in the soils, water resources and the living organisms, makes them the significant environmental pollutants. Therefore, the reduction and elimination of heavy metal ions from aqueous systems is very important from the ecological, nutritional and environmental reasons. The aim of this study is to investigate whether the natural peanut husks, an agricultural waste, and their chemically modified form are capable to remove Ni(II) ions from aqueous solutions using batch method and to compare their efficiency. The effects of the mass of the natural peanut husks and the initial pH of the solution were studied to find the optimal conditions for maximal removal of Ni(II) ions. MATLAB/Curve Fitting Toolbox was implemented to determine the adequate adsorption isotherm as well as to optimise the equilibrium state of the investigated systems.     

Structure‐Based Mechanism of Oleate Hydratase from Elizabethkingia meningoseptica

Hydratases provide access to secondary and tertiary alcohols by regio‐ and/or stereospecifically adding water to carbon‐carbon double bonds. Thereby, hydroxy groups are introduced without the need for costly cofactor recycling, and that makes this approach highly interesting on an industrial scale. Here we present the first crystal structure of a recombinant oleate hydratase originating from Elizabethkingia meningoseptica in the presence of flavin adenine dinucleotide (FAD). A structure‐based mutagenesis study targeting active site residues identified E122 and Y241 as crucial for the activation of a water molecule and for protonation of the double bond, respectively. Moreover, we also observed that two‐electron reduction of FAD results in a sevenfold increase in the substrate hydration rate. We propose the first reaction mechanism for this enzyme class that explains the requirement for the flavin cofactor and the involvement of conserved amino acid residues in this regio‐ and stereoselective hydration.     

The Antimicrobial Effect of Spice‐Based Marinades against Campylobacter jejuni on Contaminated Fresh Broiler Wings

The antimicrobial effect of spice‐based marinades against Campylobacter jejuni on inoculated fresh broiler wings was investigated. Experiments were carried out with 1 strain of C. jejuni and 6 marinades. Four experimental marinades were composed for the study and contained spices (thyme, rosemary, basil, marjoram, and so on) and different combination of bioactive compounds. Two marinades were commercial and contained spices (black pepper, sweet red pepper, and so on) and chemical additives (monosodium glutamate, sodium diacetate, calcium lactate), 1 commercial marinade was also enriched with bioactive compounds (linalool, cinnamaldehyde, lactic acid). Total aerobic bacterial count was examined to estimate the possible effect of tested marinades on the shelf‐life of marinated broiler wings. Study revealed that thyme‐based marinade was the most effective against C. jejuni on broiler wings and reduced the numbers of campylobacters by 1.04 log colony forming unit (CFU)/g (P ≤ 0.05) during storage for 168 h at 4 °C temperature. Moreover, it was more effective against C. jejuni than commercial marinade with 0.47 log CFU/g (P ≤ 0.05) reduction effect. Both experimental and commercial marinades had very similar effect on the total aerobic bacterial count. Although experimental and commercial marinades had different effect on pH of broiler wings, this parameter did not show a major impact on the antimicrobial effect of tested marinades (P ≥ 0.05). Our study shows that experimental natural thyme‐based marinade can reduce numbers of C. jejuni more effectively than tested commercial marinades.     

Aquatic passive sampling of herbicides on naked particle loaded membranes: accelerated measurement and empirical estimation of kinetic parameters

Water-sampler equilibrium partitioning coefficients and aqueous boundary layer mass transfer coefficients for atrazine, diuron, hexazionone and fluometuron onto C18 and SDB-RPS Empore disk-based aquatic passive samplers have been determined experimentally under a laminar flow regime (Re = 5400). The method involved accelerating the time to equilibrium of the samplers by exposing them to three water concentrations, decreasing stepwise to 50% and then 25% of the original concentration. Assuming first-order Fickian kinetics across a rate-limiting aqueous boundary layer, both parameters are determined computationally by unconstrained nonlinear optimization. In addition, a method of estimation of mass transfer coefficients--therefore sampling rates--using the dimension-less Sherwood correlation developed for laminar flow over a flat plate is applied. For each of the herbicides, this correlation is validated to within 40% of the experimental data.The study demonstrates that for trace concentrations (sub 0.1 microg/L) and these flow conditions, a naked Empore disk performs well as an integrative sampler over short deployments (up to 7 days) for the range of polar herbicides investigated. The SDB-RPS disk allows a longer integrative period than the C18 disk due to its higher sorbent mass and/or its more polar sorbent chemistry. This work also suggests that for certain passive sampler designs, empirical estimation of sampling rates may be possible using correlations that have been available in the chemical engineering literature for some time.     

Electrophoretic studies of chhana whey and effect of temperature and time of storage on its quality

Chhana whey contains less protein than Cheddar cheese whey, acid casein and cottage cheese whey, and the protein composition is quite different. Electrophoretic methods demonstrated that most of the proteins in chhana whey were denatured, and there was considerable variation in the protein composition between samples of chhana whey and paneer whey obtained from different sources. The effect of storage temperature and time (up to 10 h at 40°C, 50°C, 60°C, 70°C and 80°C) on the quality of chhana whey was investigated. There were no significant changes in the pH and titratable acidity in any of these cases. Electrophoretic separation showed no qualitative changes in the protein composition pattern of chhana whey after up to 10 h of storage at 70°C.     

Transient natural convective flow of a radiative viscous incompressible fluid past an exponentially accelerated porous plate with chemical reaction species

The present study deals with an unsteady magnetohydrodynamic natural convective flow of a viscous, incompressible fluid past an exponentially accelerated porous plate surrounded by a porous medium with suction or injection. The novelty of the current research is to analyze the behavior of the flow due to mass transfer with first-order chemical reaction in the presence of a heat source in the energy equation. The existence of suction/injection and radiation parameters in the flow enhances the utility of the research as they are an integral part of nuclear reactors, thermal and chemical engineering processes, and many more. The Laplace transform technique (via Bromwich contour) is applied to solve exactly the governing equations. The nature of the flow velocity, temperature, and concentration profiles due to the impact of pertinent flow parameters are presented graphically. The numerical outcomes of coefficient of skin friction, rate of heat transfer, and mass transfer are obtained in tabular form. The results indicate that the skin friction increases slowly with the reaction parameter and largely with the suction parameter, whereas the concentration gradient increases at a much higher rate with the reaction parameter. The fluid injection has a negative impact on the velocity gradient. It is seen that the heat source enhances both velocity and temperature profiles throughout the flow field, whereas the first-order chemical reaction acts reversely on the velocity and mass transfer process. The current research can be applied to identify the cause behind the drag force produced in seepage flow due to the heated or cooled accelerated plate.     

Effects of exercising before versus after eating on dieting and exercise evaluations: A preliminary investigation.

Psychological processes may play a role in the evaluation of the effectiveness of exercise and subsequent food intake. In order to further investigate this phenomenon, the effects of the timing of exercise relative to an eating opportunity were evaluated. Female undergraduate participants who were of average weight and did not exercise regularly were randomly assigned to one of three conditions (exercise before eating [n = 10], exercise after eating [n = 11], or no exercise [n = 12]). Expectations of the effectiveness of the exercise, value of dieting, and intake were assessed. Participants who exercised after eating had higher expectations of the effectiveness of the exercise than those who exercised before eating, while those who exercised before eating reported valuing dieting more than controls. No effects on intake emerged; therefore, there appears to be a disconnect between dieting appraisals and actual eating behaviour. The results are discussed in relation to theories on conflicting goals. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

HPLC–MS identification of phenols in hazelnut (Corylus avellana L.) kernels

In whole hazelnut kernels, as the main product of hazelnut (Corylus avellana L.), phenols were analysed in 20 hazelnut cultivars by high-performance liquid chromatography–tandem mass spectrometry (HPLC–MS). Twenty-three compounds from different phenolic groups were detected, and 15 of them were identified. In hazelnut kernels, these substances were detected: nine flavan-3-ols, two benzoic acids (gallic and protocatechuic acid), three flavonols and phloretin glycoside. Total phenol concentrations ranged from 70 to 478 mg gallic acid equivalents per kg hazelnut kernels. A high content level of total phenols was observed in the ‘Tonda Gentile delle Langhe’ and ‘Lewis’ cultivars, which was followed by the ‘Corabel’, ‘Fertile de Coutard’, ‘Daria’ and ‘Tonda Gentile Romana’ cultivars. Similarly, the highest antioxidative activity, measured by employing DPPH-antiradical assay, was also found in the ‘Tonda Gentile delle Langhe’ cultivar, followed by the ‘Fertile de Coutard’.