Lessons Learned from Field and Laboratory Testing of a DBR Project

Where faulting takes place due to the absence of dowel bars and inadequate subbase support in jointed concrete pavement (JCP), dowel bar retrofit (DBR) is used to improve load transfer efficiency (LTE) and to prevent further faulting of slabs at transverse joints. Even though DBR generally improves LTEs and overall performance of JCPs, not all DBR projects have been successful. Faulting reoccurred within 2?years after DBR treatment on US59 in Texas. An investigation from the cores taken in the project revealed excessive voids under a dowel bar due to poor consolidation of the grouting material. A laboratory investigation was performed to determine the most critical factors for adequate consolidation of grouting materials in DBR. Typical rapid-setting grout materials widely used in DBR were selected and full-scale specimens were made for evaluations. Four testing variables for consolidation performance were investigated: time of placement after mixing, vibration time, slot width, and maximum aggregate size. Maximum aggregate size and slot width were not critical factors for consolidation performance of grout. The most significant factor was vibration time. Twenty s of vibration is recommended. Placement time was also an important factor, with grout materials placed after initial set performing poorly. Delayed placement of grout materials without vibration led to the most voids under the dowel bars.     

Field and Lab Investigations of Prematurely Cracking Pavements

A forensic study was conducted to identify the cause of the premature cracking on three recently completed projects that were built with the same design. Nondestructive [ground penetration radar, falling weight deflectometer (FWD), GeoGauge, and Portable FWD], nuclear density gauge, dynamic cone penetration, and extensive laboratory tests were performed. It was found that the initial stiffness of the treated base was found to be excessively high by FWD backcalculation. Some sections of the backcalculated base moduli were over 20.7?GPa. This indicates that the layer is excessively brittle for a base material, similar to lean concrete. Six specimens (that were made without a mellowing period) exhibited cracks. There was no cracking for six specimens that had two days of mellowing. It was concluded that the culprit of the transverse cracking in the main lanes was the shrinkage of lime treated base layers. The longitudinal cracks are related to the edge drying and the transverse cracks are related to the insufficient mellowing period. Based on the findings of this study, the District implemented a 2-day mellowing period for Quicklime treated caliche base. Three newly constructed pavements (age 8, 5, and 2?months) were surveyed. No cracking can be observed so far, and the District thinks the cracking problem has been mitigated by the 2-day mellowing period. Without the mellowing period, cracking had normally occurred 1?to?2?months after construction..     

Sub-pixel mapping of urban land cover using multiple endmember spectral mixture analysis: Manaus, Brazil

The spatial and spectral variability of urban environments present fundamental challenges to deriving accurate remote sensing products for urban areas. Multiple endmember spectral mixture analysis (MESMA) is a technique that potentially addresses both challenges. MESMA models spectra as the linear sum of spectrally pure endmembers that vary on a per-pixel basis. Spatial variability is addressed by mapping sub-pixel components of land cover as a combination of endmembers. Spectral variability is addressed by allowing the number and type of endmembers to vary from pixel to pixel. This paper presents an application of MESMA to map the physical components of urban land cover for the city of Manaus, Brazil, using Landsat Enhanced Thematic Mapper (ETM+) imagery.We present a methodology to build a regionally specific spectral library of urban materials based on generalized categories of urban land-cover components: vegetation, impervious surfaces, soil, and water. Using this library, we applied MESMA to generate a total of 1137 two-, three-, and four-endmember models for each pixel; the model with the lowest root-mean-squared (RMS) error and lowest complexity was selected on a per-pixel basis. Almost 97% of the pixels within the image were modeled within the 2.5% RMS error constraint. The modeled fractions were used to generate continuous maps of the per-pixel abundance of each generalized land-cover component. We provide an example to demonstrate that land-cover components have the potential to characterize trajectories of physical landscape change as urban neighborhoods develop through time. Accuracy of land-cover fractions was assessed using high-resolution, geocoded images mosaicked from digital aerial videography. Modeled vegetation and impervious fractions corresponded well with the reference fractions. Modeled soil fractions did not correspond as closely with the reference fractions, in part due to limitations of the reference data. This work demonstrates the potential of moderate-resolution, multispectral imagery to map and monitor the evolution of the physical urban environment.     

Management’s Perception of Key Performance Indicators for Construction

There is a great need in the construction industry for identifying a set of common indicators to be used by construction executive and project managers in measuring construction performance at the project level. The focus of this research was to collect management perceptions of the key performance indicators currently utilized in the construction industry. Both quantitative performance indicators and qualitative performance indicators are represented. A literature search was used to generate the initial set of perceived key performance indicators, which were administered to the construction industry via a survey. A statistical analysis of the collected survey responses provided information for the identification of a common set of perceived Key Performance Indicators (KPIs) by construction sector, management level, and experience level. Correlations were performed for both the quantitative and qualitative indicators to determine which type of indicator is used most extensively. Basic statistical analyses and frequency distributions provided evidence in support of some of the hypotheses of the research. The results of the survey data analysis support the hypothesis that KPIs vary according to management’s perspective. Further analysis displayed a substantial difference between construction executive and project management’s perceptions. However, six indicators were reported as being most useful by every segment of the construction industry involved in this study. The correlation between quantitative indicators and qualitative indicators proved to be inconclusive.     

Electrical conduction in light rare-earth tungstates

This paper reports the results of electrical conductivity (σ) and thermoelectric power (H) of light rare-earth tungstates in the temperature range 600–1200K. Holes are the dominant charge carriers over the whole studied temperature range for Nd, Sm and Gd tungstates. However, in the case of La, Ce and Pr tungstates, the conduction is dominated by electrons at lower temperatures, but above 950K in La, 800K in Ce and 950K in Pr the dominant charge carriers become holes. A sharp break and change in the log σ vs 1/T slope occurs in La, Ce and Pr tungstates around the same temperature at which the dominant charge carrier changes from electrons to holes. In the case of Nd, the conductivity anomaly occurs around 1020K without any change in the nature of the charge carrier. The data have been analysed using band theory.     

Cytogenetic studies in reproductive loss

On the basis of the two years investigations carried on the green pea (var. Delis 11 fold), it was confirmed that blanching and freezing decrease the content of albumen and amino acids. The sterilizing belongs to the most drastic process. It was also confirmed that methionine limits the content of albumen.     

Acid-induced aggregation and gelation of heat-treated chia proteins

This work studied for the first time the acid-induced aggregation and gelation of heat-treated chia protein isolates obtained by extraction at pH 10 or 12 (CPI10 and CPI12, respectively). The aggregation state of proteins was modified during acidification. The size of the aggregates was reduced for both samples when the pH decreased but below pH 4.5 further protein aggregation took place for CPI12. Gelation of CPI12 was completed after about 30 min of acidification with glucone-δ-lactone. By contrast, this period was not enough to reach a constant value in G′ for CPI10. When gelation was ensured, confocal laser scanning micrographs from those gels revealed a coarse and irregular structure with large pores (median size of diameters: 30 μm). Instead, micrographs from CPI12 cold gels showed a more regular and interconnected network, with smaller pores (median size of diameters: 9 μm). These differences are consistent with a higher elastic behaviour ( = 13.6 ± 0.1 Pa).     

Fluorination-controlled Aggregation and Intermolecular Interactions in Pt(II) Complexes with Tetradentate Luminophores

In this work we describe the synthesis and DFT-supported photophysical characterization of a series of Pt(II) complexes bearing tetradentate luminophores with increasing degree of fluorination. Aggregation into crystalline phases leads to substitution-dependent arrangements that in all cases hinder intermetallic coupling, as intermolecular interactions are dominated by hydrogen bonding and π-stacking. In amorphous matrices, on the other hand, we observed that an increasing level of fluorination favors the tendency towards Pt−Pt interaction upon aggregation, leading to a red-shifted phosphorescence, if compared with monomeric species in dilute solutions and crystalline solids.     

Layer-by-layer assembly of TiO2 nanowire/carbon nanotube films and characterization of their photocatalytic activity

We report on the layer-by-layer (LbL) formation of TiO(2)-MWNT-TiO(2) coatings on quartz with either trititanate derived TiO(2) nanowires or Degussa P25 as the photocatalytically active material. The optimized deposition sequence is discussed in detail and the morphology of the prepared coatings is analyzed by SEM and XRD. The heterogeneous photocatalytic performance of the coatings was tested in the methyl orange oxidation reaction. The apparent first order rate constant fell in the 0.01-0.20 h(-1) range over a 2.5 × 2.5 cm(2) film depending on the type and the thickness of the titanate coating. Building a multiwall carbon nanotube layer into the middle of the layer improved the photocatalytic activity for each material for all of the studied thicknesses. P25 based films performed 2-5 times better than TiO(2) nanowire films; however, the pores in the P25 based films were largely blocked because the isotropic P25 nanoparticles form closely packed layers by themselves and even more so with the comparably sized multiwall carbon nanotubes. Therefore, films derived from titanate nanowires appear to be more suitable for use as multifunctional, photocatalytically active filtration media.