An optical FSK heterodyne dual filter detection system for takingadvantage of DFB LD applications

An optimum system configuration for an optical frequency-shift keying (FSK) heterodyne dual-filter detection system with distributed feedback laser diodes (DFB LDs) is investigated, taking into consideration LD phase noise influence. Experimental and theoretical examination show that an IF filter bandwidth greater than 10 times the beat spectral linewidth is necessary to avoid LD phase noise influence. A 301-km long-span transmission experiment has been successfully carried out with an optimum configuration for 34 Mb/s. High receiver sensitivity, -61.8 dBm with more than 10 dB improvement over the direct detection system, has also been achieved. Experimental results at higher bit rates of 140, 200, and 280 Mb/s indicate that a modulation index greater than two is desirable to avoid cross talk between mark and space signals. With sufficient frequency deviations, high receiver sensitivities of -54.7 dBm (140 Mb/s) and -52.5 dBm (200 Mb/s) have been achieved. These represent 9.6- and 9-dB sensitivity improvement, respectively, over direct detection systems. A guide for FSK dual-filter detection system design is derived from the experimental and theoretical results. Potential application regions for a dual-filter detection system with DFB LDs are determined     

Development of a directly-driven thread whirling unit with advanced tool materials for mass-production of implantable medical parts

Medical screws are a common mass-produced implantable medical component made of Titanium. To machine the threads of these types of components, thread whirling with carbide tools is typically used. However, tool wear and low cutting speed limit the productivity and increase the manufacturing cost of such medical parts. In this study, a direct motor driven thread whirling unit for an advanced Swiss-type CNC lathe was developed and it was used with advanced tool materials such as low binder content Cubic boron nitride (CBN) and Polycrystalline diamond (PCD) to find a cost-effective and more productive alternative to carbide tools.     

Preparation of mesoporous silica replica using ordered mesoporous carbon by vapor phase transport of silica source

A new vapor phase transport (VPT) technique to prepare an inverse silica replica of an ordered mesoporous carbon was developed. Tetraethyl orthosilicate (TEOS) was infiltrated in mesoporous carbon CMK-3 as the hard template at 180 °C for 48 h under an autogenous pressure in an autoclave in the presence of water. The samples obtained by removal of CMK-3 retained structural regularity of CMK-3 with little shrinkage of framework, which were characterized by SAXRD, N₂ adsorption, TG-DTA, and SEM. Influence of preparation temperature on the loading amount of silica was investigated. The multi-step replication process was monitored by characterizing the replicated materials as well as intermediate composites.     

Micro-flowers of poly(p-phenylene pyromelliteimide) crystals

Morphology control of poly(p-phenylene pyromelliteimide) (PPPI) crystals was examined using reaction-induced crystallization of oligomers during solution polymerization of self-polymerizable N-(4′-aminophenyl)-3-carboxyl-4-alkoxycarbonylphthalimide. Micro-flowers of the PPPI needle-like crystals were formed in which the needle-like crystals grew radially from the center part as petals. The molecules aligned regularly along the long axis of the needle-like crystal. The structure of alkoxy group in the monomer and the monomer concentration influenced the size of the needle-like crystals, and their average length and width were changeable from 640 nm to 1.69 μm and from 110 nm to 210 nm, respectively. The average thickness was 20 nm. The obtained micro-flowers possessed high crystallinity and exhibited excellent thermal stability.     

Multi-component granulation in a fast fluidized bed

The granulation of multi-component particles was conducted in a fast fluidized bed with an atomizing binder solution. The effects of gas velocity and binder droplet diameter on granulation rate, granule size distribution and granule composition were studied. The granulation rate and granule yield were determined by the balance between the agglomeration rate of feed particles and the disintegration rate of granules because there was no secondary granulation. With the increase in gas velocity and the reduction in binder droplet size, the agglomeration rate of feed particles decreased but the disintegration rate of granules increased, resulting in a reduced granule yield. Despite the larger fraction of small particles in the granules, the homogenous granulation of multi-component particles was achieved.     

Development of ultra-stable Ni catalysts for CO2 reforming of methane

Carbon deposition behavior in CO₂ reforming of methane, methane decomposition, and CO disproportionation on nickel-magnesia solid solution was investigated by means of thermogravimetric analysis and temperature programmed reaction of deposited carbon with carbon dioxide. It was found that rapid oxidation of CH_x on Ni surface by oxygen species from CO₂ through dissociation at metal-support interface is a key step for the inhibition of carbon formation.     

Preparation of Cu2ZnSnS4 thin films by sulfurizing electroplated precursors

Cu₂ZnSnS₄ (CZTS) thin films were prepared by sulfurizing precursors deposited by electroplating. The precursors (Cu/Sn/Zn stacked layers) were deposited by electroplating sequentially onto Mo-coated glass substrates. Aqueous solutions containing copper sulfate for Cu plating, tin sulfate for Sn plating and zinc sulfate for Zn plating were used as the electrolytes. The precursors were sulfurized by annealing with sulfur at temperatures of 300, 400, 500 and 600 °C in an N₂ gas atmosphere. The X-ray diffraction peaks attributable to CZTS were detected in thin films sulfurized at temperatures above 400 °C. A photovoltaic cell using a CZTS thin film produced by sulfurizing an electroplated Sn-rich precursor at 600 °C exhibited an open-circuit voltage of 262 mV, a short-circuit current of 9.85 mA/cm² and an efficiency of 0.98%.