High Hydrostatic Pressure and Mild Heat Treatments for the Modification of Orange Peel Dietary Fiber: Effects on Hygroscopic Properties and Functionality

Fruit by-products, such as orange peels, are non-conventional sources of dietary fiber (DF) suitable for developing food ingredients with novel applications. Orange peels were processed at 600 MPa (come up time–CUT, 2, 5, 10, or 20 min) and two temperatures (55 or 70 °C) with the aim to study changes in total (TDF), soluble (SDF), and insoluble (IDF) dietary fiber contents, water-/oil-holding capacity (WHC/OHC), solubility, swelling capacity (SC), pH, tap density, and hygroscopic properties. Increments of 1.9 times on the SDF content were observed after HHP treatment at 55 and 70 °C, compared to the untreated sample content (7.17% dw). Constant values of TDF (51.2–54.6% dw) suggested the significant conversion of assayable IDF to SDF. An increase on SC (6.5%) and OHC (20.1%) values were observed in samples treated with CUT at 70 and 55 °C, respectively. Compared to control samples, HHP (55 °C/5 min) exerted changes on moisture isotherms expressed as relative water sorption content. HHP improved the adsorption and desorption water retention of samples in the 0.1–0.93 a _w range studied. Results indicate that HHP combined with heat treatment has potential to modify the functionality of orange peels with short processing times.     

Characteristics of effluents from healthcare waste treatment with alkaline hydrolysis

Although alkaline hydrolysis emerges as an alternative process to treat healthcare waste (HCW), information about its emissions is scarce, namely as regards effluents production. This work aims to characterize the effluents from alkaline hydrolysis tests with samples of components usually present in HCW, under a temperature of 110°C and with 1 M NaOH aqueous solutions. Some of the regulatory parameters for discharging effluents were determined; also, tests for assessing aerobic and anaerobic biodegradation of those effluents were carried out. The effluents showed values lower than threshold values for almost all the parameters except pH, total nitrogen, TOC, COD and BOD₅. Although with high organic load, the effluents from discarded medical components (DMC) and animal tissues (AT) showed a percentage of aerobic biodegradation of 50.5 and 52.9%, respectively. The anaerobic biodegradability obtained for the effluents from DMC were 22.3 and 42.2% for those with AT.     

Comparison of Wicke-Kallenbach and Graham's diffusion cells for obtaining transport characteristics of porous solids

Counter-current gas diffusion measurements on a series of porous solids covering a broad range of pore sizes (mean pore radii between 78 nm and ) were performed in the Wicke-Kallenbach and Graham's diffusion cells. Mutual agreement of diffusion fluxes from both cells was found in the whole range of tested pore radii and inert gas systems. For pore materials with mean pore radii exceeding the experimentally unavoidable tiny total pressure gradient induces additional permeation flow which precludes the use of Graham's law for evaluation of transport parameters of the porous solids. Transport parameters together with 95% confidence regions were determined for porous materials with pore radii up to and the prevailing diffusion mechanism, intimately connected with the shape of confidence regions, was estimated.     

Glucose sensing using near-infrared surface-enhanced Raman spectroscopy: gold surfaces, 10-day stability, and improved accuracy

This research presents the achievement of significant milestones toward the development of a minimally invasive, continuously monitoring, glucose-sensing platform based on the optical quantitation of glucose in interstitial fluid. We expand our initial successes in the measurement of glucose by surface-enhanced Raman scattering (SERS), demonstrating substantial improvements not only in the quality and optical properties of the substrate system itself but also in the robustness of the measurement methodology and the amenability of the technique to compact, diode laser-based instrumentation. Herein, we compare the long-term stability of gold to silver film over nanosphere (AuFON, AgFON) substrates functionalized with a partitioning self-assembled monolayer (SAM) using both electrochemical and SERS measurements. AuFONs were found to be stable for a period of at least 11 days. The switch to AuFONs not only provides a more stable surface for SAM formation but also yields better chemometric results, with improved calibration and validation over a range of 0.5-44 mM (10-800 mg/dL). Measured values for glucose concentrations in phosphate-buffered saline (pH approximately 7.4) based on 160 independent SERS measurements on AuFONs have a root-mean-square error of prediction of 2.7 mM (49.5 mg/dL), with 91% of the values falling within an extended A-B range on an expanded Clarke error grid. Furthermore, AuFONs exhibit surface plasmon resonances at longer wavelengths than similar AgFONs, which make them more efficient for SERS at near-infrared wavelengths, enabling the use of low-power diode lasers in future devices.     

Real-time glucose sensing by surface-enhanced Raman spectroscopy in bovine plasma facilitated by a mixed decanethiol/mercaptohexanol partition layer

A new, mixed decanethiol (DT)/mercaptohexanol (MH) partition layer with dramatically improved properties has been developed for glucose sensing by surface-enhanced Raman spectroscopy. This work represents significant progress toward our long-term goal of a minimally invasive, continuous, reusable glucose sensor. The DT/MH-functionalized surface has greater temporal stability, demonstrates rapid, reversible partitioning and departitioning, and is simpler to control compared to the tri(ethylene glycol) monolayer used previously. The data herein show that this DT/MH-functionalized surface is stable for at least 10 days in bovine plasma. Reversibility is demonstrated by exposing the sensor alternately to 0 and 100 mM aqueous glucose solutions (pH approximately 7). The difference spectra show that complete partitioning and departitioning occur. Furthermore, physiological levels of glucose in two complex media were quantified using multivariate analysis. In the first system, the sensor is exposed to a solution consisting of water with 1 mM lactate and 2.5 mM urea. The root-mean-squared error of prediction (RMSEP) is 92.17 mg/dL (5.12 mM) with 87% of the validation points falling within the A and B range of the Clarke error grid. In the second, more complex system, glucose is measured in the presence of bovine plasma. The RMSEP is 83.16 mg/dL (4.62 mM) with 85% of the validation points falling within the A and B range of the Clarke error grid. Finally, to evaluate the real-time response of the sensor, the 1/e time constant for glucose partitioning and departitioning in the bovine plasma environment was calculated. The time constant is 28 s for partitioning and 25 s for departitioning, indicating the rapid interaction between the SAM and glucose that is essential for continuous sensing.     

1H and 13C nuclear magnetic resonance studies of the hindered phencyclone adducts of some smaller branched N-alkyl maleimides: rigorous aryl proton assignments with high-resolution two-dimensional (COSY45) spectroscopy, and anisotropic shielding effects and ab initio geometry optimizations

Phencyclone, 1, a potent Diels-Alder diene, reacts with a series of N-alkylmaleimides, 2, to form hindered adducts, 3. The 300 MHz 1H and 75 MHz 13C NMR studies of these adducts at ambient temperatures have demonstrated slow rotations on the nuclear magnetic resonance (NMR) timescales for the unsubstituted bridgehead phenyl groups, and have revealed substantial magnetic anisotropic shielding effects in the 1H spectra of the N-alkyl groups of the adducts. The selected N-alkyl groups for the target compounds emphasized smaller branched alkyls, including C3 (isopropyl, a); C4 (isobutyl, b; and t-butyl, c); C5 (n-pentyl, d; isopentyl [isoamyl], e; 1-ethylpropyl, f; t-amyl, g;) and a related C8 isomer (1,1,3,3-tetramethylbutyl ["t-octyl"], h). The straight-chain n-pentyl analog was included as a reference. This present work on the branched N-alkylmaleimide adducts appreciably extends our earlier compilation on the N-n-alkylmaleimide adducts. Key methods for proton assignments included "high-resolution" 1H-1H chemical shift correlation spectroscopy, COSY45. 13C NMR of the adducts, 3, verified the expected number of aryl carbons for slow exchange limit (SEL) spectra of the bridgehead phenyl groups. The synthetic routes involved reaction of the corresponding amines, 4, with maleic anhydride to give the N-alkylmaleamic acids, 5, which underwent cyclodehydration to form the maleimides, 2. Magnetic anisotropic shielding magnitudes for alkyl group protons in the adducts were calculated relative to corresponding proton chemical shifts in the maleimides. Geometry optimizations for the above adducts (and for the N-n-butylmaleimide adduct) were performed at the Hartree-Fock level with the 6-31G* basis set. The existence of different contributing conformers for the adducts is discussed with respect to their calculated energies and implications regarding experimentally observed anisotropic shielding magnitudes.     

On the Laplace transform of a matrix of fundamental solutions for thermoelastic plates

The Laplace transform of a matrix D(x,t) of fundamental solutions for the partial differential operator describing the time-dependent bending of thermoelastic plates with transverse shear deformation is constructed, and its asymptotic behavior near the origin is investigated. The differential system is reduced to an algebraic one through the application of the Laplace and then Fourier transformations, and all possible cases of roots of the determinant of the latter system are considered. It is shown that in every case, the asymptotic expansion of near the origin has the same dominant term. This is an important step in the construction of boundary-element methods for the above time-dependent model because it determines the nature of the singularity of the kernel of the boundary-integral-equations associated with various initial-boundary-value problems for the governing system.     

What is the leanest stream to sustain a nonadiabatic loop reactor: Analysis and methane combustion experiments

While previous studies experimentally demonstrated that loop reactor (LR) can be sustained with a lean feed (using ethylene combustion) and have analyzed the single‐reaction adiabatic case, this work analyzes the effects of heat loss and of reactor size to determine the leanest stream (expressed in terms of adiabatic temperature rise ΔT_lim) that will sustain the operation. For an adiabatic infinitely long reactor ΔT_lim→0 while for a finite reactor ΔT_lim scales as (1 + Pe/4)^?1 where Pe = Luρc_pf/k, and heat loss increases this limit by (β/Pe)^1/2. Thus, a good design of a LR will aim to decrease conductivity (k) and radial heat‐transfer coefficient (β) while increasing throughput (u) and reactor length. This article is also the first experimental demonstration of auto‐thermal operation in a LR for catalytic abatement of low‐concentration of methane, showing the leanest stream to be of 8000 ppm vs. 33,000 ppm in a once‐through reactor. Experimental combustion results of methane and of ethylene are compared with model predictions. © 2016 American Institute of Chemical Engineers AIChE J, 63: 2030–2042, 2017     

Accurate and efficient lighting for skinned models

In the context of real‐time, GPU‐based rendering of animated skinned meshes, we propose a new algorithm to compute surface normals with minimal overhead both in terms of the memory footprint and the required per‐vertex operations. By accounting for the variation of the skinning weights over the surface, we achieve a higher visual quality compared to the standard approximation ubiquitously used in video‐game engines and other real‐time applications. Our method supports Linear Blend Skinning and Dual Quaternion Skinning. We demonstrate the advantages of our technique on a variety of datasets and provide a complete open‐source implementation, including GLSL shaders.     

Electrochemically controlled molecular weight of polystyrene production

Summary It is well known that physical properties such as mechanical and thermal characteristics of a polymer are highly dependent on its molecular weight and molecular weight distribution (MWD). This feature encourages our interest for finding suitable conditions that allow us to control the molecular weight of the formed polymer, by controlling the experimental parameters. We are reporting some results about the electropolymerization of styrene in tetrahydrofuran with tetrabutylammonium tetrafluoroborate and sodium tetraphenylboron as supporting electrolytes. From the electrolyses using tetrabutylammonium tetrafluoroborate two molecular weight distribution curves, showing weight average molecular weight values ( ) of 3.6×10⁵–1.7×10⁶ for the first and 5×10³ for the second one were observed. When using sodium tetraphenylboron a unique distribution curve was displayed suggesting that the weight average molecular weight of the polystyrene, increases by increasing the current density; the observed MWD being rather low.