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11.
A molecular orbital approach to materials design has recently made great progress. This approach is based on the electronic structure calculations by the DV-Xα cluster method. In this paper recent progress in this approachis reviewed. In particular 相似文献
12.
The electrochemical behavior of ferrocene (Fc) and ferricenium (Fc+) was investigated by cyclic voltammetry with convolutional and semi-differential electroanalyses in the temperature range 298-373 K in the hydrophobic room temperature ionic liquid systems consisting of bis(trifluoromethanesulfone)imide anion with quaternary ammonium cation. The experimental results indicated that the redox reaction of Fc/Fc+ was reversible in this ionic liquid and the charge-transfer rate constant (k0) has been obtained. Mass transport towards the electrode is a simple diffusion process and the diffusion coefficient (D) for Fc/Fc+ has been also calculated. These results indicated that the k0 and D increased with increasing temperature in ionic liquids. The validity of the Arrhenius law was verified by investigating the temperature dependences of k0 and D. 相似文献
13.
Remi Kasai Hideaki Yaegashi Hiroshi Yokoyama Masahiko Yamanaka Hideo Sawada 《Journal of Materials Science》2007,42(24):10228-10238
Fluoroalkanoyl peroxides reacted with FULLERENES [fullerene (C60) and commercially available fullerenes (Nanom MixTR and Nanom BlackTR)] and radical polymerizable comonomers such as acrylic acid, N,N-dimethylacrylamide, N-(1,1-dimethyl-3-oxobutyl)acrylamide, and acryloylmorpholine to afford fluoroalkyl end-capped cooligomers having FULLERENES
in the main chain under very mild conditions. Fluoroalkyl end-capped Nanom Mix and Nanom Black cooligomers thus obtained were
found to exhibit a similar solubility to that of the corresponding fluoroalkyl end-capped cooligomers having fullerene in
the main chain. These fluorinated FULLERENES cooligomers were found to form the nanometer size-controlled self-assembled cooligomeric
aggregates in aqueous solutions. These fluoroalkyl end-capped FULLERENES cooligomers were more effective for solubilizing
fullerene, Nanom Mix and Nanom Black into water, compared to those of the corresponding fluoroalkyl end-capped homooligomers
having no FULLERENES in the main chain. Fluoroalkyl end-capped fullerene- and Nanom Mix-acrylic acid cooligomers were found
to exhibit fluorescence spectra related to fullerene and Nanom Mix in cooligomers, respectively, in aqueous solutions. Additionally,
these fluorinated fullerene- and Nanom Mix-acrylic acid cooligomers were able to increase chemiluminescence intensity related
to luminol, effectively, compared to the corresponding fluorinated acrylic
acid homooligomers. 相似文献
14.
H Imano H Iso T Tanigawa T Sankai T Ohira M Kudo T Shimamoto S Sato T Okamura M Iida 《Canadian Metallurgical Quarterly》1998,45(6):536-551
To investigate the contribution of the platelet aggregation in the development of cardiovascular diseases, we examined the relation of constitutional and lifestyle variables with platelet aggregation for a total of 306 males aged 50 to 70 in Ikawa town, Akita prefecture (n = 163) and Noichi town, Kochi prefecture (n = 143). The examination of platelet aggregation was completed within 3 hours of obtaining blood samples. We used ADP (Adenosine 5'-diphosphate) as an agonist and obtained PATI (the platelet aggregatory threshold index) by nephelometry. Platelet count, mean platelet volume, white blood cell count, serum fatty acid compositions were also examined and dietary intake of fish, seafood and soy bean foods were inquired using one-week dietary records. PATI indicated a logarithmic normal distribution in both Ikawa and Noichi. The mean of logarithmic transformed PATI (log PATI) was higher in Ikawa than in Noichi. Thus platelet aggregation was lower in Ikawa than in Noichi. According to multiple regression analysis, age, platelet count in platelet rich plasma, mean platelet volume in platelet rich plasma, and white blood cell count were inversely associated with log PATI. Serum arachidonic acid composition tended to be inversely related with log PATI. Serum n3-polyunsaturated fatty acid composition was positively related with log PATI, and log gamma-GTP tended to be positively associated with log PATI. Soy protein intake and cigarette smoking showed no consistent associations with log PATI. This cross-sectional study suggests that serum n3-polyunsaturated fatty acid, and gamma-GTP, as an index of alcohol intake, reduce platelet aggregation while age, white blood cell count, platelet count, mean platelet volume, and serum arachidonic acid raise platelet aggregation. 相似文献
15.
Motonobu Yoshikawa Hiroshi Nakajima Takeshi Inada Yasushi Harada Masahiko Amano Yuji Nakata 《Electrical Engineering in Japan》1995,115(7):29-39
A new practical method is proposed which gives a quasi-optimal solution of the dynamic load-dispatching problem formulated by a multiconstraint multiobjective optimization problem. Here, the multiple constraints are rate reserve constraints and power flow ones, and the multiple objectives are fuel cost and CO2 emission. The proposed method is an integration of the following three techniques: (1) “Group Dispatch Scheme,” which is developed by the authors, is used to satisfy a violated constraint easily. This scheme consists of three steps. The first step is to classify all generators into two groups. One is the group which should be more loaded to satisfy the violated constraint, and the other is the should-be less loaded group. The second step is to add some load to the former group, and to subtract the same load from the latter. The third step is to dispatch each group load to each groups generators, respectively; (2) the dynamic load-dispatching algorithm is used which provides, in practical time, quasi-optimal generation trajectories; (3) the conventional weighting parametric method is used to obtain a Pareto optimal solution of multiobjective problems. The effectiveness of the method is clarified by a computer simulation on the actual power system of Kansai Electric Power Company. 相似文献
16.
Crystallization of potassium titanate from the amorphous phase 总被引:1,自引:0,他引:1
Tadashi Endo Hiroyuki Nagayama Tsugio Sato Masahiko Shimada 《Journal of Materials Science》1988,23(2):694-698
By using amorphous potassium titanates as the starting materials, a sintered body of K2Ti4O9 or K2Ti6O13 with porous and fibrous textures was prepared. K2Ti2O5 and a new phase, K6Ti4O11 were synthesized by the thermal reaction of KNO3 with TiO2 at 1000° C for 10 to 20 h. On leaching in water to expel excess of potassium ions, both phases became amorphous. After mixing and moulding these amorphous materials in the desired proportion, a sintered body containing fibrous crystals of K2Ti4O9 was readily fabricated by heating at 1000° C for 12 h. When 5 wt % B2O3 was added to the amorphous phases, single phase K2Ti6O13, with a fibrous texture grew well on heating at 1000° C for 12 h. Addition of PVA polymer to the amorphous phases was responsible for controlling the porosity of the sintered body, e.g. about 52% theoretical density at 20 wt% PVA polymer. The optimum conditions for preparing the amorphous phases were systematically examined and the effect of the chemical reaction environments, such as different crucible materials on the calcination of KNO3 and TiO2 were also discussed. 相似文献
17.
18.
Koji Tsukuma Kuniyoshi Ueda Masahiko Shimada 《Journal of the American Ceramic Society》1985,68(1):4-C-5
Composites of Al2 O3 and Y2 O3 partially-stabilized ZrO2 were isostatically hot-pressed using submicrometer powders as the starting material. The addition of Al2 O3 resulted in a large increase in bending strength. The average bending strength for a composite containing 20 wt% Al2 O3 was 2400 MPa, and its fracture toughness was 17 MN·w−3/2 相似文献
19.
Zeyun Yu Jun Wang Zhanheng Gao Ming Xu Masahiko Hoshijima 《Computer methods and programs in biomedicine》2014
In this paper we present a new software toolkit for generating and optimizing surface and volumetric meshes from three-dimensional (3D) biomedical imaging data, targeted at image-based finite element analysis of some biomedical activities in a single material domain. Our toolkit includes a series of geometric processing algorithms including surface re-meshing and quality-guaranteed tetrahedral mesh generation and optimization. All methods described have been encapsulated into a user-friendly graphical interface for easy manipulation and informative visualization of biomedical images and mesh models. Numerous examples are presented to demonstrate the effectiveness and efficiency of the described methods and toolkit. 相似文献
20.
The H2 evolution reaction from an aqueous Na2SO3 solution proceeded with 3.7% quantum yield under visible light irradiation (λ > 420 nm) on a Zn0.957Cu0.043S solid solution photocatalyst without co‐catalysts such as Pt.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献