Electrical contact resistance between stainless steel bipolar plate and carbon felt in PEFC: A comprehensive study

Bipolar plate represents a key component of Proton Exchange Membrane Fuel Cell (PEFC) with several essential functions, among them the electric connection of elementary cells. Usually made of graphite, this component is studied worldwide in order to develop a commercially viable alternative: different ways have been being investigated, and to date, despite corrosion issues, stainless steel (SS) appears as a good candidate material, but its Electrical Contact Resistance (ECR) can reach unacceptable values when exposed to PEFC environment. This paper offers a comprehensive study of the parameters acting on ECR when using uncoated SS in PEFC: roughness, which influences the surface contact area with carbon baking, bulk composition of the alloy, which influences only partly the nature of passive films, and the composition and structure of passive films, strongly modified by surface treatments and ageing conditions.     

The effect of a scattering layer on the edge output of a luminescent solar concentrator

The effect of adding white scattering layers to the bottom side of luminescent solar concentrator waveguides is evaluated. It is determined that adding a rear scatterer separated from the waveguide by an air gap results in a large increase of energy output from the waveguides, and this enhancement persists over long (>30 cm) distances, although the magnitude of the enhancement decreases with distance. An attached scatterer resulted in the greatest improvement of light output for short (∼6 cm) distances, but actually reduced edge emissions over longer distances. We provide estimates for the relative contribution of dye-emitted light and scattered light to the total waveguide emission, as well as distinguishing between the contributions of direct and indirect scattering of light to the total output as a function of dye content of the waveguides.     

Contribution to the textural characterisation of Filtrasorb 400 and other commercial activated carbons commonly used for water treatment

The textural characteristics of three commercial activated carbons, Filtrasorb 400 (F400), Industrial React High Affinity and Picabiol, commonly used in water treatment, are reinvestigated. Nitrogen physisorption isotherms are determined in the range P/P ₀ = [4 × 10⁻⁷–0.998] and processed using BET, α_S (Sing), Dubinin–Radushkevich and Density Functional Theory methods. In addition, fractal dimensions are determined by the Frenkel–Halsey–Hill procedure. Since F400 is often considered as a reference material in studies on the adsorption of solutes in aqueous solutions, a review of the textural characteristics of this carbon is carried out. The results obtained in this work using the different methods are consistent and a critical crossed comparison of these results allows discussing the limitations of the methods used. In particular, the impact of the P/P ₀ range considered on S _BET value is examined. In addition, the accuracy of the BET specific surface area is assessed in the light of information from recent literature.     

A hierarchical approach for planning a multisensor multizone search for a moving target

This paper deals with a well-known problem in the general area of search theory: optimize the search resources sharing so as to maximize the probability of detection of a (moving) target. However, the problem we consider here considerably differs from the classical one. First, there is a bilevel search planning and we have to consider jointly discrete and continuous optimization problems. To this perspective original methods are proposed within a common framework. Furthermore, this framework is sufficiently general and versatile so as to be easily and successfully extended to the difficult problem of the multizone multisensor search planning for a Markovian target.     

RFID behavior study in enclosed marine container for real time temperature tracking

The performance of radio waves in open environments has been studied for years. In contrast, the behavior of Radio Frequency Identification (RFID) inside metal enclosed areas is not yet understood. This research project focuses on the 3-D mapping of RFID signal strength inside a 12 m refrigerated marine container instrumented with three different types of radio frequency (RF) emitters: 915 MHz reader; 2.45 GHz reader and 433 MHz RF transmitter. The main goal is to find a frequency/configuration that would allow real time reading of the temperature in a shipment of perishable products using RFID. Only one frequency and one antenna were used at a time. The RF transmitter antenna was mounted at two different places inside the container; at the top of the front wall (facing back) and on the ceiling in the middle of the container (facing down). The signal strength was acquired by a spectrum analyzer and its antenna was mounted on a small electric cart inside the container. The cart was programmed to move along the length of the container and stop repeatedly, allowing three automated measures per position. All data were analyzed in terms of power level and attenuation. The maps showed that the RFID antenna positioned at the front of the container delivered slightly better results than the one in the middle of the ceiling. The results showed a significantly higher performance at the 433 MHz level. This article was presented at Food Processing Automation Conference, American Society of Agricultural and Biological Engineering (ASABE), Providence, RI, June 28–29 2008.     

Software für den Mars

SciencenewsTu Wien

Software für den Mars     

Building blocks for a two-frequency laser lidar-radar: a preliminary study

A new principle of lidar-radar is theoretically and experimentally investigated. The proposed architecture is based on the use of an rf modulation of the emitted light beam and a direct detection of the backscattered intensity. Use of a radar-processing chain allows one to obtain range and Doppler measurements with the advantages of lidar spatial resolution. We calculate the maximum range of this device, taking into account different possible improvements. In particular, we show that use of a pulsed two-frequency laser and a spatially multimode optical preamplification of the backscattered light leads to calculated ranges larger than 20 km, including the possibility of both range and Doppler measurements. The building blocks of this lidar-radar are tested experimentally: The radar processing of an rf-modulated backscattered cw laser beam is demonstrated at 532 nm, illustrating the Doppler and identification capabilities of the system. In addition, signal-to-noise ratio improvement by optical pre-amplification is demonstrated at 1.06 microm. Finally, a two-frequency passively Q-switched Nd:YAG laser is developed. This laser then permits two-frequency pulses with tunable pulse duration (from 18 to 240 ns) and beat frequency (from 0 to 2.65 GHz) to be obtained.     

Effectiveness of simultaneous independent realizations at low carrier-to-noise ratio to improve heterodyne Doppler lidar performance. I. Theory and numerical simulations

It is shown that the performance of heterodyne Doppler lidar (HDL) can be improved by (i) at least one good realization for every single shot or (ii) several simultaneous good realizations for accumulation. Until now, several simultaneous independent realizations at high carrier-to-noise ratio (CNR) have been considered. At low CNR, noise may have a detrimental effect on the accumulation techniques. We determine the chances of getting "heavy" speckles in HDL signals from many receiver-detector units on a single-shot basis and several good realizations on a single-shot basis, which is required for an effective accumulation. The use of multiple receiver-detector units at low CNR is worthwhile in contexts such as space lidar, where optimized treatment is at a premium. We conclude on the effectiveness of many receiver-detector units in parallel in order to achieve simultaneous independent realizations at low CNR to improve the performance of HDL on a statistical basis.     

Fast quantification of humic substances and organic matter by direct analysis of sediments using DRIFT spectroscopy

A simple method based on diffuse reflectance coupled with infrared Fourier transform spectroscopy (DRIFTS) has been developed for the quantification and the characterization of sedimentary (or soil, peat, etc.) humic substances. Under optimized conditions, the quantification of humic substances or total organic matter is possible with DRIFTS at a frequency of 2930 cm(-1) using whole dry sediment samples. A study of the operational parameters that affect the DRIFTS signal shows the importance of normalizing analysis conditions, especially the diffuse reflectance accessory alignment, the particle size and compaction, and the homogeneity of the powdered samples, to obtain reproducible quantitative analyses. The quantification of total humic substances by DRIFTS correlates well with the concentrations determined using classical extraction methods. DRIFTS analysis requires only a few minutes instead of tedious extractions of humic substances. Moreover, the distribution of total organic matter and of fulvic acids, humic acids, and humin can also be obtained. Analysis of natural samples indicates that a calibration using humic material representative of the studied area provides the most accurate quantification. The fast screening of organic matter fractions by DRIFTS on intact natural samples provides useful quantitative and qualitative information that can be used in environmental or monitoring studies.