3D printed millireactors for process intensification

The scope of the present research aims at demonstrating the 3D printing use in the manufacturing of microchannels for chemical process applications. A comparison among digital model processing applications for 3D print(slicers) and a print layer thickness analysis were performed. The 3D print fidelity was verified in several devices, including the microchannels' printing with and without micromixer zones. In order to highlight the 3D print potential in Chemical Engineering, the biodiesel synthesis was also carried out in a millireactor manufactured by 3D printing. The millireactor operated under laminar flow regime with a total flow rate of 75.25 ml ? min~(-1)(increment of about 130 times over traditional microdevices used for biodiesel production).The printed millireactor provided a maximum yield of Ethyl Esters of 73.51% at 40 °C, ethanol:oil molar ratio of7 and catalyst concentration of 1.25 wt% and residence time about 10 s. As a result of flow rate increment attained in the millireactor, the number of required units for scaling-up the chemical processes is reduced. Using the approach described in the present research, anyone could produce their own millireactor for chemical process in a simple way with the aid of a 3D printer.     

Thermoelectric properties of plasma sprayed of calcium cobaltite (Ca2Co2O5)

The thermoelectric properties of calcium cobaltite deposits produced by the plasma spray process are investigated from room-temperature to 873 K. Synthesis of Ca₃Co₂O₆ and Ca₂Co₂O₅ powders were prepared by the solid-state reaction from CaO and CoO_x starting powders. During their subsequent plasma spray Ca particles experience preferential evaporation within the plasma, resulting in a complex interplay among process conditions, stoichiometry, and resultant phases. The as-sprayed material predominantly contains amorphous and secondary phases. Upon annealing, the deposits show sensitivity to phase evolution and therefore thermoelectric properties. Through screening studies, optimal annealing conditions were identified which show a p-type Seebeck coefficient value of 180 μV K^?1, electrical conductivity of 1.09 × 10⁴ S m^?1, thermal conductivity of 1.16 W m^-1 K^-1 at 873 K. The resultant figure of merit value reached 0.266 for this combination of processing and thermal treatment and is in line with data reported from other techniques for this system.     

Assessing two large area burnt area products across Australian Southern Forests

Burnt area is a critical parameter for estimating emissions of greenhouse gases associated with biomass burning. Several burnt area products (BAPs) derived from Earth Observation satellites/sensors have been released; these are based on different spatial resolutions and derived using different methodologies so that accuracies can vary amongst them. This study validates a global (MODIS) and a national (AVHRR) BAP across Australian southern forests using two reference datasets: state fire histories (SFHs) from 2000 to 2013 and a forest cover map derived through high resolution air photo interpretation (API). The spatial and temporal agreement between fires in the BAPs and reference SFH were analysed based on 2610 sample points representative of Australian southern forest types (successful detection was evaluated according to fire type: planned burn vs. wildfire, size of fire, and land tenure). Results show that both BAPs were most successful when identifying large wildfires (>5000 ha). Overall accuracy for AVHRR and MODIS was 73.9% and 62.5%, respectively. When compared to the API derived forest cover map as reference dataset, both products achieved higher overall accuracies (94.1% for AVHRR and 87.1% for MODIS); an expected result given that the fires detected in this dataset are known to be observable using Earth observation data. But regardless of reference dataset, the AVHRR BAP which is tailored to Australian conditions achieved better results than the MODIS global BAP. Also, the AVHRR archive in Australia goes back to 1988, which is an important consideration for calculating wildfire history for greenhouse gas accounting.     

Optimization of rhein-loaded polymeric nanoparticles using a factorial design and evaluation of the cytotoxic and anti-inflammatory effects

The aim of the work was to develop rhein loaded polymeric nanoparticles (R-PNPs). Nanoparticles were prepared by three methods, solvent emulsion-evaporation, double emulsion, and nanoprecipitation, by means of experimental design. Additionally, the effects of the best formulation on in vitro cytotoxicity and inflammation were evaluated. The solvent emulsion-evaporation method presented the highest encapsulation efficiency of the three techniques (38.41%), as well as had a mean diameter of 189.33?nm and a polydispersity index of less than 0.1. Despite efforts to optimize the encapsulation of rhein, the drug release from nanoparticles was close to 50% during the first 5?min, followed by a continuous release within 60?min. It was observed that macrophages exposed to the highest concentration of R-PNPs showed cell viability about 80% and at the lowest nanoparticle concentrations was closed to 100%. IL-1β in cell culture supernatants was decreased in the presence of R-PNPs and TNFα concentrations were lower than the sensitivity of the assay. ROS production was only inhibited with R-PNPs at concentrations of 2.5 and 5?μM. In conclusion, the solvent emulsion-evaporation was the best method evaluated to obtain nanoparticles with the desired specifications. It was possible to assess R-PNPs with low cytotoxicity and anti-inflammatory properties showed by the inhibition of IL-1β production and a low decrease in ROS production.     

Multiaxial fatigue of quenched and tempered U2 steel: Testing and fatigue life prediction

Tension‐compression, tension‐tension, torsional, and 90° out‐of‐phase axial‐torsional fatigue tests were performed on a quenched and tempered U2 steel. All tests were conducted under force/torque control because macroscopic plastic strains were insignificant in the life range of interest (from 10⁴ to 2 × 10⁶ loading cycles). Stress‐based versions of the Fatemi‐Socie critical plane parameter and of the Smith‐Watson‐Topper parameter with a critical plane interpretation were evaluated using the experimental data. The Smith‐Watson‐Topper parameter was not able to correlate the test data. The Fatemi‐Socie method correlated most of the test data within factor‐of‐three boundaries. A modified Crossland invariant‐based parameter made of two interaction rules between the shear stress amplitude and the maximum hydrostatic stress, and of a definition of shear stress amplitude based on the maximum prismatic hull method, yielded fatigue life estimates in reasonable agreement with the experimental observations.     

Nanodroplet‐Containing Polymers for Efficient Low‐Power Light Upconversion

Sensitized triplet–triplet‐annihilation‐based photon upconversion (TTA‐UC) permits the conversion of light into radiation of higher energy and involves a sequence of photophysical processes between two dyes. In contrast to other upconversion schemes, TTA‐UC allows the frequency shifting of low‐intensity light, which makes it particularly suitable for solar‐energy harvesting technologies. High upconversion yields can be observed for low viscosity solutions of dyes; but, in solid materials, which are better suited for integration in devices, the process is usually less efficient. Here, it is shown that this problem can be solved by using transparent nanodroplet‐containing polymers that consist of a continuous polymer matrix and a dispersed liquid phase containing the upconverting dyes. These materials can be accessed by a simple one‐step procedure that involves the free‐radical polymerization of a microemulsion of hydrophilic monomers, a lipophilic solvent, the upconverting dyes, and a surfactant. Several glassy and rubbery materials are explored and a range of dyes that enable TTA‐UC in different spectral regions are utilized. The materials display upconversion efficiencies of up to ≈15%, approaching the performance of optimized oxygen‐free reference solutions. The data suggest that the matrix not only serves as mechanically coherent carrier for the upconverting liquid phase, but also provides good protection from atmospheric oxygen.