Synthesis of visible light-active nanostructured TiOx (x < 2) photocatalysts in a flame aerosol reactor

Titanium dioxide is a wide band gap (3.2 eV) semiconductor which is photo-active when irradiated with UV light. For wider scale use of TiO₂ as a photocatalyst, its activity needs to be extended to the visible light region (constituting 45% of total incident solar energy). A diffusion flame aerosol reactor (FLAR) with an oxygen lean environment in the particle formation zone has been used to synthesize oxygen deficient titanium suboxide (TiO_x with x < 2) nanoparticles. Using a standard-based electron energy loss spectroscopy (EELS) technique, the non-stoichiometry (x in TiO_x) in the flame synthesized particles has been quantified with high accuracy (uncertainty less than 3%). Under an oxygen lean environment in the particle formation zone, the non-stoichiometry in the TiO_x particles is a function of the flame temperature. The value of x in the flame synthesized TiO_x nanoparticles is in the range of 1.88 < x < 1.94. Diffuse reflectance spectra confirmed that the oxygen deficient TiO_x particles absorbed visible light. Visible light activity of the TiO_x particles is demonstrated by photocatalytic degradation of methyl orange solution under visible light illumination.     

Experimental and FE analysis of submerged arc weld induced residual stress and angular deformation of single and double sided fillet welded joint

Submerged arc welding is well-known for its very high deposition rate and thus the capability to join very high thickness metal pieces in large structural applications. Fillet joints are mostly used in structural applications which can be extensively seen in shipbuilding, bridge construction, house buildings, automobile or any other large structures. Thermal stresses generates in a fusion welded joint due to high temperature gradient, which is the cause of the residual stresses upon cooling followed by the angular deformation and failure of the welded structure. As an effect of the thermal gradient, the induced longitudinal, transverse residual stress & angular distortion can vary in single sided and double sided submerged arc welded fillet joints, during designing & manufacturing welded structures which should be taken into account. The main objective of this paper is to quantify the amount of residual stresses and angular deformation in a fillet welding joint. An elasto-plastic thermomechanical model has been developed for predicting residual stresses. A comparison of the residual stress and angular deformation between single and double sided fillet weld joint has been made. The simulation results reveal that the amount of residual stress present in the single sided fillet weld is more and unbalanced in both side of the center of weld line compared to the double sided fillet weld and the predicted results have been matched with the experiments as well as published literatures.     

Oxygen impurity in self-propagating high-temperature synthesis of NiAl

The technique of Self-propagating High-temperature Synthesis (SHS) was used to prepare NiAl from compacts using elemental powder mixtures in stoichiometric amounts under vacuum and argon atmosphere. Considerable changes in the oxygen contents of the specimen before and after the SH-synthesis were not observed. But, unusual occurrence of an impurity phase was noticed in the product as second phase precipitate. The sparsely distributed precipitates could be detected only in the Transmission Electron Microscope and was characterized to be an oxide of aluminium (-Al₂O₃) containing nickel oxide (NiO), whose solubility in -Al₂O₃ at room temperature has not been reported earlier. The occurrence of this phase could be traced to the oxygen on the surface of the reactant particles.     

Large-Eddy Simulation of High Reynolds Number Turbulent Flow Past a Square Cylinder

Flow past a square cylinder at a Reynolds number of 21,400 has been studied numerically using the large-eddy simulation technique. A dynamic subgrid-scale stress model has been used for the small scales of turbulence. The time- and span-averaged axial and transverse velocities in the downstream of the cylinder are in good agreement with the experimental results. The distribution of turbulent normal and shear stresses is also well predicted. The coherent and incoherent components of turbulent fluctuations at some specified phases have been separated and their relative magnitudes downstream of the cylinder have been compared. The comparison shows more coherence in the near wake than the far wake, while the coherent and incoherent components are of comparable magnitude in the far wake. The far wake shows irregular phase-averaged structures.     

A method for motion compensation of a moving nematode Caenorhabditis elegans and its application to frequency analysis of pharyngeal pulsation

A new sequential image processing method for motion compensation of a moving object with stringy shape has been developed for estimating the pharyngeal pulsation of the nematode Caenorhabditis elegans under several environmental conditions. The method is based on the pixel data transfer on a new image frame while changing the boundary shape and the position but preserving the conformation of the inner structure of an object. All digitized image frames of C. elegans were first converted to motion-compensated images to arrange the pulsation site in the same region of the every transformed frame. The pulsation site was then automatically detected by determining the pixels where the temporal brightness variation was much larger than that of the other pixels. Finally, the pulsation frequency was determined by the Fourier analysis. The validity of our method has been confirmed by analyzing various test data, and the method has been applied for detecting the pharyngeal pulsation frequencies of C. elegans on some environmental conditions, i.e. feed bacteria-free/rich, doping of nerve inactivating ethyl-alcohol and nerve stimulant neurochemical substance of serotonin. The motion compensation method automatically provided reasonable pulsation frequencies which were found to be comparable to those obtained by manual counting. Thus the method is useful for systematic investigations on the variation of pharyngeal pulsation associated with the activity change of the nervous system in environments.