Accelerated deactivation of medium-temperature lignite coke

Efforts are made to eliminate the self-heating and self-ignition of medium-temperature coke produced from Kansk-Achinsk brown coal (lignite) in a fluidized bed via “Termokoks-KS” technology. The optimal conditions of accelerated coke deactivation are found. The deactivation process is based on the low-temperature oxidation of coke by the surrounding air. Deactivation may be greatly accelerated at temperatures close to the critical temperature at which ignition occurs for samples of the given material.     

Selective Ring-Opening of Methylcyclopentane Over Titania-Supported Monometallic (Pt, Ir) and Bimetallic (Pt–Ir) Catalysts

An investigation of the selective ring-opening of methylcyclopentane (MCP) was conducted for the first time on Pt/TiO₂, Ir/TiO₂ and Pt?CIr/TiO₂ catalysts with low amounts of noble metals (0.5?wt%) over a temperature range of 180?C400?°C under hydrogen at atmospheric pressure. The catalysts were prepared by impregnation or co-impregnation and characterized by different physico-chemical techniques, including SEM, XRD, H₂-TPR, N₂-sorption, TEM and elemental analysis. The metallic particles were highly dispersed on the TiO₂ support at isodispersion of ~1?nm. The particles exhibited icosahedral Mackay structures limited by (111) planes. The catalytic results show that the activity in the MCP was strongly influenced by the intrinsic nature of the metal and by the temperature. The most active catalyst was Ir/TiO₂. The order of the reactivity as a function of the temperature and total conversion was Ir/TiO₂ 180?°C (???=?2?%)?>?Pt?CIr/TiO₂ 220?°C (???=?27.8?%)?>?Pt/TiO₂ 260?°C (???=?9.9?%). Under these conditions, all of the catalysts exhibited the ability to open the ring of MCP with an atom economy, without unwanted products of cracking and ring-enlargement reactions. The synergy between Pt?CIr bimetallic particles was assessed by the total conversion of MCP, whereas the ring-opening results indicated that the reaction took place on Ir sites. These results suggest that the bimetallic catalyst contained separate entities of two metals. Increased reaction temperatures led to reduced reaction selectivity with respect to ring-opening of MCP versus the cracking side reaction.     

Influence of Optimized Tire Shreds on Shear Strength Parameters of Sand

This paper presents the usefulness of optimizing the size of waste tire shreds on shear strength parameters of sand reinforced with shredded waste tires. A relatively, uniform sand has been mixed with randomly distributed waste tire shreds with rectangular shape and compacted at 2° of compaction. Waste tire shreds were prepared with a special cutter in three widths of 2, 3, and 4?cm and various lengths for each shred width. Three shred contents of 15, 30, and 50% by volume were chosen and mixed with the sand to obtain a uniformly distributed mixture. In order to compare the shear strength of different sand–tire shred samples, two compaction efforts in terms of sand matrix unit weights of 15.5 and 16.8?kN/m3 were considered. The results show that the influencing parameters on shear strength characteristics of sand–shred mixtures are normal stress, sand matrix unit weight, shred content, shred width, and aspect ratio of tire shreds. With the selected widths of shreds, compaction efforts, shred contents, and the variations of aspect ratios, it is possible to increase the initial friction angle ?1 up to 113.5%, that is ?1 = 67°. The average value for the influence of aspect ratio variations on increase in friction angle of the mixtures for all tests has been found to be about 25%. These average values for lower and higher compacted samples containing different widths and aspect rations were 37.6 and 17.2%, respectively. It has been investigated that for a given width of tire rectangular shreds, there is solely a certain length, which gives the greatest initial friction angle for sand–tire shred mixtures. This is the main contribution of this paper.     

Development and characterisation of (Ni, Cu, Co)-YSZ and Cu-Co-YSZ cermets anode materials for SOFC application

To improve the internal reforming reactions at SOFC anode, alternative (Ni, Cu, Co) -YSZ and Cu-Co-YSZ anode cermets materials are coated by atmospheric plasma spraying (APS). The spray parameters including carrying gas flow rate, spraying distance, argon flow rate and hydrogen flow rate were investigated by an orthogonal experiment to fabricate gas-permeable anode cermets coatings. Scanning electron microscopy and X-ray diffraction are used to characterise the morphology and structure of coated films respectively. The porosity was deduced by the statistical image analysis. By proper selection of the spray parameters to decrease the particles velocity and temperature, the sprayed coatings monometallic and bimetallic ones show that the cross porosity is dependent of metal weight ratio. In fact, when the metal percentage increases, the porosity decreases. Monometallic Ni-YSZ, Cu-YSZ and Co-YSZ cermets with a weight ratio of (3:2) appear to be less porous than those with (1:1) and (2:3) ones respectively, to reach a maximum porosity of 21.57% for Co-YSZ cermet of (2:3) weight ratio. Cu-Co-YSZ bimetallic cermet coating with weight ratio of (0.5:1:2.5) is more porous than those with (1:2:3) and (2:1:2) weight ratios respectively. Its porosity is about 19.15% which is closed to that of Ni-YSZ (2:3) coating. The X-ray diffraction results showed that the metal content in the cermets have a negligible influence on the crystalline phase structure. Such bimetallic materials anode are very interesting because Co diffuses in Cu lattice offering thus, best electronic conductivity, thermal stability and an avoided carbon formation, by replacing Ni with an electron conductor such as Cu that does not catalyze carbon formation.     

Comparison of graphene films grown on 6H-SiC and 4H-SiC substrates

Abstract

Atomic force microscopy, Kelvin-probe microscopy and Raman spectroscopy have been used to examine graphene films grown by thermal decomposition of the Si face of semi-insulating substrates of 6H-SiC and 4H-SiC polytypes in the atmosphere of argon. It was demonstrated that the quality of graphene grown on substrates of various polytypes at identical technological growth regimes is about the same. A conclusion was made that the differences in crystal structure between 6H-SiC and 4H-SiC does not lead to significant dissimilarities in the mechanism of sublimation of silicon carbide components from the surface of a crystal and in that of graphene crystallization.     

New sulfonated aramide nanoparticles and their copper complexes with anomalous dielectric behavior

We report the preparation of thermally stable spherical sulfonated aramides nanoparticles and their copper(II) complexes. Metal chelation with copper ions furnished polymeric complexes in a 1 : 2 ratio with square planar geometries as judged by their IR, UV, electron spin resonance, and elemental analysis data. The direct‐current electrical conductivities demonstrated the semiconducting nature of the polymeric particles and their copper complexes. Dielectric loss analysis studies showed spectral peaks appearing at characteristic frequencies, which suggested the presence of relaxing dipoles in all of the polymers. All loss peaks were shown on a linear frequency scale and appeared in the range of 1 decade, and no overlap was observed in any of the samples, whereas in the normal polymer's dielectric loss behavior, each peak covered more than 1 decade. Moreover, the peak positions did not change with increasing temperature; this indicated a nonactivated process. The reported dielectric results revealed anomalous behavior, which has not been reported before for such polymeric analogues, as the polarization in these cases was limited by nonthermal forces, and a steady‐state constant polarization was produced by an applied field. A simple method for the formation of a microporous semiconducting thin film of a polymer derived from isophthalic acid and diaminodiphenylsulfone is described. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013     

Evaluation of the genetic polymorphism among Lactococcus lactis subsp. cremoris strains using comparative genomic hybridization and multilocus sequence analysis

Genetic diversity of Lactococcus lactis subsp. cremoris provides an important reservoir of industrial functions. Knowledge of strain diversity is an important step for the selection of starter cultures, because technological and sensorial attributes are strain-dependent and it may help to distinguish strains with particular technological properties and performances. In the present study, microarray-based comparative genomic hybridization (CGH) and multilocus sequence analysis (MLSA) were used to investigate the genetic variation among eight strains of Lactococcus lactis subsp. cremoris. The CGH analysis allows strain grouping and identification of absent or divergent genes involved in metabolism, amino acid biosynthesis, osmoregulation and proteolysis. The MLSA clustering of strains based on the partial sequence of eight genes shows good correlation with the CGH grouping. Strains HP, ATCC 19257 and Wg2 were clustered together, followed by E8, and finally SK11 was in a separate cluster. The combined information provides genetic markers for distinguishing between strains and their variants. By selecting strains according to their genetic profiles, compatible and complementary mixed starters can be formulated, opening new avenues for industrial applications.     

SAFT-VNDN: A Socially-Aware Forwarding Technique in Vehicular Named Data Networking

Vehicular Social Networks (VSNs) is the bridge of social networks and Vehicular Ad-Hoc Networks (VANETs). VSNs are promising as they allow the exchange of various types of contents in large-scale through Vehicle-to-Vehicle (V2V) and Vehicle-to-Infrastructure (V2I) communication protocols. Vehicular Named Data Networking (VNDN) is an auspicious communication paradigm for the challenging VSN environment since it can optimize content dissemination by decoupling contents from their physical locations. However, content dissemination and caching represent crucial challenges in VSNs due to short link lifetime and intermittent connectivity caused by vehicles’ high mobility. Our aim with this paper is to improve content delivery and cache hit ratio, as well as decrease the transmission delay between end-users. In this regard, we propose a novel hybrid VNDN-VSN forwarding technique based on social communities, which allows requester vehicles to easily find the most suitable forwarder or producer among the community members in their neighborhood area. Furthermore, we introduce an effective caching mechanism by dividing the content store into two parts, one for community private contents and the second one for public contents. Simulation results show that our proposed forwarding technique can achieve a favorable performance compared with traditional VNDN, in terms of data delivery ratio, average data delivery delay, and cache hit ratio.     

Impact of Treated Wastewater Reuse on Agriculture and Aquifer Recharge in a Coastal Area: Korba Case Study

Treated wastewater (TWW) reuse has increasingly been integrated in the planning and development of water resources in Tunisia. The present study aimed the evaluation of the environmental and health impact that would have the reuse of TWW for crops direct irrigation or for the recharge of the local aquifer in Korba (Tunisia). For this purpose water analyses were carried on the TWW intended for the aquifer recharge and on underground water of this area. As for underground water before recharge, no contamination by organic matter or heavy metals is shown but high salinity, nitrate, potassium and chloride concentrations are detected. The bacteriological analyses show the occurrence of faecal streptococcus, thermo-tolerant coliforms, total coliforms and E coli, but absence of salmonella. These results indicate that this water is not suitable for irrigation worse still for drinking purpose. The monitoring of TWW pollutants has demonstrated that oxygen demands (COD and BOD) do not exceed the Tunisian standards for TWW used in agriculture (NT 106.03) except for August when samples reach high values (COD = 139 mg O₂ L^− 1, BOD = 34). It is also the case for temperature, electrical conductivity (EC), salinity and pH. Heavy metal concentrations are under the detection limit. The determination of nutrients shows relatively low concentrations of nitrates, nitrites and orthophosphate (the maxima in mg L^− 1 are respectively 6.6, 5.6 and 0.92) whereas the potassium levels are high (up to 48.8 mg L^− 1) and the ammonia levels very high, reaching 60.6 mg L^− 1. As for bacteriological pollution, while no salmonella and intestinal nematods are detected, high concentrations of total coliforms, thermo-tolerant coliforms, faecal streptococci and E. coli are analysed. Consequently, the better use of TWW in this region would be the use of infiltration basins for the recharge of the deteriorated aquifer by TWW. It would give the opportunity to better the quality of the TWW reaching the groundwater by an additional treatment for bacteriological and suspended solid (TSS) contaminants while being an alternative water for the aquifer recharge and a coastal barrier against seawater intrusion.