全文获取类型
收费全文 | 279830篇 |
免费 | 7013篇 |
国内免费 | 2992篇 |
学科分类
工业技术 | 289835篇 |
出版年
2021年 | 3452篇 |
2020年 | 2470篇 |
2019年 | 2722篇 |
2018年 | 4107篇 |
2017年 | 4129篇 |
2016年 | 4382篇 |
2015年 | 3712篇 |
2014年 | 5742篇 |
2013年 | 12645篇 |
2012年 | 9204篇 |
2011年 | 11750篇 |
2010年 | 9523篇 |
2009年 | 9865篇 |
2008年 | 10712篇 |
2007年 | 10633篇 |
2006年 | 9437篇 |
2005年 | 8183篇 |
2004年 | 7297篇 |
2003年 | 6912篇 |
2002年 | 6991篇 |
2001年 | 7010篇 |
2000年 | 6402篇 |
1999年 | 6241篇 |
1998年 | 13117篇 |
1997年 | 9739篇 |
1996年 | 7505篇 |
1995年 | 5688篇 |
1994年 | 5194篇 |
1993年 | 5025篇 |
1992年 | 4019篇 |
1991年 | 3806篇 |
1990年 | 3870篇 |
1989年 | 3758篇 |
1988年 | 3517篇 |
1987年 | 2999篇 |
1986年 | 3027篇 |
1985年 | 3399篇 |
1984年 | 3299篇 |
1983年 | 3044篇 |
1982年 | 2683篇 |
1981年 | 2872篇 |
1980年 | 2626篇 |
1979年 | 2822篇 |
1978年 | 2722篇 |
1977年 | 2826篇 |
1976年 | 3680篇 |
1975年 | 2442篇 |
1974年 | 2281篇 |
1973年 | 2309篇 |
1972年 | 1974篇 |
排序方式: 共有10000条查询结果,搜索用时 203 毫秒
132.
L.C. Souza A.C.A. Silva N.O. Dantas P.C. Morais S.W. da Silva 《Ceramics International》2018,44(1):208-215
Successful fabrication of glass-based hybrid nanocomposites (GHNCs) incorporating Ag, core-shell CdSe/CdS and CdSxSe1?x nanoparticles (NPs) is herein reported. Both metallic (Ag) and semiconductor (CdSe/CdS) NPs were pre-synthesized, suspended in colloids and added into the sol-gel reaction medium which was used to fabricate the GHNCs. During fabrication of the nanocomposites a fraction (20–60%) of core-shell CdSe/CdS NPs was alloyed into CdSxSe1?x (0.20 < x < 0.35) NPs without changing morphology. Modulation of in situ alloying is possible via the relative content of organics added into the sol-gel protocol. Within colloids Ag (core-shell CdSe/CdS) NPs presented average diameter and polydispersity index of 49.5 nm (4.2 nm) and 0.41 (0.21), respectively. On the other hand, the Ag (core-shell CdSe/CdS) NPs’ average diameter and polydispersity index assessed from the GHNCs were respectively 51.5 nm (4.1 nm) and 0.43 (0.25), revealing negligible aggregation of the nanophases within the glass template. The new GHNCs herein introduced presented two independent excitonic transitions associated to homogenously dispersed semiconductor NPs, peaking around 420 nm (core-shell CdSe/CdS) and 650 nm (CdSxSe1?x) and matching the plasmonic resonance (Ag NPs) in the 400–500 nm range. We envisage that the new GHNCs represent very promising candidates for superior light manipulation while illuminated with multiple laser beams in quantum interference-based devices. 相似文献
133.
Zdeněk Slanina Filip Uhlík Lipiao Bao Takeshi Akasaka Xing Lu Ludwik Adamowicz 《Fullerenes, Nanotubes and Carbon Nanostructures》2020,28(7):565-570
AbstractRelative populations of four energy-lowest IPR (isolated-pentagon-rule) isomers of Eu@C86 are computed using the Gibbs energy based on characteristics from density functional theory calculations (M06-2X/3-21G?~?SDD entropy term, M06-2X/6-31G*~SDD or B2PLYP(D)/6-31G*~SDD energetics). The calculations confirm that the recently isolated Eu@C1(7)-C86 species is a major isomer in a relevant temperature region. Relationship to the empty C86 cages is discussed, too. 相似文献
134.
135.
Temperature history can have a significant effect on the strength of water-saturated chalk.In this study,hydrostatic stress cycles are applied to understand the mechanical response of chalk samples exposed to temperature cycling between each stress cycle,compared to the samples tested at a constant temperature.The total accumulated strain during a stress cycle and the irreversible strain are reported.Chalk samples from Kansas(USA)and Mons(Belgium),with different degrees of induration(i.e.amount of contact cementation),were used.The samples were saturated with equilibrated water(polar)and nonpolar Isopar H oil to quantify water weakening.All samples tested during 10 stress cycles with varying temperature(i.e.temperature cycled in between each stress cycle)accumulated more strain than those tested at constant temperatures.All the stress cycles were performed at 30℃.The two chalk types behaved similarly when saturated with Isopar H oil,but differently when saturated with water.When saturated with water,the stronger Kansas chalk accumulated more total strain and more irreversible strain within each stress cycle than the weaker Mons chalk. 相似文献
136.
137.
The red grape berry pigments, anthocyanins, were characterized in the early 20th century, but investigations of wine pigments were stymied during that era. The question of their identity was a major challenge for wine chemists. A number of techniques showed that the pigments were polymeric in nature. Some structures were postulated by mid-century based on reactions between anthocyanins and condensed tannin, and later postulated wine pigments were observed in model reactions. Some related compounds were then observed in wine. By the end of the 20th century, the ionization of non-volatiles for mass spectrometry opened the door to these compounds. In addition, a new class of compounds was observed, the pyranoanthocyanins, a product of fermentation and aging metabolites with anthocyanins. These compounds possess the pigment stability to SO2 and pH change that is characteristic of aged red wine. Aging experiments show a dynamic situation with shifts in the population of pigment classes over time. The very large number of diverse pigments explains why it has been so difficult to answer the century-old question of the structure of wine pigments. Our current understanding is founded on the use of mass spectral analysis using electrospray and related ionization techniques over the last 25 years. Future progress will rely on more sophisticated analysis of this very complex mixture of substances. © 2019 Society of Chemical Industry 相似文献
138.
Y.K. Yang F.L. Liu Y.W. Zhang M.F. Li F. Ling H.T. Wu 《Ceramics International》2018,44(11):12238-12244
In this work, ultra-low loss Li2MgTi0.7(Mg1/3Nb2/3)0.3O4 ceramics were successfully prepared via the conventional solid-state method. X-ray photoelectron spectroscopy (XPS), thermally stimulated depolarization current (TSDC) and bond energy were used to determine the distinction between intrinsic and extrinsic dielectric loss in (Mg1/3Nb2/3)4+ ions substituted ceramics. The addition of (Mg1/3Nb2/3)4+ ions enhances the bond energy in unit cell without changing the crystal structure of Li2MgTiO4, which results in high Q·f value as an intrinsic factor. The extrinsic factors such as porosity and grain size influence the dielectric loss at lower sintering temperature, while the oxygen vacancies play dominant role when the ceramics densified at 1400?°C. The Li2MgTi0.7(Mg1/3Nb2/3)0.3O4 ceramics sintered at 1400?°C can achieve an excellent combination of microwave dielectric properties: εr =?16.19, Q·f?=?160,000?GHz and τf =??3.14?ppm/°C. In addition, a certain amount of LiF can effectively lower the sintering temperature of the matrix, and the Li2MgTi0.7(Mg1/3Nb2/3)0.3O4-3?wt% LiF ceramics sintered at 1100?°C possess balanced properties with εr?=?16.32, Q·f?=?145,384?GHz and τf =??16.33?ppm/°C. 相似文献
139.
Wang Lu-di Zhou Wei Xing Ying Liu Na Movahedipour Mahmood Zhou Xiao-guang 《浙江大学学报:C卷英文版》2019,20(3):405-413
Frontiers of Information Technology & Electronic Engineering - Reconstruction of a 12-lead electrocardiogram (ECG) from a serial 3-lead ECG has been researched in the past to satisfy the need... 相似文献
140.
视觉里程计利用视频信息来估计相机运动的位姿参数,实现对智能体的定位。传统视觉里程计方法需要特征提取、特征匹配/跟踪、外点剔除、运动估计、优化等流程,解算非常复杂,因此,提出了基于卷积神经网络的方法来实现端对端的单目视觉里程计。借助卷积神经网络对彩色图片自动学习提取图像帧间变化的全局特征,将用于分类的卷积神经网络转化为帧间时序特征网络,通过三层全连接层输出相机的帧间相对位姿参数。在KITTI数据集上的实验结果表明,提出的Deep-CNN-VO模型可以较准确地估计车辆的运动轨迹,证明了方法的可行性。在简化了复杂模型的基础上,与传统的视觉里程计系统相比,该模型的精度也有所提高。 相似文献