Plasma‐modified poly(vinyl alcohol) membranes for the dehydrationof ethanol

Non‐porous poly(vinyl alcohol) (PVA) membranes prepared by a cast‐evaporating technique were covered with an allyl alcohol or acrylic acid plasma‐polymerized layer. The wettability and the surface energy, as well as the chemical nature of the deposit, were assigned by X‐ray photoelectron spectroscopy (XPS) and Fourier‐transform infrared spectroscopy (FTIR). The ability of the modified membranes for dehydrating the water/ethanol azeotropic mixture by pervaporation was studied at 25, 40 and 60 °C. The best selectivity (α = 250 at 25 °C) was obtained in the case of the allyl alcohol plasma treatment. The results obtained are discussed on the basis of the hydrophilicity as well as in terms of the weakly crosslinked superficial layer that favoured the membrane swelling. Copyright © 2003 Society of Chemical Industry     

Extraction and functional properties of gelatin from the skin of cuttlefish (Sepia officinalis) using smooth hound crude acid protease-aided process

The characteristics and functional properties of gelatin from skin cuttlefish (Sepia officinalis) were investigated and compared to those of halal bovine gelatin (HBG). The gelatin extraction efficiency was improved by an acid-swelling process in the presence of smooth hound crude acid protease extract (SHCAP). The yields of gelatins from cuttlefish skin after 48 h with acid and with crude acid protease (15 units/g alkaline-treated skin) were 2.21% and 7.84%, respectively. The gelatin from skin cuttlefish had high protein (91.35%) but low fat (0.28%) contents. Compared to HBG, the cuttlefish-skin gelatin (CSG) has different amino acids composition than halal bovine gelatin. CSG contained slightly low hydroxyproline and proline (180‰) than HBG (219‰), whereas the content of serine was higher (49‰ versus 29‰). The gel strength of the gelatin gel from CSG (181 g) was lower than that of HBG (259 g) (p < 0.05) possibly due to lower hydroxyproline content. Cuttlefish-skin gelatin exhibited a similar emulsifying activity but greater emulsifying and foam stability than the halal bovine gelatin (p < 0.05). Foam formation ability, foam stability and water-holding capacity of CSG were slightly lower than those of the HBG, but fat-binding capacity was higher in the cuttlefish gelatin.     

A Higher-Order Chimera Method for Finite Volume Schemes

In this work a higher-order accurate finite volume method for the resolution of the Euler/Navier–Stokes equations using Chimera grid techniques is presented. The formulation is based on the use of Moving Least Squares approximations in order to obtain higher-order accurate reconstruction and connectivity between the overlapped grids. The accuracy and performance of the proposed methodology is demonstrated by solving different benchmark problems.     

Modelling of sintering during rotational moulding of the thermoplastic polymers

This paper concerns the study of sintering phenomenon during rotational molding of polypropylene(PP),Polyvinylidenefluoride (PVDF) and Polymethyl methacrylate (PMMA). First, the coalescence (first step of sintering) of two grains has been followed. Bellehumeur’s model has been tested as a model to explain this phenomenon. In order to study the effect of neighboring grains on coalescence of two grains, a third grain has been put in contact with these two grains. For modeling the phenomenon in this case, Bellehumeur’s model has been modified by a geometric parameter called Farz Factor (FF), being this model validated by experimental test. Concerning densification, two different stages have been observed. In the first stage, before welding of the grains and formation of interphases between them, the grains are not stuck yet. The air trapped between the grains escapes through free ways between grains. This first step of densification is directly related to the coalescence where the density of the polymer varies very quickly. A new tridimensional model, based on a Body Centered Tetragonal (BCT) configuration, has been proposed to explain the densification during this first stage. In the second stage, the migration of air is controlled by diffusion.     

Changes in phytate and minerals during germination and cooking of fenugreek seeds

The effects of germination, cooking and roasting on the phytic acid content, total phosphorus, water soluble inorganic phosphorus and mineral content of fenugreek seeds have been estimated. After 96 h germination, the dry weight of fenugreek seeds decreased while total ash content increased. Phytase and phosphatase activity of the ungerminated and germinated seeds have been assayed. It is observed that during germination the phytic acid values diminish and the water soluble inorganic phosphorus values increase. Phytase activity which is absent in the ungerminated seeds originates after germination and the phosphatase activity is increased in the germinated seeds. Heat treatment practised in cooking and roasting fenugreek seeds has less effect on phytate elimination than does germination. Changes in calcium, magnesium, iron, manganese, copper and zinc are found to be dependent on the loss of dry weight which occurs during processing of fenugreek seeds.     

Preliminary studies on the mucilages extracted from Okra fruits,Taro tubers,Jew's mellow leaves and Fenugreek seeds

Okra fruits, Taro tubers, Jew's mellow leaves and Fenugreek seeds are commonly used in Egypt to prepare popular diets with desired slimy consistency.The mucilages were extracted and preliminary studies conducted to characterise them physically. The pH values of a 1% solution of the mucilages varied from 6·9-7·5 for Okra and Taro, 7·1–7·8 for Jew's mellow, and 5·9-6 for Fenugreek, depending upon extraction conditions. The highest viscosity was observed in Okra solutions, followed by Fenugreek, Jew's mellow and Taro mucilages. Okra and Jew's mellow mucilages are acidic polysaccharides which contain higher amounts of ash than the Taro and Fenugreek mucilages which are neutral polysaccharides. All mucilages are associated with protein. Gel chromatography indicated strong interaction of protein with the polysaccharide. The acid hydrolysis of the mucilages followed by paper chromatography revealed that all mucilages contain methyl pentose, glucose, galactose, and fructose, in different proportions. Taro and Fenugreek mucilages are free of rhamnose. All mucilages are devoid of arabinose and mannose except Fenugreek which contained these two sugars.     

Hygrothermal behavior modeling of the hygroscopic envelopes of buildings: A dynamic co-simulation approach

High levels of humidity in buildings lead to building pathologies. Moisture also has an impact on the indoor air quality and the hygrothermal comfort of the building’s occupants. To better assess these pathologies, it is necessary to take into account the heat and moisture transfer between the building envelope and its indoor ambience. In this work, a new methodology was developed to predict the overall behavior of buildings, which combines two simulation tools: COMSOL Multiphysics© and TRNSYS. The first software is used for the modeling of heat, air and moisture transfer in multilayer porous walls (HAM model: Heat, Air and Moisture transfer), and the second is used to simulate the hygrothermal behavior of the building (BES model: Building Energy Simulation). The combined software applications dynamically solve the mass and energy conservation equations of the two physical models. The HAM-BES coupling efficiency was verified. In this paper, the use of a coupled (HAM-BES) co-simulation for the prediction of the hygrothermal behavior of building envelopes is discussed. Furthermore, the effect of the 2D HAM modeling on relative humidity variations within the building ambience is shown. The results confirm the importance of the HAM modeling in the envelope on the hygrothermal behavior and energy demand of buildings.     

A study on electrodeposited zinc oxide nanostructures

Zinc oxide (ZnO) nanostructures prepared by electrochemical deposition method from aqueous zinc nitrate solution at 65 °C onto fluorine doped tin oxide coated glass substrates were investigated. Characterization of ZnO nanostructures was realized using conventional electrochemical techniques, scanning electron microscopy (SEM) and X-ray diffraction (XRD) techniques. Cyclic voltammetry experiments were performed to elucidate the electrodic processes that occurred when potentials were applied and the optimum potential for electrodeposition were determined. From the Mott-Schottky measurements, the flat-band potential and the donor density for the ZnO nanostructure are determined. From single-step potential experiment in the potential ranges from ?1.1 to ?1.4 V, the formation of ZnO nuclei in the early deposition stages was proceeded according to the three dimensional (3D) instantaneous nucleation followed by diffusion-limited growth rather than a progressive one. SEM images demonstrated that the morphology of ZnO nanostructures depend greatly on the potential depositions. XRD studies revealed that the deposited films were polycrystalline in nature with wurtzite phase.