An evaluation of fuelwood properties of some Aravally mountain tree and shrub species of Western India

The study analyses the fuelwood characteristics of 26 trees including shrub species from the dry deciduous forest in Aravally region, Rajasthan, Western India was carried out to explore trees with potential for fuelwood production. Fuelwood value index (FVI) based on the properties of calorific value, wood density and ash. Calorific value was ranged between 18.54 ± 0.04 and 27.44 ± 0.09 KJ g⁻¹ in Jatropha curcus and Wrightia tinctoria respectively. Wood density varied from 0.538 ± 0.01 to 0.966 ± 0.07 g/cm³ in J. curcus and Acacia nilotica. Same way ash and moisture content was highest in J. curcus (3.38 ± 0.19%) and Sterculia urens (70.28 ± 7.52%) and lowest in Miliusa tomentosa (0.85 ± 0.06%) and Azadirachta indica (30.7 ± 10.02%) respectively. On the basis, of the 26 species analyzed, M. tomentosa has the highest FVI, followed by Lannea coromandelica, Acacia leucophloea, Madhuca indica, A. nilotica, W. tinctoria, Butea monosperma, Zizyphus nummularia, S. urens, Boswellia serrata, A. indica, Grewia tenax, Syzygium cuminii, Tectona grandis and Dalbergia sissoo were shown to have promising fuelwood production.     

Analysis of Fatty Acid and Lignan Composition of Indian Germplasm of Sesame to Evaluate Their Nutritional Merits

An attempt was made to individually analyze a germplasm collection of 54 indigenous Indian sesame cultivars for fatty acid and lignan composition of their seed oil by gas chromatography and high performance liquid chromatography, respectively. The entries varied in their fatty acid and lignan composition. The mean percentage contents of palmitic, stearic, oleic, linoleic and α‐linolenic acids ranged between 10–22, 5–10, 38–50, 18–43 and less than 1 whereas sesamol, sesamin and sesamolin scored between 3–37, 27–67, 20–59 of the total percentage of lignan, respectively. The highest percentage of α‐linolenic acid (ALA) was obtained in Var‐9 (1.3 % of the total fatty acids). Among the lignans, high sesamin content is considered to be significant, particularly in terms of long shelf life and nutraceutical value of sesame seed oil. The study has broadened our understanding related to differential biochemical composition of the rich sesame germplasms, thereby providing us with a useful groundwork for identifying potential targets and suitable cultivars for genetic engineering approaches to be undertaken in order to improve the nutritional quality of sesame oil, which in turn would be beneficial towards human health.     

Poly dimethylsiloxane/carbon nanofiber nanocomposites: fabrication and characterization of electrical and thermal properties

This article presents the fabrication and characterization of poly dimethylsiloxane/carbon nanofiber (CNF)-based nanocomposites. Although silica and carbon nanoparticles have been traditionally used to reinforce mechanical properties in PDMS matrix nanocomposites, this article focuses on understanding their impacts on electrical and thermal properties. By adjusting both the silica and CNF concentrations, 12 different nanocomposite formulations were studied, and the thermal and electrical properties of these materials were experimentally characterized. The developed nanocomposites were prepared using a solvent-assisted method providing uniform dispersion of the CNFs in the polymer matrix. Scanning electron microscopy was employed to determine the dispersion of the CNFs at different length scales. The thermal properties, such as thermal stability and thermal diffusivity, of the developed nanocomposites were studied using thermogravimetirc and laser flash techniques. Furthermore, the electrical volume conductivity of each type of nanocomposite was tested using the four-probe method to eliminate the effects of contact electrical resistance during measurement. Experimental results showed that both CNFs and silica were able to impact on the overall properties of the synthesized PDMS/CNF nanocomposites. The developed nanocomposites have the potential to be applied to the development of new load sensors in the future.     

Gelatin‐carbohydrate phase‐separated hydrogels as bioactive carriers in vaginal delivery: Preparation and physical characterizations

The current study focuses on the alteration of properties of the gelatin hydrogels using polysaccharides (e.g., maltodextrin, dextran, and sodium carboxymethyl cellulose) for probable use in vaginal delivery of antimicrobials. The hydrogels were prepared by varying the proportions of gelatin and polysaccharides and were characterized by microscopy, mechanical testing, and impedance spectroscopy. Metronidazole (MZ), drug of choice for the treatment of bacterial vaginosis, was incorporated within the hydrogels. In vitro release studies of MZ from the hydrogels was studied in‐depth using modified Franz's diffusion cell. Antimicrobial efficiency of the MZ‐loaded hydrogels was tested against E. coli and B. subtilis. The results suggested that the incorporation of polysaccharides resulted in the phase‐separated hydrogels. The properties of the hydrogels was found be suitable for vaginal delivery. The drug release and antimicrobial efficiency from the hydrogels suggested that the developed hydrogels may be used for the delivery of antimicrobials in the vaginal lumen. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40445.     

A relativistic two-parameter core-envelope model of compact stars

A core-envelope model for a spherical superdense distribution of matter is reported, with a core consisting of anisotropic fluid engulfed by an envelope containing fluid with isotropic pressure is reported. The background space-time of the whole configuration is characterized by a two-parameter parabolic geometry. The physical plausibility of the model is examined both analytically and numerically, and suitability of the model for describing space-times of superdense stars containing strange matter, such as Her-X1 and SAX, is also discussed.     

Analysis of the “Wavelet Tree Quantization” watermarking strategy and a modified robust scheme

Here we study a recently proposed watermarking scheme based on the paper “Wavelet Tree Quantization” (WTQ) by Wang and Lin (IEEE Trans Image Process 13(2):154–165, 2004). In given scheme, wavelet coefficients corresponding to the same spatial locations are grouped together. Two such groups, selected at random, constitute a supertree. Some of these supertrees are quantized to embed the watermark information in the image. In the process of cryptanalysis we first identify the groups which are quantized during the watermark insertion process. Then we select the non-quantized groups and quantize them too, to remove the watermark. Experimental results show that the watermark is completely removed by this attack. The cryptanalysis falls under the cipher text only jamming attack which requires only a single watermarked copy. Further, we suitably modify the WTQ scheme to make it robust against such cryptanalytic attacks.This is an extended and revised version of the paper Cryptanalysis of “Wavelet Tree Quantization” Watermarking Scheme presented at the International Workshop on Distributed Computing, IWDC 2004, Kolkata, 27–30 December 2004, Lecture Notes in Computer Science, vol. 3326, pp. 219–230. Springer, Berlin Heidelberg New York (2004). Section 4 of this paper introduces a modified scheme which is an addition over the conference version. Part of this work has been done while the author T. K. Das was visiting Indian Statistical Institute, Kolkata during 2004.     

Chiral discrimination of basic and hydrophobic molecules by chemical force spectroscopy

Chemical force spectroscopy (CFS) is becoming a powerful technique with which to measure intermolecular forces. The prime advantage over other techniques is the ability to map spatial distribution of ligands on the surface. We have used CFS to explore the binding force of a variety of different chiral molecules in order to understand more about the nature of what is a fundamental aspect of chemical biology and of central importance in pharmacology.     

Contribution of organomodified clay on hybrid microstructures and properties of epoxidized natural rubber‐based nanocomposites

Influence of organic modifying agent of clay on dispersion, distribution, hybrid microstructure formation, and associated performance properties of epoxidized natural rubber‐based composites was evaluated. Binary and ternary composites of carbon black (CB) and two organomodified layered silicates (i.e., nanomer I30E and Cloisite 30B) were prepared and characterized based on small angle X‐ray scattering, transmission electron microscopy, hydrodynamic swelling, tensile measurement, and dynamic mechanical analyses. Greater extent of exfoliation and “nanounit” formation was noted in ternary composites containing nanomer I30E, which was reflected in higher interfacial roughness (d_s = 2.82) and lower radius of gyration (R_g = 205 Å). Morphological observations suggested higher nanomer I30E–CB interactions than that of Cloisite 30B–CB. The interplatelet distance in Cloisite 30B (d = 1.83 nm) stacks was lower than that of nanomer I30E (d = 2.26 nm). These two factors jointly contributed in higher breakdown of nanomer I30E stacks by CB than that of Cloisite 30B stacks. Greater exfoliation and nanounit formation in I30E–CB‐filled nanocomposite was also reflected in increased degree of crosslinking (n = 20 × 10^?5%), tensile modulus/strength, half height width of damping peak (20.3°C), and filler effectiveness (C = 0.33). POLYM. ENG. SCI., 2013. © 2012 Society of Plastics Engineers     

Investigation on jet stability,fiber diameter,and tensile properties of electrospun polyacrylonitrile nanofibrous yarns

Electrospinning is a flexible and efficient method for producing nanofibers by using relatively dilute polymer solution. However, there are many parameters related to material and processing that influence the morphology and property of the nanofibers. This study investigates the influence of electric field and flow rate on diameter and tensile properties of nanofibers produced using polyacrylonitrile (PAN)‐dimethylformamide (DMF) solution. Stability of the spinning jet is investigated via fiber current measurement and an image system at different electric fields and solution flow rates. It is observed that a set of electric field and flow rate conditions favor producing thinnest, strongest, and toughest nanofibers during electrospinning process. Other conditions may lead to instability of the Taylor cone, discontinuous jet, larger diameter fiber, and lower mechanical properties. Finally, a simple dynamic whipping model is adopted to correlate the nanofiber diameter with volumetric charge density and is found to be excellent validating our experimental results. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41918.     

Inverse and efficiency of heat transfer convex fin with multiple nonlinearities

In this article, we first propose the novel semi‐analytical technique—modified Adomian decomposition method (MADM)—for a closed‐form solution of the nonlinear heat transfer equation of convex profile with singularity where all thermal parameters are functions of temperature. The longitudinal convex fin is subjected to different boiling regimes, which are defined by particular values of n (power index) of heat transfer coefficient. The energy balance equation of the convex fin with several temperature‐dependent properties are solved separately using the MADM and the spectral quasi‐linearization method. Using the values obtained from the direct heat transfer method, the unknown parameters of the profile, such as thermal conductivity, surface emissivity, heat generation number, conduction‐convection parameter, and radiation‐conduction parameter are inversely predicted by an inverse heat transfer analysis using the simplex search method. The effect of the measurement error and the number of measurement points has been presented. It is found that present measurement points and reconstruction of the exact temperature distribution of the convex fin are fairly in good agreement.