Effect of sulfate on Cu(Ⅱ) sorption to polymer-supported nano-hydrated ferric oxides: Experimental and modeling studies

Incorporating of hydrous ferric oxide(HFO) inside porous supports with large sizes has become an effective way to decontaminate the water from heavy metals. Ubiquitous anions like sulfate are usually present in high concentrations in water, and might greatly affect adsorption behavior of hybrid HFO. Here, a polymer-based HFO-CPS was fabricated by encapsulating nano-HFO inside a chloromethylated polystyrene polymer(CPS) and the reactivity of HFO-CPS with Cu(Ⅱ) was evaluated in the presence of sulfate ions.Surface complexation theory was firstly employed to describe the effect of sulfate on Cu(Ⅱ) adsorption edges of hybrid HFO-CPS, where constant capacitance model(CCM) was adopted. The available weak adsorption site Fe_((2))OH of hybrid HFO-CPS was found to decrease from 20% Fe to 5% Fe, which might be caused by the pore plugging effect after HFO encapsulation. With the assumption that a ternary complex was formed, the effect of sulfate on Cu(Ⅱ) adsorption by HFO-CPS were successfully described by CCM using the optimized Fe_((2))OH site under different sulfate concentrations(1 or 10 mmol·L~(-1)) and Cu/Fe ratios(0.0042 or 0.0252). It is confirmed that the formation of Fe OHCu SO_4 ternary surface complexes played an important role in enhancing Cu(Ⅱ) adsorption on HFO-CPS in the presence of sulfate.     

电场耦合取能技术的仿真与试验研究

为给输电线路的监测器件提供稳定、便利的电源,基于电磁感应的原理设计了无线电容取电装置,可以最大化利用空间能量,对支撑输电线路的运行状态监测具有重要意义。首先,分析了电容取电的结构,以此得到取能装置输出功率与高压杂散电容、低压杂散电容、负载电阻等参数的计算关系,发现合理增加感应电极面积、减小感应电极电容值和增加负载电阻值可以有效提升取能装置输出功率;其次,利用多物理场仿真软件模拟了电容取电的影响因素,最后,通过Matlab软件设计了高压实验装置,对实际情况进行模拟与实验。实验结果表明,当电源电压为10 k V、耦合电容为14 p F时,1 MΩ的负载可以得到0.12 m W功率。     

PAN/FPU Composite Nanofiber Membrane with Superhydrophobic and Superoleophobic Surface as a Filter Element for High-Efficiency Protective Masks

Recently, because of the outbreak of COVID-19, the demand for various types of filter elements in protective materials has increased globally. Furthermore, new requirements for the filtration performance of PM2.5 liquid (oil) particles have been put forward. In this work, Superhydrophobic and superoleophobic composite nanofibers with excellent filtration capacity for oil and salt particles are developed through the modification of polyacrylonitrile (PAN) by fluoro-polyurethane (FPU) doping. The results show that the PAN/FPU composite nanofibers doped with 9 wt% FPU has a uniform fiber morphology with a diameter of 240 ± 30 nm. Compared to the pure PAN nanofibers, the water-based contact angle of PAN/FPU increases from 90 ± 5° to 151 ± 5°, and the oil-based contact angle increases from 58 ± 2° to 152 ± 3°. Importantly, at a high flow rate of 95 L min⁻¹, the filtration efficiency of the PAN/FPU nanofiber membrane for 0.3 µm oil particles increases from 92 ± 1% to 99.2 ± 0.1%. After cyclic loading, the filtration efficiency of 0.3 µm oil particles remains above 98%. Meanwhile, the filtration efficiency for 0.3 µm salt particles remains at 98.23 ± 0.1%. The PAN/FPU nanofiber membrane developed in this work is effective in applications and has good market prospects as a protective filtration material.     

改性环氧树脂在立磨主减速机基础修复的应用

某公司一条60万t/年矿渣微粉生产线,使用的是其他公司出售的二手立磨设备,经过异地拆卸、分解运输至新生产线进行组装和调试。经过3个月左右的使用,立磨主减速机出现了较大幅度的周期性摆动（无需仪器检测,肉眼可见摆动幅度）,基础钢底板周期性弹动。     

Co-colouration Effects in the Systems of Metal(Ⅱ)-Rare Earth(Ⅲ)-Xanthene Dye and Their Influences on Photometric Determination of Metal Ions

After comparing the influences of each rare earth(Ⅲ),11 species of metal(Ⅱ)and 8 species of acidictriphenylmethane dye on the formation of coloured coordination compound in the system of Metal(Ⅱ)-RE(Ⅲ)-Dye,it was proven that the co-colouration effect can be caused only by the xanthene dyes(XD)con-taining substituting hydroxy.group on the ortho-position of etheric oxygen group.Besides,the radius of met-al(Ⅱ)must not be smaller than a definite limit;otherwise,no co-colouration appears.Furthermore,the acid-ity of medium is another important factor to affect co-colouration,Bromopyrogallol red causesco-colouration of Pb(Ⅱ)-RE(Ⅲ)only,owing to its higher chromophoric acidity;while alizarin violet causesco-colouration of M(Ⅱ)-RE(Ⅲ)(M=Pb,Ca,Sr and Ba),due to its lower chromophoric acidity.The condi-tions causing co-colouration,the regularities of co-colouration and the influences of co-colouration inphotometric determination of metals were discussed.     

The improvement of thermal error modeling and compensation on machine tools by CMAC neural network

In this paper, a cerebellar model articulation controller (CMAC) neural network is proposed for thermal error modeling in machine tools. The CMAC is a systematic learning algorithm which can search for the nonlinear and interaction characteristics between the thermal errors and temperature field on the machine tools. The CMAC is investigated in terms of accuracy in prediction, robustness to sensor placement, speed of learning, and tolerance to sensor failures. Experimental measurements of the spindle drift errors for both a horizontal machining center and a CNC turning center were performed using capacitance sensors and thermal sensors. Results show that the CMAC model has better performance than other modeling methods in robustness to sensor placement and speed of learning. This makes determination of the sensor locations easier, and reduces calibration time. In addition, a sensor failure detection algorithm is developed to provide better reliability.     

含B4C中性盐浴渗硼工艺问题的研究

在含Ｂ４Ｃ中性盐浴渗硼的高温反应研究的基础上，对该盐浴存在的工艺问题进行了分析研究。指出了渗硼能力均匀性，工件表面腐蚀斑与玻璃体的关系，分析了老化盐致使工件清洗困难的成因。     

报废车回收离国际化标准还有多远

国家发改委、科技部、环保总局正式对外发布的<汽车产品回收利用技术政策>中明确指出,加强汽车生产者责任的管理,在汽车生产、使用、报废、回收等环节建立起以汽车生产企业为主导的管理体系,并提出自2010年起,我国汽车生产企业或进口汽车总代理商要负责回收处理其销售的汽车产品及其包装物品.     

低成本钛合金制备技术研究进展

为了降低钛合金的生产成本,美、俄、日、中等国家都在此领域进行了广泛的研究。对国际上新出现的以降低钛合金生产成本为目的的新冶金方法、新的低成本合金化钛合金和新的加工生产技术进行了综述。目前,国际上研究较为活跃的低成本钛冶炼新方法有FFC剑桥法、Armstrong工艺、EMR复合阳极工艺、SRI工艺、Idaho钛工艺及OS工艺。其中,以FFC剑桥法为代表的TiO2直接电解还原方法,最有希望成为替代传统Kroll工艺的新方法。     

热型连铸过程的一维稳态传热模型

根据热型连铸技术原理，建立了热型连铸凝固过程一维稳态温度场的物理、数学模型。通过数值计算，得出了铸型出口温度、冷却距离、拉铸速度和喷水冷却强度等工艺参数对铸坯固液界面位置的影响。计算结果与试验结果吻合。