采用同步变化量的超高压线路保护启动判据研究

超高压线路保护在运行中受负荷波动影响,负荷不对称的线路在正常运行时,都存在较大零序电流,为防止频繁启动不得不提高启动值,从而降低了启动元件的灵敏度,导致现有的零序电流判据对经高阻接地的故障无法灵敏判别,不能满足超高压线路保护对启动元件快速性的要求。提出一种采用线电压、同相间电流同步变化量开放的相间启动判据和零序电流、相电流同步变化量比较方式的零序启动判据。通过PSCAD/EMTDC仿真表明,如果使用同步变化量的启动判据,保护的灵敏度、快速性和可靠性均有一定程度的提高。     

安防大数据应用研究

描述了安防大数据的几个来源,论述了安防大数据实施中存在的难题,并据此提出了安防大数据实施的要点和步骤,最后重点分析了安防大数据的整体架构、与现有视频监控平台的关系以及基于GPU的安防大数据平台的系统架构.安防大数据实施时必须根据数据特点及算法成熟度分阶段进行.     

基于遗传算法的机器人加工位姿优化研究

针对工业机器人的加工效果具有位姿依赖性这一特点,基于机器人性能评价指标和遗传算法提出一种优化机器人加工位姿的方法.建立机器人正运动学模型和静刚度模型并选取机器人运动性能评价指标和刚度性能评价指标;通过蒙特卡罗法得到机器人运动性能、刚度性能在关节空间和笛卡儿空间的分布图,通过分布图研究机器人各关节对机器人运动性能、刚度性能的影响;基于机器人运动性能评价指标和刚度性能评价指标设计适应度函数,使用遗传算法对机器人加工位姿进行优化,优化后机器人性能得到了提升.     

Exploration on tribological behaviours of perrhenates as potential lubricating oil additive during a wide temperature range

The perrhenates of calcium, copper and lead used as oil additive were synthesised by using the aqueous solution method. The tribological properties of these perrhenates were examined by using a ball‐on‐disc tribotester during a wide temperature range and a four‐ball testing machine at room temperature. The four‐ball test results showed that all synthesised perrhenates presented good extreme pressure property to a certain degree and demonstrated satisfactory wear resistance at room temperature. The ball‐on‐disc experiment results showed that the base oil with perrhenate additives significantly decreased friction and wear compared with pure base oil at elevated temperatures. An antifriction and low‐shear layer was verified to form on sample surface after testing under high temperature. This layer effectively prevented the direct contact of sliding surfaces and decreased the friction coefficient. The antifriction behaviour of perrhenates implied that they could be developed as the candidate of oil additives for a hybrid lubricating mode. Copyright © 2015 John Wiley & Sons, Ltd.     

基于能见度图的元胞疏散最短路径模型研究

近年来发生的火灾多在人员密集场所,当突发事件发生时,人员疏散往往特别困难,因此,规划行人在大型公众聚集建筑物中的疏散路径非常重要。基于能见度图建构的元胞疏散最短路径模型可直接用于实际的紧急疏散指示路径的规划,避免设置大量逃生指示装置致使工程成本过高及视觉不美观,并且也解决了有限制逃生指示装置数量当作限制条件的最大涵盖面积的求解复杂、空间大的问题。     

Synthesis,characterization and polymerization of novel sugars based on methacrylate

The present study describes the synthesis and characterizations of polymerizable vinyl sugars. Glucose, mannose, galactose and fructose are abundant and sustainable natural compounds. As it is not possible to make many derivatives of sugars without using protective groups, first of all, diacetone derivatives [diacetone-d-glucose (1), diacetone-d-mannose (2), diacetone-d-galactose (3) and diacetone-d-fructose (4)] were synthesized according to the literature as starting compounds. The remaining free hydroxyl groups on C-3 (diacetone glucose), C-6 (diacetone galactose), C-1 (diacetone fructose) and C-1 (diacetone mannose), were reacted with epichlorohydrin (1-chloro-2,3-epoxypropane) to produce then “-O-(2′,3′-epoxypropane-1′-yl)” ether derivatives (5, 6, 7, and 8) which are epoxy sugars in the basic medium. Next, the epoxy rings of the ethers (5, 6, 7, and 8) were opened with methacrylic acid in DMF to produce new sugar based methacrylates (9, 10, 11, and 12). Finally, free radical polymerization of these sugar based methacrylate monomers was performed, producing related polymers (13, 14, 15 and 16). The polymerizations were carried out using AIBN as an initiator at 70 °C in DMF. All the products were characterized by FTIR, ¹HNMR and ¹³CNMR techniques. Thermal properties of all polymers were investigated by TG, DTG and DSC. The data obtained has suggested that thermal stability of the synthesized polymers has changed with the structure of the sugar and increase in molecular weight.     

Utilization of Electrospun Polystyrene Membranes as a Preliminary Step for Rapid Diagnosis

Recent advances in clinical practice drive deoxyribonucleic acid (DNA) as an important class of biomarker. Monitoring the change in their concentration suggests the initiation and/or progression of various disorders. However, low quantity of DNA biomarkers in body fluids requires a delicate isolation methodology that provides efficient separation and easy handling. This study describes a newer‐generation separation technology relying on electrospun fibers of sub‐micrometer diameter of a commodity polymer for DNA biomarkers in simulative serum. Fibrous polystyrene membranes are prepared by electrospinning and they are subjected to post‐modification with Au. The composite membranes may provide a convenient environment for the removal of bovine serum albumin (BSA) from BSA and DNA mixtures. The eluent can be used as an efficient tool for detection of DNA biomarkers associated with diagnosis of numerous life‐threatening diseases.

     

用于钯催化载体的P改性高孔隙率γ-Al2O3/α-Al2O3泡沫(英文)

提出了一种新方法来制备用于钯催化剂的P-γ-Al₂O₃涂层改性的α-Al₂O₃泡沫。采用聚氨酯模板法,通过优化工艺参数,使陶瓷泡沫的显气孔率达到90.28%,体积密度达到0.45 g·cm^-3,且该泡沫具有可使用强度。将掺有P元素的γ-Al₂O₃涂层涂覆在α-Al₂O₃泡沫上,然后通过超声波辅助浸渍法来装载活性催化相(Pd)。结果表明,含P涂层增加了惰性泡沫的比表面积和弱酸性位点,同时减少了强酸性位点的占比。与无涂层的泡沫相比,改性的泡沫更容易装载活性相,且装载的金属Pd不容易被氧化,CO的催化转化温度(T₅₀,T₉₀)降低了50℃左右。该研究证明了低成本改性α-Al₂O₃陶瓷泡沫在钯催化剂生产中具有极大的应用潜力。     

Electrochemical copper (II) sensor based on chitosan covered gold nanoparticles

This study outlines a new sensing platform based on glassy carbon electrodes modified by gold nanoparticles (AuNPs) for the determination of heavy metal. A glassy carbon electrode was modified by chitosan stabilized AuNPs. AuNPs were prepared by reducing gold salt with a polysaccharide chitosan. Here, chitosan acted as a reducing/stabilizing agent. The AuNPs were characterized with UV–Visible absorption spectroscopy, Fourier transform infrared spectroscopy, and transmission electron microscopy. Chitosan covered AuNPs were immobilized on the glassy carbon electrode for the determination of Cu (II) in aqueous solutions. The electrochemical determination of Cu (II) ions was performed using the differential pulse voltammetry technique. Some parameters for Cu (II) determination, such as pH, preconcentration time and electrolysis potential of Cu (II), were optimized. The detection limit was calculated as 5 × 10^?9 mol L^?1 by means of the 3:1 current-to-noise ratio. The interference of Cr(III), Fe(II), Ni(II), Pb(II), Mg(II), Zn(II), Ba(II) ions was investigated and showed a negligible effect on the electrode response. Recovery studies were carried out using tap water.