Low energy oblique ion beam sputtering induced surface engineering of polyethylene terephthalate

ABSTRACT

In the present work, the self-organized pattern formation with simultaneous surface smoothing of Polyethylene terephthalate (PET) by 40 keV Ar+ ions irradiation has been discussed. The effect of most important experimental parameter i.e. ion beam incidence that control these processes has been discussed by varying off normal incidences from 30⁰ to 50⁰. The changes in surface topography have been studied using Atomic Force Microscopy (AFM). It has been investigated from AFM analysis that oblique ion beam induced sputtering significantly reduced the surface roughness with simultaneous formation of some hillock and hole like structures.     

Study of electroless template synthesized ZnSe nanowires and its characterization

In this work, the successful synthesis of ZnSe nanowires using alumina template by simple and facile electroless template technique has been reported. Morphological characterization of the synthesized nanowires has been done by X-ray diffraction (XRD) and scanning electron microscopy (SEM) measurements. The optical characterizations were conducted by UV–visible and time resolved photo-luminescence. Grain size of synthesized ZnSe nanowires was also calculated using the XRD results. The calculated crystallite size was found to be 6.80 nm. SEM analysis confirms the fabrication of nanowires successfully and it also confirms the size of the nanowires as per the template parameters. The calculated band gap value of 3.03 eV shows the origin of quantum confinement effect in ZnSe nanowires even at the 100 nm scale. The time resolved photoluminescence result indicates that the ZnSe nanowires can be a promising material for luminescent applications in micro-second time domain.     

Parametric study of a reverse flat plate absorber cabinet dryer: A new concept

In this communication, the concept of reverse flat plate collector has been used as a heating medium of air for the drying of agricultural products in a cabinet dryer. The reverse flat plate absorber is a non-concentrating collector which can collect solar heat at high temperature unlike conventional nonconcentrating collectors. The thermal performance of the proposed dryer is analyzed by solving the various energy balance equations. An attempt has been made to optimize the vent area of the dryer for speedy flow of humid air from the drying chamber to the atmosphere. In order to have parametric studies, numerical computations have been carried out for a typical day in June for Delhi climatic conditions. The performance of this system is compared with that of conventional cabinet dryers. It is found that the reverse flat plate absorber dryer gives the better performance.     

GFEM analysis of MHD nanofluid flow toward a power‐law stretching sheet in the presence of thermodiffusive effect along with regression investigation

In the current study, we use Galerkin finite‐element simulation to analyze the concept of triple diffusive flow with magnetic field effect toward a power law stretching sheet. The fluid comprises dissolved solutal particles and nanoparticles in the base fluid. The three important mechanisms that are responsible for rise in phenomenon of convective transportation are diffusophoresis, thermophoresis along with Brownian motion have been considered. Recently, the proposed nanoparticles' mass flux and heat flux boundary conditions have been imposed. Nanoparticle mass transportation, solutal mass transportation with heat transportation for prominent physical parameters, such as stretching parameter, magnetic influence parameter, thermophoresis parameter, and Brownian motion parameter are calculated. To further verify and understand the strength of the relationship between heat transportation rate and controlling parameters, the multiple regression process is used. The finite difference approach was adopted to numerically solve the nonlinear governing equations and the linked boundary conditions. In the present study, we used MATLAB software for finding the final outcomes and relating the concluding results for $?{{\theta }_{\delta }}^{\prime }\left(0\right)$ with extant outcomes in the literature as a limiting case in the absence of the magnetic intensity parameter and an excellent agreement was noted. It was observed that the magnetic field has a positive effect on heat and mass transfer. This study also helps in understanding and thus controlling the velocity of the flow along with solutal depositions, which has a significant engineering application in the process of extrusion. The findings of the present study help to control the rate of heat and mass transfer, aiding manufacturing companies in obtaining the desired quality of product.     

Solar assisted biogas plants III: Energy balance of fixed dome biogas plants and enhancement of production in winters

This paper presents a thermal model of a fixed dome biogas plant, with or without hot charging and having the ground surface above the plant, blackened and glazed. The rate of energy transfer, between the ground and the plant has been determined by electrical simulation experiments, using a small scale model of the plant (made of copper), suspended in copper sulphate solution. For hot charging a shallow solar pond, built on the ground has been considered. The monthly variation of the slurry temperature, corresponding to 1, 4, 8, 15 and 30 m³ plants have been evaluated for Madras, New Delhi and Srinagar, which correspond to typical hot, composite and cold climates; the following cases have been considered:

• 1 Bare plant, without hot charging and blackening/glazing of the ground, above the plant.
• 2 Plant, charged with hot slurry from a shallow solar pond.
• 3 Plant, with ground above blackened and glazed.
• 4 Plant, with ground above blackened and double glazed and also provision for heating the slurry by burning a part of the produced biogas.

It is seen that blackening and single glazing of the ground above the plant is able to maintain the slurry temperature between 28 and 35°C throughout the year in composite climate such as Delhi; in cold climates even double glazing alone is not enough for that purpose. Hot charging from a shallow solar pond alone is not sufficient to maintain satisfactory slurry temperatures in winters of Delhi and of course Srinagar. In hot climates the slurry temperature is sufficiently high, except for a couple of months, when either hot charging from a shallow solar pond or blackening/glazing of the ground above is sufficient to have the slurry temperature in the desirable range. In cold climates such as Srinagar, the desired slurry temperatures can be maintained if a part of the gas produced is burnt for heating the slurry, in addition to blackening and double glazing of the ground above the dome. Theoretical predictions of slurry temperatures have been compared with the field data recorded for an 8 m³ digester at the Energy Complex, Masoodpur, Delhi; the agreement is satisfactory.     

Forecasting of daily air quality index in Delhi

As the impact of air pollutants on human health through ambient air address much attention in recent years, the air quality forecasting in terms of air pollution parameters becomes an important topic in environmental science. The Air Quality Index (AQI) can be estimated through a formula, based on comprehensive assessment of concentration of air pollutants, which can be used by government agencies to characterize the status of air quality at a given location. The present study aims to develop forecasting model for predicting daily AQI, which can be used as a basis of decision making processes. Firstly, the AQI has been estimated through a method used by US Environmental Protection Agency (USEPA) for different criteria pollutants as Respirable Suspended Particulate Matter (RSPM), Sulfur dioxide (SO₂), Nitrogen dioxide (NO₂) and Suspended Particulate Matter (SPM). However, the sub-index and breakpoint concentrations in the formula are made according to Indian National Ambient Air Quality Standard. Secondly, the daily AQI for each season is forecasted through three statistical models namely time series auto regressive integrated moving average (ARIMA) (model 1), principal component regression (PCR) (model 2) and combination of both (model 3) in Delhi. The performance of all three models are evaluated with the help of observed concentrations of pollutants, which reflects that model 3 agrees well with observed values, as compared to the values of model 1 and model 2. The same is supported by the statistical parameters also. The significance of meteorological parameters of model 3 has been assessed through principal component analysis (PCA), which indicates that daily rainfall, station level pressure, daily mean temperature, wind direction index are maximum explained in summer, monsoon, post-monsoon and winter respectively. Further, the variation of AQI during the weekends (holidays) and weekdays are found negligible. Therefore all the days of week are accounted same in the models.     

Implications of proxy caching for provisioning networks and servers

In this paper, we examine the potential benefits of Web proxy caches in improving the effective capacity of servers and networks. Since networks and servers are typically provisioned based on a high percentile of the load, we focus on the effects of proxy caching on the tail of the load distribution. We find that, unlike their substantial impact on the average load, proxies have a diminished impact on the tail of the load distribution. The exact reduction in the tail and the corresponding capacity savings depend on the nature of the workload and the percentile of the load distribution chosen for provisioning networks and servers-the higher the percentile, the smaller the savings. For workloads considered in this study, compared with over a 50% reduction in the average load, the savings in network and server capacity was only 20%-35% for the 99th percentile of the load distribution. We also find that while proxies can be somewhat useful in smoothing out some of the burstiness in Web workloads; the resulting workload continues, however, to exhibit substantial burstiness and a heavy-tailed nature. We identify one-time requests for large objects to be the limiting factor that diminishes the impact of proxies on the tail of load distribution. We conclude that, while proxies are immensely useful to users due to the reduction in the average response time, they are less effective in improving the capacities of networks and servers.     

Calculated fiber attenuation: a general method yielding stationaryvalues

A method of calculating the attenuation constant of an optical fiber under very general but weakly guiding conditions is derived. The method, based on Galerkin's formalism, allows a nonuniform and complex refractive-index profile. The real and imaginary parts of the refractive index are allowed to vary independently and arbitrarily as a function of radius. The result is the predicted complex propagation constant. The results are inherently stationary     

High-Brightness Wavelength Beam Combined Semiconductor Laser Diode Arrays

We report the wavelength beam combining of an array of high-power high-brightness 970-nm slab-coupled optical waveguide lasers. A 50-W peak power under quasi-continuous-wave (CW) operation was measured in an output beam with a beam quality of M_x,y ²=1.2, and 30 W under CW operation was measured with a beam quality of M_x,y ²=2     

Enzyme‐catalyzed regioselective synthesis of sugar esters and related compounds

In this review, a comprehensive and illustrative survey is made of the regioselective synthesis of esters of sugars and related compounds using lipases. The main emphasis has been given to the screening and use of commercially available lipases for the enzymatic esterification of neutral monosaccharides, disaccharides, sugar alcohols and their selected ether and ester derivatives. The effect of solvents and solubilizing agents in improving the yields of the resultant sugar fatty acid esters has been incorporated. Further, solvent‐free esterification with molten fatty acids, use of ionic liquids and microwave radiations for improvement in the methodology have also been discussed. Copyright © 2006 Society of Chemical Industry