High-Efficiency Polycrystalline CdS/CdTe Solar Cells on Buffered Commercial TCO-Coated Glass

Multiple polycrystalline CdS/CdTe solar cells with efficiencies greater than 15% were produced on buffered, commercially available Pilkington TEC Glass at EPIR Technologies, Inc. (EPIR, Bolingbrook, IL) and verified by the National Renewable Energy Laboratory (NREL). n-CdS and p-CdTe were grown by chemical bath deposition (CBD) and close space sublimation, respectively. Samples with sputter-deposited CdS were also investigated. Initial results indicate that this is a viable dry-process alternative to CBD for production-scale processing. Published results for polycrystalline CdS/CdTe solar cells with high efficiencies are typically based on cells using research-grade transparent conducting oxides (TCOs) requiring high-temperature processing inconducive to low-cost manufacturing. EPIR’s results for cells on commercial glass were obtained by implementing a high-resistivity SnO₂ buffer layer and by optimizing the CdS window layer thickness. The high-resistivity buffer layer prevents the formation of CdTe-TCO junctions, thereby maintaining a high open-circuit voltage and fill factor, whereas using a thin CdS layer reduces absorption losses and improves the short-circuit current density. EPIR’s best device demonstrated an NREL-verified efficiency of 15.3%. The mean efficiency of hundreds of cells produced with a buffer layer between December 2010 and June 2011 is 14.4%. Quantum efficiency results are presented to demonstrate EPIR’s progress toward NREL’s best-published results.     

The costs, air quality, and human health effects of meeting peak electricity demand with installed backup generators

Existing generators installed for backup during blackouts could be operated during periods of peak electricity demand, increasing grid reliability and supporting electricity delivery. Many generators, however, have non-negligible air emissions and may potentially damage air quality and harm human health. To evaluate using these generators, we compare the levelized private and social (health) costs of diesel internal combustion engines (ICE) with and without diesel particulate filters (DPF), natural gas ICEs, and microturbines to a new peaking plant in New York, NY. To estimate the social cost, first we calculate the upper range emissions for each generator option from producing 36,000 megawatt-hours (MWh) of electricity over 3 days. We then convert the emissions into ambient concentrations with a 3-D chemical transport model, PMCAMx, and Gaussian dispersion plumes. Using a Monte Carlo approach to incorporate the uncertainties, we calculate the health endpoints using concentration-response functions and multiply the response by its economic value. While uncontrolled diesel ICEs would harm air quality and health, a generator with a DPF has a social cost, comparable to natural gas options. We conclude on a full cost basis that backup generators, including controlled diesel ICEs, are a cost-effective method of meeting peak demand.     

Ratings of semiconductors for AC drives

This paper discusses the characteristics and limitations of various power semiconductors used in motor controls and drives. Semiconductor types discussed include the insulated gate bipolar transistor (IGBT), transistor (bipolar and MOS device), SCR, gate-turn-off transistor (thyristor) (GTO), and diode. Important limitations, including voltage rating, current ratings, safe operating area, heat transfer characteristics, and limitations due to a particular device characteristic are discussed. The focus is on the IGBT; its advantages and disadvantages are discussed, as well as how it can be rated in a drive application     

Particle velocity and deposition efficiency in the cold spray process

Copper powder was sprayed by the cold gas-dynamic method. In-flight particle velocities were measured with a laser two-focus system as a function of process parameters such as gas temperature, gas pressure, and powder feed rate. Mean particle velocities were uniform in a relatively large volume within the plume and agreed with theoretical predictions. The presence of a substrate was found to have no significant effect on in-flight particle velocities prior to impact. Cold-spray deposition efficiencies were measured on aluminum substrates as a function of particle velocity and incident angle of the plume. Deposition efficiencies of up to 95% were achieved. The critical velocity for deposition was determined to be about 640 m/s for the system studied.