Ion track-based electronic elements

In the past years, fundaments were set for a new type of electronics which is based on tracks in insulators formed by individual or multiple swift heavy ions. Due to the possibility of inserting any (semi)conducting material into these tracks, various active and passive electronic devices can be created. Among them are also transistor-like and Esaki diode-like elements. As many of these structures have sensing properties and the capability to undergo logic decisions, autonomous intelligent sensors appear to be a favourite field for future application. The use of liquid conductors may even expand the range of applicability towards medical implants.     

Low temperature fabrication of magnesium phosphate cement scaffolds by 3D powder printing

Synthetic bone replacement materials are of great interest because they offer certain advantages compared with organic bone grafts. Biodegradability and preoperative manufacturing of patient specific implants are further desirable features in various clinical situations. Both can be realised by 3D powder printing. In this study, we introduce powder-printed magnesium ammonium phosphate (struvite) structures, accompanied by a neutral setting reaction by printing farringtonite (Mg₃(PO₄)₂) powder with ammonium phosphate solution as binder. Suitable powders were obtained after sintering at 1100°C for 5 h following 20–40 min dry grinding in a ball mill. Depending on the post-treatment of the samples, compressive strengths were found to be in the range 2–7 MPa. Cytocompatibility was demonstrated in vitro using the human osteoblastic cell line MG63.     

缓解影响原则：缓解影响的评估及平衡程序

德国在20世纪70年代时就已经开始做环境评估，并且发展得非常快。环境污染问题的产生让人们意识到自然资源的消耗是不可持续的。所以在1976年，通过了首个关于减少环境影响的法律法规。1988年，德国环保局针对人们的居住地环境做出了一些规定，同时它也再一次提到了减少环境影响，所有大的开发商都必须高度重视这一点。在法律当中还规定了一系列的项目，这些项目都要合乎环保标准，它具有法律约束力，所有的地方都要遵守。比如说要恢复旧的居住地的时候，必须按照环保的规定来做。     

Rotor position and velocity estimation for a salient-pole permanentmagnet synchronous machine at standstill and high speeds

This paper addresses self-sensing (“sensorless”) control of salient-pole permanent magnet synchronous motors (PMSMs). The major contribution of this work is the introduction of a simple-to-implement estimation technique that operates over a wide speed range, including zero speed. The technique achieves simplicity by decoupling the inherent cross-coupling in PMSMs. The technique utilizes the dependence of inductance on rotor position in interior permanent magnet machines to produce position and velocity estimates both for field orientation and for all motion control of the drives. The technique functions in a manner similar to a resolver and resolver-to-digital converter (RTDC) sensing system, whereby in the proposed technique the motor acts as the electromagnetic resolver and the power converter applies carrier-frequency voltages to the stator which produce high-frequency currents that vary with position. The sensed currents are then processed with a heterodyning technique that produces a signal that is approximately proportional to the difference between the actual rotor position and an estimated rotor position. This position error signal and a torque estimate are then used as inputs to a Luenberger style observer to produce parameter insensitive, zero lag, position and velocity estimates     

Properties of CsI(TI) — Renaissance of an old scintillation material

CsI(TI) is an interesting material for calorimeters in high energy physics. Properties of this material are reported.     

Electrochemical impedance spectroscopy on porous electrodes

Electrochemical d.c. and a.c. measurements have been carried out on porous Raney nickel in H₂-saturated 0.1 M, 1 M, and 6 M NaOH solutions atT=303 K and 333 K using rotating-disc and static-plaar electrodes. For comparison, measurements were also performed on graphite-cloth and graphite-felt electrodes. From polarization curves and current transients obtained in the potential range of the hydrogen evolution and hydrogen oxidation reactions the dependence of the electrocatalytic activity of Raney nickel on the prepolarization conditions was studied. Impedance spectra in the frequency range 1 mHzf 10 kHz were used to determine the characteristic pore parameters and to identify the kinetic behaviour of the porous electrodes by application of transfer function analysis using non-linear fit routines.     

Simple N‐Heterocyclic Carbenes as Ligands in Ullmann‐Type Ether and Thioether Formations

A simple N‐heterocyclic carbene (NHC) derived from 1‐methyl‐3‐ethylimidazolium tetrafluoroborate was found to be an efficient ligand for a range of copper‐catalyzed cross‐coupling reactions, leading to the formation of aromatic ethers and thioethers.

     

Biological properties of iron oxide nanoparticles for cellular and molecular magnetic resonance imaging

Superparamagnetic iron-oxide particles (SPIO) are used in different ways as contrast agents for magnetic resonance imaging (MRI): Particles with high nonspecific uptake are required for unspecific labeling of phagocytic cells whereas those that target specific molecules need to have very low unspecific cellular uptake. We compared iron-oxide particles with different core materials (magnetite, maghemite), different coatings (none, dextran, carboxydextran, polystyrene) and different hydrodynamic diameters (20-850 nm) for internalization kinetics, release of internalized particles, toxicity, localization of particles and ability to generate contrast in MRI. Particle uptake was investigated with U118 glioma cells und human umbilical vein endothelial cells (HUVEC), which exhibit different phagocytic properties. In both cell types, the contrast agents Resovist, B102, non-coated Fe(3)O(4) particles and microspheres were better internalized than dextran-coated Nanomag particles. SPIO uptake into the cells increased with particle/iron concentrations. Maximum intracellular accumulation of iron particles was observed between 24 h to 36 h of exposure. Most particles were retained in the cells for at least two weeks, were deeply internalized, and only few remained adsorbed at the cell surface. Internalized particles clustered in the cytosol of the cells. Furthermore, all particles showed a low toxicity. By MRI, monolayers consisting of 5000 Resovist-labeled cells could easily be visualized. Thus, for unspecific cell labeling, Resovist and microspheres show the highest potential, whereas Nanomag particles are promising contrast agents for target-specific labeling.     

Nonlinear model predictive control for dividing wall columns

Dividing wall columns (DWCs) are practical, effective, and promising among distillation process intensification technologies. Nonlinear model predictive control (NMPC) schemes are developed in this study to control the three-product DWCs. As these systems are intensely interactive and highly nonlinear, NMPC may be more suitable than the traditional PI control. The model is established based on Python and Pyomo platforms. As the original mathematical model of the column section is ill-posed, index reduction is used to avoid a high-index differential-algebraic equation (DAE) system. The well-posed index-1 system after index reduction is employed for the steady-state simulation and dynamic control in this study. Case studies with three DWC configurations to separate the mixture of ethanol (A), n-propanol (B), and n-butanol (C) show that the NMPC performs very well with small maximum deviations and short settling times. This demonstrates that the NMPC is a feasible and very effective scheme to control three-product DWCs.