Highly basic CaO nanoparticles in mesoporous carbon materials and their excellent catalytic activity

Highly basic CaO nanoparticles immobilized mesoporous carbon materials (CaO-CMK-3) with different pore diameters have been successfully prepared by using wet-impregnation method. The prepared materials were subjected to extensive characterization studies using sophisticated techniques such as XRD, nitrogen adsorption, HRSEM-EDX, HRTEM and temperature programmed desorption of CO2 (TPD of CO2). The physico-chemical characterization results revealed that these materials possess highly dispersed CaO nanoparticles, excellent nanopores with well-ordered structure, high specific surface area, large specific pore volume, pore diameter and very high basicity. We have also demonstrated that the basicity of the CaO-CMK-3 samples can be controlled by simply varying the amount of CaO loading and pore diameter of the carbon support. The basic catalytic performance of the samples was investigated in the base-catalyzed transesterification of ethylacetoacetate by aryl, aliphatic and cyclic primary alcohols. CMK-3 catalyst with higher CaO loading and larger pore diameter was found to be highly active with higher conversion within a very short reaction time. The activity of 30% CaO-CMK3-150 catalyst for transesterification of ethylacetoacetate using different alcohols increases in the following order: octanol > butanol > cyclohexanol > benzyl alcohol > furfuryl alcohol.     

Lie group analysis for the effects of temperature-dependent fluid viscosity and chemical reaction on MHD free convective heat and mass transfer with variable stream conditions

This paper concerns with a steady two-dimensional flow of an electrically conducting incompressible fluid over a vertical stretching surface. The flow is permeated by a uniform transverse magnetic field. The fluid viscosity is assumed to vary as a linear function of temperature. A scaling group of transformations is applied to the governing equations. The system remains invariant due to some relations among the parameters of the transformations. After finding three absolute invariants a third-order ordinary differential equation corresponding to the momentum equation and two second-order ordinary differential equation corresponding to energy and diffusion equations are derived. The equations along with the boundary conditions are solved numerically. It is found that the decrease in the temperature-dependent fluid viscosity makes the velocity to decrease with the increasing distance of the stretching sheet. At a particular point of the sheet the fluid velocity decreases with the decreasing viscosity but the temperature increases in this case. It is found that with the increase of magnetic field intensity the fluid velocity decreases but the temperature increases at a particular point of the heated stretching surface. Impact of chemical reaction in the presence of thermal radiation plays an important role on the concentration boundary layer. The results thus obtained are presented graphically and discussed.     

Modelling Corrosion Behavior of Friction Stir Processed Aluminium Alloy 5083 Using Polynomial: Radial Basis Function

Aluminium alloy 5083, widely used in marine applications, undergoes accelerated corrosion in sea water due to the aggressive reaction of chloride ions with the secondary phase particles and other intermetallics present in the alloy matrix. The corrosion rate of the alloy is also influenced by the temperature difference between the alloy and its environment. Friction stir processing (FSP) is a recent solid state processing technique for improving the surface properties of metals and alloys. In this study, an attempt has been made to explore the possibility of improving the corrosion resistance of AA5083 by FSP. FSP trials were performed by varying the tool rotation speed, tool traverse speed and shoulder diameter of the tool, as per face centered central composite design. The corrosion potential and the corrosion rate of friction stir processed AA5083 was studied using potentiodynamic polarization studies, at three different temperatures. Mathematical models based on polynomial—radial basis function were developed and used to study the effect of process parameters on the corrosion potential and the corrosion rate of friction stir processed AA5083. FSP resulted in refinement of the grain structure, dispersion and partial dissolution of secondary phase particles in the matrix, which increased the corrosion resistance of the alloy.     

Variation Of Airflow Pattern Through Dissimilar Valve Lift In A Spark Ignition Engine

Abstract

Bi-fuel conversions are a common alternative fuelling option for mono-fuel gasoline SI vehicles because of the minor vehicle modifications required. In Malaysia, most bi-fuel vehicles are fuelled with compressed natural gas (CNG) and gasoline. However, CNG flame speed is lower than gasoline reducing the power and range of the vehicle when operating on CNG. This situation can be improved by increasing the flame speed via higher swirl generation. A Computational fluid dynamics model is used to analyse swirl generated by dissimilar valve lift (DVL) profiles on the intake valve. A three-dimensional engine simulation shows differences in swirl motion and turbulence between the original symmetric valve lift profile and the DVL. The higher swirl number reduces the turbulence kinetic energy level slightly. The best case profile is selected for further experimental testing.     

Antagonism of microRNA function in zebrafish embryos by using locked nucleic acid enzymes (LNAzymes)

MicroRNAs (miRNAs) have crucial functions in many cellular processes, such as differentiation, proliferation and apoptosis; aberrant expression of miRNAs has been linked to human diseases, including cancer. Tools that allow specific and efficient knockdown of miRNAs would be of immense importance for exploring miRNA function. Zebrafish serves as an excellent vertebrate model system to understand the functions of miRNAs involved in a variety of biological processes. We designed and employed a strategy based on locked nucleic acid enzymes (LNAzymes) for in vivo knockdown of miRNA in zebrafish embryos. We demonstrate that LNAzyme can efficiently knockdown miRNAs with minimal toxicity to the zebrafish embryos.     

Synthesis and morphological control of europium doped cadmium sulphide nanocrystals

Europium doped cadmium sulphide (Cd(0.98)Eu(0.2)S) nanostructures were synthesised by chemical co-precipitation method using ethylene glycol (EG) and deionized water (Eu:CdS-1), and isopropyl alcohol (IPA) and deionized water (Eu:CdS-2) as mixed solvents. It has been found that the nanostructure of the europium doped CdS can be controlled by simply varying the mixed solvent system. Powder XRD pattern reveals the formation of hexagonal (wurtzite) and cubic (zinc blende) structure for Eu:CdS-1, and Eu:CdS-2, respectively. The crystallite size of the sample prepared using IPA and deionized water was measured to be 2.64 nm which is much smaller than that of the sample prepared using EG and deionized water as mixed solvent (3.65 nm). Morphology of the materials can also be changed from flower shaped crystals to paddy like structures by varying the mixed solvents. Band gap values of Eu3+ doped CdS nanocrystals synthesized from two different solvents were estimated using UV-reflectance spectra. The size and crystallinity of the samples were confirmed by HRTEM and SAED analysis. A significant change in the PL emission of the CdS nanocrystals was observed for the europium doped CdS which is mainly due to the presence of EU3+ ions which also play a significant role in the energy transfer process. It was also observed that the shift in the emission and efficiency depends on size and shape of the synthesised nanoparticles.     

Synthesis and evaluation of trimethylolpropane triacrylate crosslinked superabsorbent polymers for conserving water and fertilizers

A series of superabsorbent polymers (SAP) were synthesized by free radical thermal copolymerization of acrylic acid and N‐isopropyl acrylamide monomers using trimethylolpropane triacrylate as crosslinker. They were characterized by FT‐IR and thermal stability (TGA/DTG), and evaluated for their water and fertilizer uptake and release characteristics under different crosslinker levels, temperature, pressure, and pH. The observed maximum absorption of water by the SAP was 1130 g/g of polymer. The release was modeled which showed a non‐Fickian mechanism. The water uptake of SAP was correlated with the average molecular weight between the crosslinks and crosslink density. Analysis of the weight loss data from TG in air revealed a zero order kinetics for the initial degradation step with an activation energy (AE) of 70.8 kJ/mol. The AEs for water uptake and release for thermal degradation were also determined through Arrhenius plots. The results inferred that the synthesized SAP can be exploited for commercial agricultural applications. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013     

Optimization of Process Parameters for Decortication of Finger Millet Through Response Surface Methodology

Decorticated finger millet is prepared by hardening the endosperm by hydrothermal processing and polishing the processed grains. The yield of the decorticated grains is of paramount importance in the millet industry. Milling yield depends on the grain moisture content and incipient moisture conditioning during milling. It was found that steaming conditions such as steaming time and steam pressure significantly influenced the milling yield. Hence, studies were undertaken to determine the influence of moisture and steaming conditions on the yield of decorticated millet. Steaming conditions were optimized through response surface methodology. The responses studied were hardness, milling yield, porosity and water uptake of hydrothermally processed millet. The studies indicated that hydrothermally processed millet with 16±1% moisture content, tempered with 5% added water at I stage and 4% water in the II stage milling, resulted in a yield of 64.6%. The relationship of milling yield, hardness and porosity of the millet was quadratic with the severity of steaming conditions, while water uptake of the steamed millet exhibited a linear relationship. Based on the regression analysis, optimum conditions estimated for steaming time and pressure were 17.5 min and 313.8 kPa, respectively. At this condition, the milling yield, water uptake, porosity and hardness values were also predicted and the values were 68.33 g/100 g, 63.43 g/100 g, 52.23% and 204.01 N, respectively. The studies indicate that steaming the millet at elevated pressure and temperature increases the milling yield and steaming beyond the threshold level has a detrimental effect on the yield of head grains.     

Deacidification of Coconut Oil by Membrane Filtration

Ultrafiltration (UF) of coconut oil was carried out using a Millipore membrane cell at different pressures (0.1–0.4 MPa) and with different molecular weight cutoff membranes, that is,YM-1 (1 kDa), YM-3 (3 kDa), YM-10 (10 kDa), YM-30 (30 kDa), and PLTK-30 (30 kDa). Reduction of free fatty acids (FFAs) was 93.6%, 92.7%, 83.5%, 82.6%, and 81.6% with ethanol, methanol, acetone, n-propanol, and isopropyl alcohol, respectively, in three-stage filtration. The effects of temperature and applied pressure on the permeate flux and oil rejection were also studied with membranes using multistage filtration. As pressure increased from 0.1 to 0.4 MPa, the permeate flux and oil rejection increased linearly. A significant reduction of FFA was observed, which is in proportional with the amount of solvent in the feed used. The oil loss was less at lower temperature (25 °C) and pressure (0.2 MPa). Using PLTK 30 membrane with three-stage filtration, reduction of FFA was achieved up to 93% and 94% with methanol and ethanol solvents, respectively.