全文获取类型
收费全文 | 6430篇 |
免费 | 660篇 |
国内免费 | 398篇 |
学科分类
工业技术 | 7488篇 |
出版年
2024年 | 8篇 |
2023年 | 67篇 |
2022年 | 156篇 |
2021年 | 235篇 |
2020年 | 184篇 |
2019年 | 191篇 |
2018年 | 175篇 |
2017年 | 193篇 |
2016年 | 166篇 |
2015年 | 273篇 |
2014年 | 280篇 |
2013年 | 360篇 |
2012年 | 388篇 |
2011年 | 408篇 |
2010年 | 405篇 |
2009年 | 308篇 |
2008年 | 358篇 |
2007年 | 355篇 |
2006年 | 289篇 |
2005年 | 220篇 |
2004年 | 252篇 |
2003年 | 386篇 |
2002年 | 512篇 |
2001年 | 471篇 |
2000年 | 195篇 |
1999年 | 133篇 |
1998年 | 104篇 |
1997年 | 73篇 |
1996年 | 49篇 |
1995年 | 51篇 |
1994年 | 31篇 |
1993年 | 40篇 |
1992年 | 26篇 |
1991年 | 11篇 |
1990年 | 30篇 |
1989年 | 22篇 |
1988年 | 4篇 |
1987年 | 10篇 |
1986年 | 9篇 |
1985年 | 6篇 |
1984年 | 5篇 |
1983年 | 5篇 |
1982年 | 5篇 |
1980年 | 7篇 |
1978年 | 3篇 |
1977年 | 3篇 |
1976年 | 8篇 |
1975年 | 5篇 |
1969年 | 2篇 |
1958年 | 2篇 |
排序方式: 共有7488条查询结果,搜索用时 15 毫秒
81.
P. Da Costa C. Potvin J.-M. Manoli M. Breysse G. Djega-Mariadassou 《Catalysis Letters》2003,86(1-3):133-138
Hydrodesulfurization (HDS) of 4,6-dimethyldibenzothiophene on alumina-supported Mo2C has been studied. These catalysts are stable and active under deep HDS conditions (0-250 wt ppm S). However, although they are well known to have hydrogenation properties, they lead preferentially to a non-hydrogenated product of the HDS reaction: dimethylbiphenyl. For the same reaction, supported platinum and sulfided molybdenum oxide lead to the hydrogenated products dimethyldicyclohexyl and methylcyclohexyltoluene, respectively. The ranking of HDS activity is as follows: MoS2/Al2O3 < Mo2C/Al2O3 < Pt/SiO2. 相似文献
82.
83.
Inter-domain routing data and Internet active probing measurements are two types of information commonly available in huge datasets and subject to extensive, focused analysis. However, the study of the correlation between these two complementary types of information still remains one of the most challenging problems in today’s research in networking. In this paper we describe a metaphor for the visualization of the interplay between the routing information exchanged via BGP and the round-trip delay measurements collected by several geolocated probes. We implemented a prototype based on the above metaphor. Our prototype highlights both the Autonomous System topology and the latency associated with each AS-path over time. Further, it shows how probes are partitioned into clusters associated with each border gateway, based on observed traffic patterns. The resulting visualization allows the user to explore the dynamics of the correlation between the two types of information. 相似文献
84.
以蒂巴因为原料,经三步反应合成了高效镇痛剂依托啡,总产率由原来的19.1%提高到35.9%,并对各单元反应的条件及影响因素进行了探讨。 相似文献
85.
PET/纳米SiO2复合材料的制备(Ⅱ):纳米SiO2在PET中的分散性研究 总被引:8,自引:0,他引:8
研究了分散方法、纳米材料的加入体系、分散时间、分散剂的种类及SiO2 的加入量对纳米SiO2 在PET/纳米SiO2 中分散性的影响 ,用TEM对其分散情况进行表征 ,并对其分散机理进行探讨与研究。其结果表明 :采用球磨分散法并以氨基硅烷A1 1 2 0分散剂时分散效果最佳 ;当分散时间达 7 5h时 ,分散液中SiO2 基本以纳米尺寸存在 ;将分散液加入对苯二甲酸二甲酯熔体中并在球磨状态下进行酯交换SiO2 的分散效果最好 ,1 0 0nm以下的SiO2 达 95 0 7% ;体系中随SiO2 量的增加 ,其分散性变差 ,当纳米SiO2 的加入量为 1 %~ 4 %时 ,粒径在 1 0 0nm以下的SiO2 由 88%下降到 61 %。 相似文献
86.
不饱和聚酯树脂光固化工艺的研究-光引发剂浓度 总被引:5,自引:2,他引:5
本文选用TPO、651两种光引发剂,分别配制引发剂浓度为0.25、0.5、1、2wt%的不饱和聚酯体系。通过测定光固化试样的显微硬度分析光引发剂浓度对固化程度的影响。结果表明,提高引发剂浓度能抑制氧阻聚的作用,但对于较厚的试样,引发剂浓度过高会导致固化不完全。 相似文献
87.
88.
89.
Hai‐Xia Yang Yan‐Feng Li Jin‐Gang Liu Shi‐Yong Yang Da‐Xue Yin Lincheng Zhou Lin Fan 《应用聚合物科学杂志》2004,91(6):3981-3990
A series of new polymerized monomer reactants (PMR) matrix resins of poly(pyrrolone‐benzimidazole)s containing a pyridine unit (PPBP) were synthesized by polycondensation of monoethyl ester of cis‐5‐norbornene‐endo‐2,3‐dicarboxylic acid, 2,6‐diphenyl ester pyridinedicarboxylic acid or 3,5‐diphenyl ester pyridinedicarboxylic acid, and diethyl ester of 4,4′‐oxydiphthalic acid with 3,3′‐diaminobenzidine in a mixing solution of anhydrous ethyl alcohol and N‐methylpyrrolidone under given temperature and pressure conditions. The resulting resin solutions showed good solubility in polar organic solvents and stability at room temperature. The corresponding PPBP matrix resin, molded powder, and molded plate were prepared by undergoing amidation, imidization, cyclization, and crosslinking reactions when the reaction temperature was increased from 80 to 350°C, successively; the crosslinking structure was formed by the reverse Diels–Alder reaction at 270–290°C under 50 MPa pressure (2.5–3.5 MPa displayed by the pressure meter). The chemical reactions and properties of the resulting PPBP were studied by means of FTIR, TGA, and DMA methods, and the results indicated that the kinds of PPBP materials retain excellent thermal stability and processability; when the initial decomposition temperature was above 620°C the Tg was at 413.5°C for 3,5‐PPBP‐20 molded plate. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 91: 3981–3990, 2004 相似文献
90.
This paper considers the problem of employing multiple unmanned aerial vehicles (UAVs) to the mobile ad hoc network (MANET) as relay backbone nodes to construct the backbone network, to improve the network connectivity, and to address many issues in the MANET such as linkage, capacity, load balance, and reliability. With considering the dynamic nature of the problem, this study provides several linear location problem models and their extensions to accommodate these issues. Due to the size of linear location models associated with a large number of constraints, the problem becomes computational challenging even with modest size of nodes. To overcome the computational barrier, we recast these location problem models using a quadratic unconstrained binary optimization (QUBO) framework and solve these QUBO models with a Tabu search heuristic with preprocessing. The analysis of the solutions that are produced by QUBO together with the comparisons made with the linear model highlight both the attractiveness and robustness of the proposed approach. The results of this study provide support to future advanced routing protocol development. 相似文献