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41.
Qi Yang Qilong Wu Yang Liu Shuiping Luo Xiaotong Wu Xixia Zhao Haiyuan Zou Baihua Long Wen Chen Yujia Liao Lanxi Li Pei Kang Shen Lele Duan Zewei Quan 《Advanced materials (Deerfield Beach, Fla.)》2020,32(36):2002822
Engineering novel Sn-based bimetallic materials could provide intriguing catalytic properties to boost the electrochemical CO2 reduction. Herein, the first synthesis of homogeneous Sn1−xBix alloy nanoparticles (x up to 0.20) with native Bi-doped amorphous SnOx shells for efficient CO2 reduction is reported. The Bi-SnOx nanoshells boost the production of formate with high Faradaic efficiencies (>90%) over a wide potential window (−0.67 to −0.92 V vs RHE) with low overpotentials, outperforming current tin oxide catalysts. The state-of-the-art Bi-SnOx nanoshells derived from Sn0.80Bi0.20 alloy nanoparticles exhibit a great partial current density of 74.6 mA cm−2 and high Faradaic efficiency of 95.8%. The detailed electrocatalytic analyses and corresponding density functional theory calculations simultaneously reveal that the incorporation of Bi atoms into Sn species facilitates formate production by suppressing the formation of H2 and CO. 相似文献
42.
济阳坳陷下古生界潜山油气藏特征及成藏模式 总被引:1,自引:1,他引:0
济阳坳陷下古生界潜山具有多样性、复杂性的特点,潜山差异性的形成演化、油气成藏主控因素和控藏模式不明确,严重制约了该区潜山油气勘探。在潜山分类的基础上,综合利用系统恢复、分类对比和典型解剖等方法,揭示了济阳坳陷下古生界不同类型潜山的形成演化过程和油气成藏主控因素差异性,分类建立了油气成藏模式。研究表明,济阳坳陷下古生界主要发育高位新盖侵蚀残丘潜山、中位古盖拉张断块潜山、中位新古盖拉张剪切断块潜山、中位中古盖挤压拉张断块潜山和低位古盖拉张滑脱断块潜山5种潜山类型。不同类型潜山的形成演化和油气成藏各具特色,其中,高位新盖侵蚀残丘潜山的发育受隆升、侵蚀作用控制,油气成藏主要受控于油源和盖层条件,表现为"单向供烃、砂体-不整合岩溶体联合输导、残丘控藏"的成藏模式;中位古盖拉张断块潜山的发育受掀斜、断裂作用控制,油气成藏主要受控于储集条件,表现为"单向供烃、顺向断层输导、反向断层控藏"的成藏模式;中位新古盖拉张剪切断块潜山的发育受反转、翘倾和走滑切割作用控制,油气成藏主要受控于输导条件,表现为"多源供烃、断溶体立体输导、断裂控藏"的成藏模式;中位中古盖挤压拉张断块潜山的形成受强烈挤压、拉张滑脱作用控制,油气成藏主要受控于储集条件,表现为"多源供烃、断缝体输导、断褶控藏"的成藏模式;低位古盖拉张滑脱断块潜山的形成受强烈拉张滑脱作用控制,油气成藏主要受控于输导条件,表现为"顶部供烃、断缝体输导、断裂控藏"的成藏模式。 相似文献
43.
Dy3+, Eu3+: NaLa(WO4)2 phosphors are successfully synthesized through the solid-state reaction technique. The phase-structure and morphology are measured via X-ray diffraction and energy dispersive spectrometry. The concentrations of Dy3+, Eu3+, La3+, and W6+ are measured via ICP. The absorption and excited spectra are presented, which indicate that a blue band ranging from 430 to 480 nm is suitable for excitation. Using a commercial blue LED with a wavelength of 450 nm as the excitation light source, emission spectra for samples with varying dopant concentration ratios of Dy3+ to Eu3+ are obtained, which show good tunable yellow and red emission. For the purpose of investigating white LED performance, CIE spectra and a white light photo are also presented. The results reveal that varying the dopant concentration ratio of Dy3+ to Eu3+ plays a key role in the warm-white performance. With increasing concentration of Eu3+, the correlated color temperature decreases from 4069 to 3172 K, which indicates good warm-white performance. 相似文献
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不同折流板结构螺旋折流板换热器传热性能的比较(英文) 总被引:1,自引:0,他引:1
Numerical simulations were performed on flow and heat transfer performances of heat exchangers having six helical baffles of different baffle shapes and assembly configurations, i.e., two trisection baffle schemes, two quadrant baffle schemes, and two continuous helical baffle schemes. The temperature contour or the pressure contour and velocity contour plots with superimposed velocity vectors on meridian, transverse and unfolded concentric hexagonal slices are presented to obtain a full angular view. For the six helix baffled heat exchangers, the different patterns of the single vortex secondary flow and the shortcut leakage flow were depicted as wel as the heat transfer properties were compared. The results show that the optimum scheme among the six configurations is a circumferential overlap trisection helix baffled heat exchanger with a baffle incline angle of 20° (20°TCO) scheme with an anti-shortcut baffle structure, which exhibits the second highest pressure dropΔpo, the highest overal heat transfer coefficient K, shel-side heat transfer coefficient ho and shel-side average comprehensive index ho/Δpo. 相似文献
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Thermally conductive polymers offer new possibilities for the heat dissipation in electric and electronic components, for example, by a three‐dimensional shaping of the heat sinks. To face safety regulations, improved fire performance of those components is required. In contrast to unfilled polymers, those materials exhibit an entirely different thermal behavior. To investigate the flammability, a phosphorus flame retardant was incorporated into thermally conductive composites of polyamide 6 and hexagonal boron nitride. The flame retardant decreased the thermal conductivity only slightly. However, the burning behavior changed significantly, due to a different heat propagation, which was investigated using a thermographic camera. An optimum content of hexagonal boron nitride for a sufficient thermal conductivity and fire performance was found between 20 and 30 vol%. The improvement of the fire performance was due to a faster heat release out of the pyrolysis zone and an earlier decomposition of the flame retardant. For higher contents of hexagonal boron nitride, the heat was spread faster within the part, promoting an earlier ignition and increasing the decomposition rate of the flame retardant. 相似文献