A gas chromatography–mass spectrometry method for the detection of chlorpyrifos contamination in palm-based fatty acids

Chlorpyrifos is a Malaysian Pesticide Board-approved organophosphate insecticide, which may become concentrated during fractionation. The objective of this project was to develop and validate a method to detect and quantify chlorpyrifos in food-grade fatty acids ingredients, e.g. caprylic-capric acid mixture and oleic acid (OLA) used to synthesize triacylglyceride based food additives and in the cosmetic industry. A selective ion monitoring gas chromatography–mass spectrometry method with a matrix-matched calibration curve calibration was selected. The method involved the direct injection of chlorpyrifos spiked into the fatty acids matrix. The percentage recoveries at spiking levels of 0.5, 0.75, 2.5, and 4.0 μg g⁻¹ of chlorpyrifos in OLA and caprylic-capric acid ranged from 85.7%–101.1% to 97.2%–112%, respectively, with a relative standard deviation of within 11%. The intra-day and inter-day precision were deemed acceptable as indicated by an relative SD value of within 10%. A good linear relationship with a coefficient of correlation >0.99 for the matrix-matched calibration was achieved between 0.5 and 5 μg g⁻¹. The limit of detection and limit of quantification corresponded to 0.5 μg g⁻¹ for OLA and 0.55 μg g⁻¹ for caprylic-capric acid.     

Effect of special structure of clam shell powder on structure and properties of castor oil-based composites

Castor oil (CO) is an environmentally friendly renewable green resource and ideal alternative to petroleum resources. The preparation of high strength and high toughness castor oil-based polyurethane prepolymer (COPU) composites has significant applications such as supporting material and engineering plastic sheet. In this study, unmodified clam shell powder (CSP) with a unique CaCO₃-proteoglycan structure was used as a filler to prepare compatible reinforced COPU composite materials. Investigation of the mechanical properties revealed that the elastic modulus of the composite COPU reinforced with 50 wt% of CSP had increased to 5859.0 ± 8.4 MPa representing 187.77% to obtain stiffer and stronger material over pure COPU (2036.6 ± 196.9 MPa). Moreover, the scanning electron microscopy, thermogravimetric analysis and contact angle results demonstrated that the reinforced COPU composites have better compatibility, thermal stability, and water resistance than pure COPU. This work will promote the application prospects of CO-based polyurethane.     

应用于机械手的磁致伸缩触觉传感器阵列与物体识别

利用磁致伸缩材料铁镓合金(Galfenol)设计制作了触觉传感单元,并将其集成为阵列,安装在二指机械手上.基于电磁原理、逆磁致伸缩效应和欧拉伯努利动力学原理,建立触觉传感单元力测量模型.设计的传感单元测力范围为0～3N,当压力小于1.5N时,灵敏度为151mV/N,在1.5～3N区间,灵敏度约为109mV/N,测量较低的静态力时具有更高的灵敏度,在2～4Hz范围内对动态力具有动态响应快、灵敏度高的特点.根据机械手的测量范围,选取形状较为规则的六种饮料瓶样品进行了抓取,搭建实验系统进行数据采集与存储,测试了传感器阵列的输出特性,集成的传感器阵列能很好地辨识所选样品,对于装满水样品有更高的精度.选择合适的特征值,应用支持向量机算法,通过选择不同的特征值数量和训练集与分类集的比例,对采集的数据进行分类识别.经计算可知,选择三个特征值且训练集与分类集比例为9:1时识别率最高,为87.5％.     

压力加工机械载荷与轴温的监测

分析了压力加工载荷和轴温监测的基本要求，介绍了载荷和轴温测量的原理与技术，说明了监测方案的设计及实施方法。     

金属蜂窝负载Pd催化甲烷部分氧化制合成气

采用浸渍法制备负载金属Pd(其中金属Pd含量0.6g/L)活性组分的金属蜂窝载体催化剂,应用于甲烷部分氧化制合成气。实验表明,焙烧温度为950℃的催化剂较600℃的催化剂甲烷转化率、CO和H2的选择性更高,焙烧温度为950℃的催化剂在反应温度800℃,GHSV=1×105ml/g·h条件下,甲烷转化率为91%,CO和H2的选择性分别达到90%和89%。用SEM与XPS对催化剂进行表征,结果表明,950℃焙烧催化剂并没有出现明显的烧结现象,且可能由于更多零价Pd的出现,使得该催化剂的性能更好。由于金属蜂窝载体优良的导热性,对950℃焙烧温度制备的金属蜂窝催化剂,催化剂床层的飞温点温度小于880℃,可以解决其它类型催化剂在甲烷部分氧化反应中出现的飞温问题,具有一定的工业化意义。     

Hydraulic erosion of concrete by a submerged jet

The hydraulic erosion of concrete is often found in civil and marine engineering construction. The present study explores the effects of several erosion parameters on the material loss of a concrete specimen subject to the hydraulic flow produced by a submerged jet. Such an investigation has rarely been reported in the literature. The concrete specimen has a typical compressive strength of 35 MPa, and the experimental parameters include the exposure time, incidence angle, standoff distance, and the hydraulic jet pressure. The impinging velocity is estimated based on the distance considered in the round jet model. The regression analysis shows the relationship between each parameter and the material loss. One finds that the material loss is proportional to the exposure time and the hydraulic pressure. The maximum erosion lies at an incidence angle of around 30° to 45° and is affected by the fourth-order polynomial of impinging velocity. The result of the present study provides a reference to engineering practice where concrete erosion is a concern.     

LiBH4／Mg复合氢化物的储氢性能研究

通过球磨LiBHdMg，使得镁的吸放氢性能得到明显改善。活化结果显示，在氩气气氛下，球磨1h的LiBHdMg混合物经250℃，60min处理后的吸氢量可以达到6．7％（质量分数，下同）。200℃，80min处理后的吸氢量可以达到3．0％。而纯镁粉在相同条件下几乎不吸氢。PCT结果显示，LiBH4也明显改善镁氢化后的放氢性能。     

脚踏塑件注射模嵌件定位的结构设计

分析了脚踏塑件的工艺特点，介绍了成型该塑件的注射模结构设计及一种嵌件定位的机构，阐述了该模具的工作过程。     

盖下坝水电站坝址区岩溶发育情况初步分析

盖下坝水电站工程为高山峡谷型电站,坝址区及附近岩石为碳酸盐岩,属中等坚硬易溶岩.岩溶发育是影响本工程库水外渗的重大工程地质问题之一.从施工开挖揭示的各种溶蚀现象中分析岩溶发育特征及其规律,为防渗设计提供依据.     

多场景视频监控中的人物连续跟踪

针对多场景监控,提出一种能在非重叠的多摄像机之间,实时地检测与被跟踪行人（目标）的视频监控系统。该系统分别对每个摄像机视频进行背景建模、前景检测以及运动目标的特征提取,当目标离开摄像机视域的时候,根据已知的拓扑关系向相关摄像机发布监控任务,当有目标进入处于有效监控状态的摄像机视域时,进行目标匹配,从而实现在多摄像机系统中对行人目标的持续跟踪。实验表明,该系统在非重叠摄像机场景中能实现实时的、鲁棒的目标跟踪。