Measurement method for profiling the residual stress of an optical fiber: detailed analysis of off-focusing and beam-deflection effects

The effects of off-focusing and beam deflection on polarimetric stress measurements of optical fibers are investigated. A simple method for reducing the distortion of the phase retardation caused by unwanted beam deflections in residual stress measurement is introduced. The method is examined numerically by ray-tracing techniques and experimentally by use of hollow silica fibers into which various index-matching liquids have been inserted. An autofocusing technique is introduced. The error in stress measurement reproducibility was determined to be less than 4%. We tested the absolute error in measured stress by applying incremental external tension and determined that it is less than 0.464 MPa.     

NMR of 89Y in the Copper-Oxide Spin-Chain Compound Ca2+x Y2−x Cu5O10

We report NMR lineshape, spin-lattice relaxation time T ₁, and spin-spin relaxation time T ₂ data at 17 MHz (8.07 T) for ⁸⁹Y in the copper-oxide spin-chain compound Ca_2+x Y_2–x Cu₅O₁₀. For x=0, a broad, asymmetric line with width 90 kHz is observed for T=250–300 K. The spectra exhibit an appreciable average shift (H/H+0.7%) and sharpen at lower temperature, possibly due to increasing intrachain ferromagnetic correlations. T ₁ and T ₂ decrease with decreasing temperature. The Tl data imply a short correlation-time limit, with _e=3–5×10^–11 s. The T ₂ data apparently include a contribution from dipolar interactions with copper nuclei. Relaxation time data for a doped (x=0.5) compound surprisingly show more rapid relaxation.     

Electrogenerated chemiluminescence from tris(2,2'-bipyridyl)ruthenium(II) immobilized in titania-perfluorosulfonated ionomer composite films

Electrochemical behavior and electrogenerated chemiluminescence (ECL) of tris(2,2'-bipyridyl)ruthenium(II) (Ru(bpy)3(2+)) immobilized in sol-gel-derived titania TiO2)-Nafion composite films coated on a glassy carbon electrode have been investigated. The electroactivity of Ru(bpy)3(2+) ion exchanged into the composite films and its ECL behavior were strongly dependent upon the amount of Nafion incorporated into the TiO2-Nafion composite films. The ECL sensor of Ru(bpy)32+ immobilized in a TiO2-Nafion composite with 50% Nafion content showed the maximum ECL intensities for both tripropylamine (TPA) and sodium oxalate in 0.05 M phosphate buffer solution at pH 7. Detection limits were 0.1 microM for TPA and 1.0 microM for oxalate (S/N = 3) with a linear range of 3 orders of magnitude in concentration. The present ECL sensor showed improved ECL sensitivity and long-term stability, as compared to the ECL sensors based on pure Nafion films. The present Ru(bpy)3(2+) ECL sensor based on TiO2-Nafion (50%) composite films was applied as an HPLC detector for the determination of erythromycin in human urine samples. The present Ru(bpy)3(2+) ECL sensor was stable in the mobile phase containing a high content of organic solvent (30%, v/v), in contrast to a pure Nafion-based Ru(bpy)3(2+) ECL sensor. The detection limit for erythromycin was 1.0 microM, with a linear range of 3 orders of magnitude in concentration.     

Thermal decomposition of 1,1-dichloroethene diluted in hydrogen

The reaction of 1,1-dichloroethene in an excess hydrogen environment with a Cl/H ratio of 0.04 was investigated in an isothermal tubular reactor at a total pressure of 1 atm with residence time of 0.3-2.0 s between 575 and 900 degrees C. C(2)H(3)Cl and HCl are the primary reaction products from the decomposition of CH(2)CCl(2) while the formation of C(2)H(4), C(2)H(2), C(2)H(6), and CH(4) increases as reaction time or temperature increases.Modeling used a detailed chemical mechanism involving 59 species and 202 elementary reactions; the results were compared with experimental observations. Sensitivity analyses were also performed to rank the significance of each reaction in the mechanism. The optimal reaction condition for the C(2) hydrocarbons production from the dechlorination of CH(2)CCl(2) in H(2) environment was also determined.     

Distribution of phenanthrene between soil and an aqueous phase in the presence of anionic micelle-like amphiphilic polyurethane particles

Sorption of micelle-like amphiphilic polyurethane (APU) particles to soil was studied and compared to that of a model anionic surfactant, sodium dodecyl sulfate (SDS). Three types of APU particles with different hydrophobicity were synthesized from urethane acrylate anionomers (UAA) and used in this study. Due to the chemically cross-linked structure, APU exhibited less sorption to the soil than SDS and a greater reduction in the sorption of phenanthrene, a model soil contaminant, to the soil was observed in the presence of APU than SDS even though the solubility of phenanthrene was higher in the presence of SDS than APU. A mathematical model was developed to describe the phenanthrene distribution between soil and an aqueous phase containing APU particles. The sorption of phenanthrene to the test soil could be well described by Linear isotherm. APU sorption to the soil was successfully described by Langmuir and Freundlich isotherms. The partition of phenanthrene between water and APU were successfully explained with a single partition coefficient. The model, which accounts for the limited solubilization of phenanthrene in sorbed APU particles, successfully described the experimental data for the distribution of phenanthrene between the soil and the aqueous phase in the presence of APU.     

Physicochemical characterization of diclofenac sodium-loaded poloxamer gel as a rectal delivery system with fast absorption

Rectal poloxamer gel systems composed of poloxamers and bioadhesive polymers were easy to administer to the anus and were mucoadhesive to the rectal tissues without leakage after the dose. However, a poloxamer gel containing diclofenac sodium could not be developed using bioadhesive polymers, since the drug was precipitated in this preparation. To develop a poloxamer gel using sodium chloride instead of bioadhesive polymers, the physicochemical properties such as gelation temperature, gel strength, and bioadhesive force of various formulations composed of diclofenac sodium, poloxamers, and sodium chloride were investigated. Furthermore, the pharmacokinetic study of diclofenac sodium delivered by the poloxamer gel was performed. Diclofenac sodium significantly increased the gelation temperature and weakened the gel strength and bioadhesive force, while sodium chloride did the opposite. The poloxamer gels with less than 1.0% sodium chloride, in which the drug was not precipitated, were inserted into the rectum without difficulty and leakage, and were retained in the rectum of rats for at least 6 hr. Furthermore, poloxamer gel gave significantly higher initial plasma concentrations and faster T_max of diclofenac sodium than did solid suppository, indicating that drug from poloxamer gel could be absorbed faster than that from the solid one in rats. Our results suggested that a rectal poloxamer gel system with sodium chloride and poloxamers was a more physically stable, convenient, and effective rectal dosage form for diclofenac sodium.     

Feasibility of calculating morphology-dependent resonance peaks by numerical methods

We investigate the feasibility of numerically calculating morphology-dependent resonance (MDR) peaks. To do so, one has to calculate the scattering intensities numerically and determine how difficult it is to numerically predict the position and the magnitude of the MDR peaks. However, at present, in practice it is impossible to calculate MDR peaks with a personal computer because so much computing time is required. Therefore the surface values of the Debye potential and its derivative for a homogeneous sphere are obtained from Mie's analytical solution and then used in integral equations to give the scattering intensities at a specific position of infinity by numerical integrations. It is shown that if a sufficient number of surface elements are used, the MDR peaks are exactly calculated for a homogeneous sphere with refractive index of 1.5, 1.4, and 1.3 up to a size parameter of 20. One can conjecture the number of finite and boundary elements necessary to numerically compute accurate scattering intensities. It should be also noted that the number of surface elements necessary for exact integration shows peaks similar to MDR peaks with respect to the size parameter. Therefore one will need many more elements at the size parameter at which the MDR occurs.     

Selective CO Gas Detection of Zn2SnO4 Gas Sensor

The ability of semiconductor gas sensors to differentiate between gases is essential but difficult to obtain. In this study, Zn₂SnO₄ was made to be CO selective and the possible mechanism for the selectivity was studied.The electrical and the gas-sensing properties of uncoated and CuO-coated Zn₂SnO₄ were investigated. In order to obtain an ohmic contact to Zn₂SnO₄, a ZnO layer was stacked on top of Zn₂SnO₄ and co-fired. CuO was coated by immersing the sintered sample in Cu-containing solution. Both uncoated and CuO-coated samples showed the higher sensitivity to 200 ppm CO gas than to 200 ppm H₂ gas. However, the CuO-coated Zn₂SnO₄ showed much enhanced sensitivity and thus good selectivity for CO gas (S _CO/S _{H 2} 6) compared to the uncoated sample. The excellent selectivity of Zn₂SnO₄-based materials for CO gas was explained by the difference in the mechanisms of CO and H₂ oxidation.     

Selectivity of multiple-contact nerve cuff electrodes: a simulation analysis

Advances in functional neuromuscular stimulation (FNS) have increased the need for nerve cuff designs that can control multiple motor functions through selective stimulation of selected populations of axons. This selectivity has proved to be difficult to achieve. Recent experiments suggest that it is possible to slowly reshape peripheral nerve without affecting its physiological function. Using computer simulations we have tested the hypothesis that changing the cross section of a nerve from a round to a flat configuration can significantly improve the selectivity of a nerve cuff. We introduce a new index to estimate selectivity to evaluate the various designs. This index is based on the ability of a nerve electrode to stimulate a target axon without stimulating any other axons. The calculations involve a three-dimensional finite element model to represent the electrical properties of the nerve and cuff and the determination of the firing properties of individual axons. The selectivity rating was found to be significantly higher for the Flat Cuff than the Round Cuff. The result was valid with uniform or random distribution of axons and with a random distribution of fascicles diameters. Flattening of individual fascicles also improved the selectivity of the Flat Cuff but only when the number of contacts used was increased to maintain uniform contact density. Therefore, cuff designs that can reshape the nerve into flatter configurations should yield better cuff performance than the cylindrical cuffs but will require higher contact density.     

Crystallization studies on phase-change optical recording media by use of a two-dimensional periodic mark array

We present the results of crystallization studies in thin-film samples of amorphous and crystalline Ge(x)Sb(y)Te(z). The experiments, conducted at moderately elevated temperatures, are based on measurements of the first-order diffraction efficiency from a two-dimensional periodic array of recorded marks. When the samples are slowly heated above room temperature, changes in the efficiencies of various diffracted orders give information about the on-going crystallization process within the sample. Two different compositions of the GeSbTe alloy are used in these experiments. Measurements on Ge(2)Sb(2.3)Te(5) films show crystallization dominated by nucleation. For the Sb-rich eutectic composition Ge-(SbTe), crystallization is found to be dominated by growth from crystalline boundaries. We also show that crystalline marks written by relatively high-power laser pulses are different in their optical properties from the regions crystallized by slow heating of the sample to moderate temperatures.