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991.
采用高温固相法在不同条件下合成了一系列球形LiNi0.8Co0.1Mn0.1O2正极材料,并通过XRD、SEM、TEM、EDS等表征手段对其物相结构、形貌以及电化学性能进行了研究.结果表明,Li/Me(摩尔比)为1.07时合成的正极材料结晶良好,结构稳定,以0.2 C倍率在2.8~4.3 V电压范围内的首次放电比容量为200.4 mAh/g,首次充放电效率为86.7%,1 C放电比容量为189.5 mAh/g,50次循环之后的放电比容量为178.3 mAh/g,此时容量保持率高达94.1%.继续循环至100次比容量还有145.7 mAh/g,容量保持率为76.9%. 相似文献
992.
993.
994.
The characterization and corrosion resistance of cerium chemical conversion coatings for 304 stainless steel 总被引:1,自引:0,他引:1
A golden yellow-colored cerium conversion coating was obtained on 304 stainless steel surface by immersing the steel into a solution containing cerium (III), KMnO4 and sulfuric acid. The corrosion resistance of the coatings was evaluated by electrochemical methods, potentiodynamic polarization experiments and electrochemical impedance spectrum. The experimental results indicated that the corrosion resistance for the conversion coated 304SS in 3.5% NaCl solution increased markedly. The corrosion potential of the treated steel increased to a more noble level, the pitting corrosion potential increased also, the passive potential range was enlarged markedly and the passive current density decreased about one order compared to that of the untreated steel. The cathodic and anodic reaction were both inhibited to some extent. The chemical state of the elements in the coatings was investigated by XPS. The cerium element was in the form of tetravalent state. And AES depth profile analysis suggested that the thickness of the conversion coatings was less than 66 nm. The mechanisms of coatings formation and corrosion resistance are discussed. 相似文献
995.
钛金属与汽车工业研讨会纪要 总被引:7,自引:0,他引:7
综述了介孔材料的合成方法、分类、形成机理、形貌控制和应用。目前各种形状如球形、棒状、片状、螺旋形和绳形等形状的介孔材料已经采用溶胶.凝胶、自组装、微乳、反胶束和超声等方法合成出来。按化学组成介孔材料分为硅基和非硅介孔材料,硅基介孔材料已被很好地研究,相反,非硅介孔材料虽然有着广泛的应用前景但研究不多。介孔材料的几种形成机理已经被提出,主要包括液晶模板和协同组装机理。作者也采用化学超声和反胶束方法制备出新奇的介孔二氧化钛粉末和薄膜材料,其光催化活性明显高于普通二氧化钛粉末和薄膜材料。 相似文献
996.
997.
Design of a six-axis high precision machine tool and its application in machining aspherical optical mirrors 总被引:4,自引:1,他引:4
Hao-Bo Cheng Zhi-Jing Feng Kai Cheng Ying-Wei Wang 《International Journal of Machine Tools and Manufacture》2005,45(9):1085-1094
The paper presents the design of a six-axis machining system and its application in fabricating large off-axis aspherical mirrors with sub-aperture lapping techniques. The new system is based on computer-controlled optical surfacing (CCOS), which combines the faculties of grinding, polishing, and on-machine profile measuring, has the features of conventional loose abrasive machining with the characteristics of a tool having multiple degrees of freedom moving in planar model. And a novel dual touch-trigger probe profiler is designed, which is composed of a probe, model METRO-MT60 made by HEIDENHAIN Co., is integrated into the system for measuring the shape accuracy of the tested aspherical surface, another probe modeled METRO-MT12 is designed as a calibrating device for minimizing the cosine error caused by assembly inaccuracy. The new CNC machining system with two kinds of moving coordinate systems, dual tool activities and on-machine measuring is presently developed based on the new concept. The general material removal function during machining is analyzed on the basis of the Preston hypothesis. Further, an alignment test of the measuring profiler is carried out using a leveling rule as a specimen. The accuracy of the optical surfaces measured by the dual probe profiler is found to be within 1 μm PV after removing cosine error and error compensating, achieves to the resolving power of the profiler is about 0.2–0.5 μm, so the developed system can be applied to the shape accuracy measuring of aspheric fabrication with micro precision during fine grinding process according to the calibrating results. Finally, the manufacturing experiments are carried out by virtue of an off-axis oblate ellipsoid mirror with rectangular aperture as 770 mm×210 mm and centered 127 mm. The accuracy of the aspherical mirror improved from the initial form error of 17.648 μm rms to the final one of 0.728 μm rms after grinding for 200 h. 相似文献
998.
In this research, Cr(N)/C(DLC) multilayered coatings were deposited on M2 steel substrates by an unbalanced magnetron sputtering technique. By varying the substrate rotation speed, four multilayered coatings with different bilayer thickness were produced. The bilayer thickness and structure of multilayered coatings were characterized by low-angle XRD, XPS depth profile, and cross-section TEM observation. The tribological investigation focused on the effect of layer thickness and tribological media on tribological property of the multilayer coatings against Al counterface. A pin-on-disc tribometer with a tribological medium container was used to investigate the wear behaviours of the four multilayered coatings under dry and wet (distilled water and S500 coolant) sliding. A stylus surface profilometer was used to measure wear rate. The investigation of wear tracks and wear mechanism was performed using Scanning Electron Microscopy (SEM). The research results showed that coatings with different bilayer period performed different tribological behaviour. The proper tribological media applied in the wear tests could improve the wear properties of multilayer coatings. 相似文献
999.
Zr-Si-N扩散阻挡层及其热稳定性的研究 总被引:5,自引:0,他引:5
用反应磁控溅射法在不同偏压下沉积了Zr-Si-N扩散阻挡层,结果表明:Zr-Si-N膜的Si含量、电阻率随偏压的升高而降低;Zr-Si-N膜的晶体相随溅射偏压的升高而增加;Zr-Si-N扩散阻挡层的热稳定性高,在850℃时仍能有效阻挡Cu的扩散. 相似文献
1000.